Recent developments in highly basic N-heterocyclic iminato ligands in actinide chemistry

2021 ◽  
Author(s):  
Shanmugam Revathi ◽  
Preethi Raja ◽  
Sayantani Saha ◽  
Moris S. Eisen ◽  
Tapas Ghatak
Keyword(s):  
Metal Ions ◽  
Review Article ◽  
Current Review ◽  
Actinide Chemistry ◽  
Recent Developments

Recent findings in the chemistry of light actinide metal ions with N-heterocyclic iminato moieties as supporting ligands are described in the current review article. The emphasis is on the catalytic applicability of actinide complexes for oxygen containing substrates.

Recent Synthetic Strategies for Monocyclic Azole Nucleus and Its Role in Drug Discovery and Development

2018 ◽  
Vol 15 (3) ◽  
pp. 321-340 ◽  
Author(s):  
Neha ◽  
Ashish Ranjan Dwivedi ◽  
Rakesh Kumar ◽  
Vinod Kumar
Keyword(s):  
Heterocyclic Compounds ◽  
Biological Activities ◽  
Review Article ◽  
Drug Discovery And Development ◽  
Drug Candidates ◽  
Drug Molecules ◽  
Current Review ◽  
Biological Potential ◽  
Recent Developments ◽  
Potent Drug

Background: In recent years, the development and diversification of heterocyclic compounds has become central to the discovery of bioactive compounds with novel or improved pharmacological properties. In particular, N-containing heterocycles are proved to be promising leads and drug candidates, and received huge attention of the medicinal chemists. Objective: Many drugs especially antibiotics are becoming obsolete due to the development of multidrug resistance. Moreover, toxicity and other side effects of some drugs necessitated the quest for safer and more potent drug candidates. The current review article described biological potential of various monocyclic azoles. Recent developments in the synthesis of azole derivatives have been also reviewed. Conclusion: The presence of N-heterocyclic rings can influence the pharmacokinetics, pharmacodynamics, pKa and bioavailability profile of the drug molecules. Compounds containing monocyclic azole rings showed various biological activities and number of molecules are in clinical practice. A number of important leads and potential drug candidates containing azole nucleus are in advance stages of drug developments. Thus, simple, atom economic and more efficient synthetic strategies are desired for the synthesis of new libraries of the compounds.

Recent Developments in the Downstream Processing of Phycobiliproteins from Algae: A Review

2021 ◽  
Vol 06 ◽  
Author(s):  
Ayekpam Chandralekha Devi ◽  
G. K. Hamsavi ◽  
Simran Sahota ◽  
Rochak Mittal ◽  
Hrishikesh A. Tavanandi ◽  
...  
Keyword(s):  
Cell Wall ◽  
Large Scale ◽  
Downstream Processing ◽  
Review Article ◽  
Current Status ◽  
Wall Structure ◽  
Scale Production ◽  
Cell Wall Disruption ◽  
Recent Developments ◽  
Macro Algae

Abstract: Algae (both micro and macro) have gained huge attention in the recent past for their high commercial value products. They are the source of various biomolecules of commercial applications ranging from nutraceuticals to fuels. Phycobiliproteins are one such high value low volume compounds which are mainly obtained from micro and macro algae. In order to tap the bioresource, a significant amount of work has been carried out for large scale production of algal biomass. However, work on downstream processing aspects of phycobiliproteins (PBPs) from algae is scarce, especially in case of macroalgae. There are several difficulties in cell wall disruption of both micro and macro algae because of their cell wall structure and compositions. At the same time, there are several challenges in the purification of phycobiliproteins. The current review article focuses on the recent developments in downstream processing of phycobiliproteins (mainly phycocyanins and phycoerythrins) from micro and macroalgae. The current status, the recent advancements and potential technologies (that are under development) are summarised in this review article besides providing future directions for the present research area.

