Synthesis of α-Substituted Indolylacetamide using Acetonitriles as Acetamide Enolate Equivalents through O-Transfer Reactions

2021 ◽  
Author(s):  
Takumi Abe ◽  
Kenta Noda ◽  
Daisuke Sawada
Keyword(s):  
Transfer Reactions ◽  
Primary Amide ◽  
One Pot

We introduce readily available ammonium hemiaminals as O-transfer reagents and commercially available acetonitriles as a primary amide enolate precursor. The combination serve as amide enolate equivalents, thereby providing one-pot access...

A NOVEL LOW TEMPERATURE SYNTHESIS OF CRYSTALLINE POWDERS OF CADMIUM AND ZINC SELENIDES VIA ELECTRON TRANSFER REACTIONS IN ORGANIC SOLUTION

2005 ◽  
Vol 04 (05n06) ◽  
pp. 827-830
Author(s):  
PAUL. O'BRIEN ◽  
DAVID. J. CROUCH
Keyword(s):  
Electron Transfer ◽  
Transfer Reactions ◽  
Elemental Selenium ◽  
X Ray Diffraction ◽  
Organic Solution ◽  
Low Temperature Synthesis ◽  
Temperature Synthesis ◽  
One Pot ◽  
X Ray ◽  
Wet Synthesis

Good quality crystalline powders of the II/VI semiconductors ME ( M = Zn or Cd , E = Se ) have been prepared in a "one-pot" wet synthesis from elemental selenium under "Birch"-type conditions using N -methyloctadecylamine as the solvent/electron transfer reagent. The CdSe and ZnSe materials have been characterised by powder X-ray diffraction (PXRD) and their band gaps.

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