Tailoring the triplet level of isomorphic Eu/Tb mixed MOFs for sensitive temperature sensing

2021 ◽  
Author(s):  
Tifeng Xia ◽  
Zhengfeng Shao ◽  
Xiayan Yan ◽  
Meng Liu ◽  
Libing Yu ◽  
...  

Different thermo-responsive fluorescence thermometers were obtained by regulating the triplet energy level of organic ligands within isostructural Eu/Tb mixed MOFs.

2011 ◽  
Vol 17 (9) ◽  
pp. 2592-2596 ◽  
Author(s):  
Donghui Yu ◽  
Yongbiao Zhao ◽  
Hui Xu ◽  
Chunmiao Han ◽  
Dongge Ma ◽  
...  

2011 ◽  
Vol 47 (42) ◽  
pp. 11703 ◽  
Author(s):  
Cyril Poriel ◽  
Rémi Métivier ◽  
Joëlle Rault-Berthelot ◽  
Damien Thirion ◽  
Frédéric Barrière ◽  
...  

2020 ◽  
Vol 59 (8) ◽  
pp. 5447-5455 ◽  
Author(s):  
Jorge Manzur ◽  
Carolina Poblete ◽  
Jeannette Morales ◽  
Ricardo Costa de Santana ◽  
Lauro June Queiroz Maia ◽  
...  

1974 ◽  
Vol 52 (10) ◽  
pp. 1848-1857 ◽  
Author(s):  
Jacques Ronayette ◽  
René Arnaud ◽  
Philippe Lebourgeois ◽  
Jacques Lemaire

The photochemical isomerization of azobenzene can be sensitized by aromatic compounds (chrysene, phenanthrene, naphthalene) or by carbonyls (benzil, biacetyl). Comparison of the photostationary states and the initial quantum yields of isomerization leads to the deduction of a mechanism for this sensitization. The triplet levels Tβt and Tβc of the trans and cis forms are populated by diffusion-controlled, triplet–triplet energy transfer. These levels are deactivated nonradiatively without giving rise to isomerization. The Tβc level of the cis form undergoes a quantitative internal conversion to another triplet level Tαc, while the Tβt level of the trans form undergoes a nonradiative transition to the ground state. The internal conversion Tβt → Tαt in the trans isomer occurs with low probability (0.04 to 0.06). The levels Tαt and Tαc are the intermediates in the isomerization; they are deactivated to the two isomeric forms of azobenzene with equal probability. [Journal translation]


1994 ◽  
Vol 228 (4-5) ◽  
pp. 495-498 ◽  
Author(s):  
Chris Lambert ◽  
Robert W. Redmond

RSC Advances ◽  
2021 ◽  
Vol 11 (29) ◽  
pp. 17755-17759
Author(s):  
Kai Wang ◽  
Suqin Huang ◽  
Ping Ding ◽  
Zuoqin Liang ◽  
Shuoran Chen ◽  
...  

Soluble phthalocyanine palladium derivatives were synthesized and employed as sensitizers to achieve red-to-yellow/green upconversion, when doped with different annihilators.


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