Highly efficient thermally activated delayed fluorescence emitters enabled by double charge transfer pathways via ortho-linked triarylboron/carbazole hybrids

2021 ◽  
Author(s):  
Minting Ouyang ◽  
Longjiang Xing ◽  
Qiaodeng Chen ◽  
Hong Huang ◽  
Minrong Zhu ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Delayed Fluorescence ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
Highly Efficient ◽  
Double Charge

Two thermally activated delayed fluorescence emitters with double charge transfer pathways have been studied. Owing to the restricted ortho-linked D–A–D configuration, both emitters exhibited excellent luminescent performance.

scholarly journals Solution-Processed OLEDs Based on Thermally Activated Delayed Fluorescence Copper(I) Complexes with Intraligand Charge-Transfer Excited State

Molecules ◽  
2021 ◽  
Vol 26 (4) ◽  
pp. 1125
Author(s):  
Teng Teng ◽  
Jinfan Xiong ◽  
Gang Cheng ◽  
Changjiang Zhou ◽  
Xialei Lv ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Density Functional ◽  
Delayed Fluorescence ◽  
Quantum Yields ◽  
Functional Theory ◽  
Solution Processed ◽  
Thermally Activated Delayed Fluorescence ◽  
Light Emitting ◽  
Thermally Activated ◽  
Wide Range

A new series of tetrahedral heteroleptic copper(I) complexes exhibiting efficient thermally-activated delayed fluorescence (TADF) in green to orange electromagnetic spectral regions has been developed by using D-A type N^N ligand and P^P ligands. Their structures, electrochemical, photophysical, and electroluminescence properties have been characterized. The complexes exhibit high photoluminescence quantum yields (PLQYs) of up to 0.71 at room temperature in doped film and the lifetimes are in a wide range of 4.3–24.1 μs. Density functional theory (DFT) calculations on the complexes reveal the lowest-lying intraligand charge-transfer excited states that are localized on the N^N ligands. Solution-processed organic light emitting diodes (OLEDs) based on one of the new emitters show a maximum external quantum efficiency (EQE) of 7.96%.

Highly Efficient Near‐Infrared Electrofluorescence from a Thermally‐Activated Delayed Fluorescence Molecule

2021 ◽  
Author(s):  
Umamahesh Balijapalli ◽  
Ryo Nagata ◽  
Nishiki Yamada ◽  
Hajime Nakanotani ◽  
Masaki Tanaka ◽  
...  
Keyword(s):  
Near Infrared ◽  
Delayed Fluorescence ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
Highly Efficient

High efficient T-shape deep-red thermally activated delayed fluorescence emitter: substitution position effect

2021 ◽  
Author(s):  
Kai Zhang ◽  
Jianzhong Fan ◽  
Chuankui Wang ◽  
Lili Lin
Keyword(s):  
Charge Transfer ◽  
Position Effect ◽  
Luminescent Properties ◽  
Delayed Fluorescence ◽  
Molecular Structures ◽  
Transfer Property ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
High Efficient ◽  
The Relationship

Modulating the relationship between molecular structures and luminescent properties as well as the charge transfer property for deep-red thermally activated delayed fluorescence (TADF) emitters has always been a powerful challenge,...

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