Adaptive chirality of achiral tetraphenylethene-based tetracationic cyclophanes with dual responses of fluorescence and circular dichroism in water

2021 ◽  
Author(s):  
Haiyang Zhang ◽  
Lin Cheng ◽  
Hao Nian ◽  
Jiang Du ◽  
Tao Chen ◽  
...  
Keyword(s):  
Circular Dichroism ◽  
Electrostatic Interactions ◽  
Fluorescence Enhancement ◽  
Hydrophobic Effects ◽  
Circular Dichroïsm

Tetraphenylethene-based tetracationic cyclophanes exhibited adaptive chirality with fluorescence enhancement or/and induced CD when combined with ATP and DNA via hydrophobic effects and electrostatic interactions in water.

scholarly journals Complexation of chiral amines by resorcin[4]arene sulfonic acids in polar media – circular dichroism and diffusion studies of chirality transfer and solvent dependence

2019 ◽  
Vol 15 ◽  
pp. 1913-1924 ◽  
Author(s):  
Bartosz Setner ◽  
Agnieszka Szumna
Keyword(s):  
Circular Dichroism ◽  
Self Assembly ◽  
Electrostatic Interactions ◽  
Chiral Amines ◽  
Chirality Transfer ◽  
Polar Environment ◽  
Solvent Dependence ◽  
First Choice ◽  
Polar Media ◽  
Circular Dichroïsm

Directional self‐assembly of conformationally well-defined complexes in polar environment is still a major challenge in supramolecular chemistry. In the present study we demonstrate that resorcin[4]arene sulfonic acid (RSA) interacts with chiral amines (amino acid derivatives and aminocavitands) to form inclusion complexes and capsules based on electrostatic interactions. The complexes were characterized by circular dichroism and DOSY NMR spectroscopy. Chirality transfer from amines onto a resorcinarene skeleton was manifested by the appearance of signals in CD spectra and diastereotopic splitting in NMR spectra. The complexes proved to be thermodynamically stable in methanol, but DMSO and methanol/water mixtures were found to be highly disintegrative for these complexes. This result is quite non-intuitive and worth attention in the context of formation of supramolecular complexes in polar environment, for which DMSO is most often a first-choice solvent.

Characterization of Tamm-Horsfall Urinary Glycoprotein

1973 ◽  
Vol 31 ◽  
pp. 420-421
Author(s):  
John P. Robinson ◽  
J. David Puett
Keyword(s):  
Electron Microscopy ◽  
Circular Dichroism ◽  
Secondary Structure ◽  
Quaternary Structure ◽  
Normal Adult ◽  
Morphological Properties ◽  
Adult Males ◽  
Circular Dichroïsm ◽  
Urinary Glycoprotein

Much work has been reported on the chemical, physical and morphological properties of urinary Tamm-Horsfall glycoprotein (THG). Although it was once reported that cystic fibrotic (CF) individuals had a defective THG, more recent data indicate that THG and CF-THG are similar if not identical.No studies on the conformational aspects have been reported on this glycoprotein using circular dichroism (CD). We examined the secondary structure of THG and derivatives under various conditions and have correlated these results with quaternary structure using electron microscopy.THG was prepared from normal adult males and CF-THG from a 16-year old CF female by the method of Tamm and Horsfall. CF female by the method of Tamm and Horsfall.

Circular dichroism spectra of adsorbed dye-aggregates

1968 ◽  
Vol 65 ◽  
pp. 146-151 ◽  
Author(s):  
G. Scheibe ◽  
O. Wörz ◽  
F. Haimerl ◽  
W. Seiffert ◽  
J. Winkler
Keyword(s):  
Circular Dichroism ◽  
Circular Dichroism Spectra ◽  
Circular Dichroïsm

ON THE THEORY OF THREE PHOTONIC LINEAR CIRCULAR DICHROISM IN A HOLE-CONDUCTION SEMICONDUCTOR

2020 ◽  
pp. 73-76
Author(s):  
V. R. Rasulov ◽  
R. Y. Rasulov ◽  
I. M. Eshboltaev ◽  
R. R. Sultonov ◽  
B. Z. Polvonov
Keyword(s):  
Circular Dichroism ◽  
Hole Conduction ◽  
Circular Dichroïsm

Fan-shaped mid-infrared chiral metamaterials based on indium tin oxide and their circular dichroism

2020 ◽  
Vol 13 (4) ◽  
pp. 722-727
Author(s):  
ZHU Ye-xin ◽  
◽  
◽  
LI Ya-nan ◽  
SHI Wei-jie ◽  
...  
Keyword(s):  
Circular Dichroism ◽  
Tin Oxide ◽  
Indium Tin Oxide ◽  
Mid Infrared ◽  
Chiral Metamaterials ◽  
Circular Dichroïsm
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