Scandium and Lanthanum Hydride Complexes Stabilized by Super-bulky Penta-arylcyclopentadienyl Ligands

2021 ◽  
Author(s):  
Yang Wang ◽  
Iker Del Rosal ◽  
Guorui Qin ◽  
Lanxiao Zhao ◽  
Laurent Maron ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Metal ◽  
Earth Metal ◽  
Hydride Complexes ◽  
Half Sandwich

Hydrogenolysis of the half-sandwich penta-arylcycopentadienyl-supported rare-earth metal dibenzyl complexes [(CpAr5)Ln(p-CH2-C6H4-Me)2(THF)] (CpAr5 = C5Ar5, Ar = 3,5-iPr2-C6H3; Ln = Sc, La) afforded bimetallic scandium complex [(CpAr5)Sc(H)(μ-OC4H9)]2 (2) with two terminal hydrido...

Copolymerization of Ethylene with Norbornene Catalyzed by Cationic Rare-Earth Metal Half-Sandwich Complexes

2008 ◽  
Vol 41 (24) ◽  
pp. 9565-9569 ◽  
Author(s):  
Andrea Ravasio ◽  
Cristina Zampa ◽  
Laura Boggioni ◽  
Incoronata Tritto ◽  
Julia Hitzbleck ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Metal ◽  
Earth Metal ◽  
Sandwich Complexes ◽  
Half Sandwich

Rare‐Earth‐Metal Pentadienyl Half‐Sandwich and Sandwich Tetramethylaluminates–Synthesis, Structure, Reactivity, and Performance in Isoprene Polymerization

2019 ◽  
Vol 25 (18) ◽  
pp. 4821-4832 ◽  
Author(s):  
Damir Barisic ◽  
Dennis A. Buschmann ◽  
David Schneider ◽  
Cäcilia Maichle‐Mössmer ◽  
Reiner Anwander
Keyword(s):  
Rare Earth ◽  
Rare Earth Metal ◽  
Earth Metal ◽  
And Performance ◽  
Half Sandwich ◽  
Isoprene Polymerization

Ln(II)/Pb(II)–Ln(III)/Pb(0) Redox Approach toward Rare-Earth-Metal Half-Sandwich Complexes

2015 ◽  
Vol 34 (24) ◽  
pp. 5734-5744 ◽  
Author(s):  
André M. Bienfait ◽  
Benjamin M. Wolf ◽  
Karl W. Törnroos ◽  
Reiner Anwander
Keyword(s):  
Rare Earth ◽  
Rare Earth Metal ◽  
Earth Metal ◽  
Sandwich Complexes ◽  
Half Sandwich

Synthesis of linked half sandwich rare-earth metal chlorido and borohydrido complexes and their catalytic behavior towards MMA polymerization

2010 ◽  
Vol 39 (29) ◽  
pp. 6871 ◽  
Author(s):  
Zhongbao Jian ◽  
Wei Zhao ◽  
Xinli Liu ◽  
Xuesi Chen ◽  
Tao Tang ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Metal ◽  
Earth Metal ◽  
Catalytic Behavior ◽  
Mma Polymerization ◽  
Half Sandwich
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