Numerical Taxonomy in Marketing Analysis: A Review Article

1968 ◽  
Vol 5 (1) ◽  
pp. 83-94 ◽  
Author(s):  
Ronald E. Frank ◽  
Paul E. Green
Keyword(s):  
Numerical Taxonomy ◽  
Review Article ◽  
Numerical Classification ◽  
Classification Problems ◽  
Recent Developments ◽  
Marketing Analysis

Recent developments in numerical taxonomy appear to show applicability for many classification problems in marketing. This review article describes some of the approaches to numerical classification and presents illustrative marketing applications. Current limitations of the procedures are also discussed.

scholarly journals Recent Developments on Five-Component Reactions

Molecules ◽  
2021 ◽  
Vol 26 (7) ◽  
pp. 1986
Author(s):  
Xiaoming Ma ◽  
Sanjun Zhi ◽  
Wei Zhang
Keyword(s):  
Multicomponent Reactions ◽  
High Efficiency ◽  
Review Article ◽  
Reaction Centers ◽  
Synthetic Approach ◽  
Recent Developments

Multicomponent reactions (MCRs) have inherent advantages in pot, atom, and step economy (PASE). This important green synthetic approach has gained increasing attention due to high efficiency, minimal waste, saving resources, and straightforward procedures. Presented in this review article are the recent development on 5-compoment reactions (5CRs) of the following six types: (I) five different molecules A + B + C + D + E; pseudo-5CRs including (II) 2A + B + C + D, (III) 2A + 2B + C, (IV) 3A + B + C, (V) 3A + 2B, and (VI) 4A + B. 5CRs with more than five-reaction centers are also included.

scholarly journals Recent Developments in Lignin- and Tannin-Based Non-Isocyanate Polyurethane Resins for Wood Adhesives—A Review

2021 ◽  
Vol 11 (9) ◽  
pp. 4242
Author(s):  
Manggar Arum Aristri ◽  
Muhammad Adly Rahandi Lubis ◽  
Sumit Manohar Yadav ◽  
Petar Antov ◽  
Antonios N. Papadopoulos ◽  
...  
Keyword(s):  
Automotive Industry ◽  
Polymeric Materials ◽  
Review Article ◽  
Future Perspectives ◽  
Wood Adhesives ◽  
Adhesion Properties ◽  
Lighting Industry ◽  
Renewable Natural Resources ◽  
Recent Developments ◽  
Strong Adhesion

This review article aims to summarize the potential of using renewable natural resources, such as lignin and tannin, in the preparation of NIPUs for wood adhesives. Polyurethanes (PUs) are extremely versatile polymeric materials, which have been widely used in numerous applications, e.g., packaging, footwear, construction, the automotive industry, the lighting industry, insulation panels, bedding, furniture, metallurgy, sealants, coatings, foams, and wood adhesives. The isocyanate-based PUs exhibit strong adhesion properties, excellent flexibility, and durability, but they lack renewability. Therefore, this study focused on the development of non-isocyanate polyurethane lignin and tannin resins for wood adhesives. PUs are commercially synthesized using polyols and polyisocyanates. Isocyanates are toxic, costly, and not renewable; thus, a search of suitable alternatives in the synthesis of polyurethane resins is needed. The reaction with diamine compounds could result in NIPUs based on lignin and tannin. The research on bio-based components for PU synthesis confirmed that they have good characteristics as an alternative for the petroleum-based adhesives. The advantages of improved strength, low curing temperatures, shorter pressing times, and isocyanate-free properties were demonstrated by lignin- and tannin-based NIPUs. The elimination of isocyanate, associated with environmental and human health hazards, NIPU synthesis, and its properties and applications, including wood adhesives, are reported comprehensively in this paper. The future perspectives of NIPUs’ production and application were also outlined.

scholarly journals Recent developments in voltammetric and amperometric sensors for cysteine detection

RSC Advances ◽  
2021 ◽  
Vol 11 (10) ◽  
pp. 5411-5425
Author(s):  
Somayeh Tajik ◽  
Zahra Dourandish ◽  
Peyman Mohammadzadeh Jahani ◽  
Iran Sheikhshoaie ◽  
Hadi Beitollahi ◽  
...  
Keyword(s):  
Review Article ◽  
Amperometric Sensors ◽  
Recent Advances ◽  
Recent Developments ◽  
Amperometric Sensing

This review article aims to provide an overview of the recent advances in the voltammetric and amperometric sensing of cysteine (Cys).

Rewiew of Fracture and Fatigue in Ceramic Matrix Composites

2000 ◽  
Vol 53 (6) ◽  
pp. 147-174 ◽  
Author(s):  
Victor Birman ◽  
Larry W. Byrd
Keyword(s):  
High Temperature ◽  
State Of The Art ◽  
Ceramic Matrix Composites ◽  
Ceramic Matrix ◽  
Review Article ◽  
Successful Implementation ◽  
Matrix Composites ◽  
Recent Developments ◽  
Hostile Environments

A review of recent developments and state-of-the-art in research and understanding of damage and fatigue of ceramic matrix composites is presented. Both laminated as well as woven configurations are considered. The work on the effects of high temperature on fracture and fatigue of ceramic matrix composites is emphasized, because these materials are usually designed to operate in hostile environments. Based on a detailed discussion of the mechanisms of failure, the problems that have to be addressed for a successful implementation of ceramic matrix composites in design and practical operational structures are outlined. This review article includes 317 references.

A Review on High Temperature Stable Anatase TiO2 Photocatalysts

2016 ◽  
Vol 855 ◽  
pp. 78-93 ◽  
Author(s):  
Pradeepan Periyat ◽  
Binu Naufal ◽  
Sanjay Gopal Ullattil
Keyword(s):  
High Temperature ◽  
Metal Ions ◽  
Photocatalytic Performance ◽  
Anatase Phase ◽  
Co Doping ◽  
Phase Stabilization ◽  
Antibacterial Coatings ◽  
Recent Developments ◽  
Self Cleaning

This review focuses on the recent developments of high temperature stable anatase TiO2 photocatalyst. Eventhough TiO2 exists in different forms anatase, rutile and brookite, anatase phase stabilization is often the key to obtain the highest photocatalytic performance for TiO2, particularly for the use as an antibacterial and self-cleaning coatings in high temperature processed ceramics. Different methods available for the anatase stabilization in literature are critically reviewed and emphasis is placed on relatively recent developments. Currently available methods of anatase stabilizations are classified in to four categories viz (i) doping with metal ions (ii) doping with non-metal ions (iii) co-doping with metal and non-metal ions and (iv) dopant free stabilization by oxygen richness. Further to this, the application of these high temperature stabilized anatase TiO2 photocatalyst on various ceramics substrates such as tile, glass and sanitary wares as self-cleaning and antibacterial coatings are also been briefly discussed.

Catalytic asymmetric umpolung reactions of imines via 2-azaallyl anion intermediates

2021 ◽  
Author(s):  
Yaseen Hussain ◽  
Pankaj Chauhan
Keyword(s):  
Review Article ◽  
Recent Developments ◽  
Catalytic Asymmetric

This review article describes all the significant recent developments in catalytic asymmetric umpolung reactions of imines involving a 2-azaallyl anion intermediate.

Triazole As Potent Anti-Cancer Agent- A Pharmacophoric Scaffold

2021 ◽  
Vol 17 ◽  
Author(s):  
Nidhi Kala ◽  
Kalpana Praveen Rahate
Keyword(s):  
Characteristic Feature ◽  
Biological Activities ◽  
Heterocyclic Ring ◽  
Ring System ◽  
Review Article ◽  
Current Review ◽  
Anti Cancer ◽  
Good Template ◽  
Cancer Agent

: Triazole is the main five-membered Nitrogen-containing basic heterocyclic ring system reported for their biological activities and compounds with multiple pharmacophores, which fetch together acquaintance of a target with sympathetic types of the molecule that might interact with the target. In addition, healthy, adaptable, and scalable chemistry must be employed to achieve the task. This characteristic feature of triazole would make a good template for a lead cohort library. The current review article focuses on recent advancements in triazole moiety as an anti-cancer agent with their mechanism pathways of synthesized analogues.

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