scholarly journals Emerging piezochromism in lead free alkaline earth chalcogenide perovskite AZrS3 (A = Mg, Ca, Sr and Ba) under pressure

2020 ◽  
Vol 8 (46) ◽  
pp. 16392-16403
Author(s):  
Arnab Majumdar ◽  
Adebayo A. Adeleke ◽  
Sudip Chakraborty ◽  
Rajeev Ahuja
Keyword(s):  
Hydrostatic Pressure ◽  
Physical Properties ◽  
Crystal Structures ◽  
Alkaline Earth ◽  
Lead Free

Hydrostatic pressure is an effective tool that can give rise to novel crystal structures and physical properties.

WIELAND-BB5

Alloy Digest ◽  
2007 ◽  
Vol 56 (7) ◽  
Keyword(s):  
Corrosion Resistance ◽  
Physical Properties ◽  
Tensile Properties ◽  
Heat Treating ◽  
Spray Forming ◽  
Lead Free ◽  
Good Working

Abstract Wieland-BB5 is a lead-free phosphor bronze with good working properties. The alloy can be produced by spray forming. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties. It also includes information on corrosion resistance as well as forming, heat treating, and joining. Filing Code: CU-749. Producer or source: Wieland Metals Inc.

KAISER ALUMINUM ALLOY KA62

Alloy Digest ◽  
1999 ◽  
Vol 48 (10) ◽  
Keyword(s):  
Mechanical Properties ◽  
Corrosion Resistance ◽  
Shear Strength ◽  
Aluminum Alloy ◽  
Physical Properties ◽  
Surface Treatment ◽  
Physical And Mechanical Properties ◽  
Heat Treating ◽  
Lead Free ◽  
Kaiser Aluminum

Abstract Kaiser Aluminum alloy KA62 (Tennalum alloy KA62) is a lead-free alternative to 6262. It offers good machinability and corrosion resistance and displays good acceptance of coatings (anodize response). It can be used in place of 6262 because its physical and mechanical properties are equivalent to those of 6262 (see Alloy Digest Al-361, September 1999). This datasheet provides information on composition, physical properties, hardness, tensile properties, and shear strength. It also includes information on corrosion resistance as well as forming, heat treating, machining, and surface treatment. Filing Code: AL-362. Producer or source: Tennalum, A Division of Kaiser Aluminum.

MUELLER ALLOY C27451

Alloy Digest ◽  
2016 ◽  
Vol 65 (8) ◽  
Keyword(s):  
Physical Properties ◽  
Tensile Properties ◽  
Heat Treating ◽  
Lead Free ◽  
Machining Characteristics

Abstract Mueller Alloy C27451 has excellent machining characteristics for forged and machined applications required to meet AB1953. The alloy is an improvement over C27450 (See Alloy Digest Cu-820, June 2013) in that it is both lead-free and dezincification resistant. This datasheet provides information on composition, physical properties, hardness, and tensile properties. It also includes information on forming, heat treating, and machining. Filing Code: Cu-849. Producer or source: Mueller Brass Company.

WIELAND-SW1

Alloy Digest ◽  
2015 ◽  
Vol 64 (9) ◽  
Keyword(s):  
Corrosion Resistance ◽  
Physical Properties ◽  
Tensile Properties ◽  
Heat Treating ◽  
Lead Free ◽  
Made In

Abstract Wieland-SW1 is a lead-free special brass made in extruded and drawn products. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties as well as fatigue. It also includes information on corrosion resistance as well as forming, heat treating, and joining. Filing Code: Cu-841. Producer or source: Wieland Metals Inc. and Wieland-Werke AG.

scholarly journals Crystal-to-Crystal Transformation from K2[Co(C2O4)2(H2O)2]·4H2O to K2[Co(μ-C2O4)(C2O4)]

2021 ◽  
Vol 7 (6) ◽  
pp. 77
Author(s):  
Bin Zhang ◽  
Yan Zhang ◽  
Guangcai Chang ◽  
Zheming Wang ◽  
Daoben Zhu
Keyword(s):  
Hydrogen Bond ◽  
Physical Properties ◽  
Crystal Structures ◽  
Molecular Crystal ◽  
Trigonal Prism ◽  
Space Group ◽  
Cell Parameters ◽  
Oxalate Anion ◽  
Crystal Transformation ◽  
Antiferromagnetic Ordering

Crystal-to-crystal transformation is a path to obtain crystals with different crystal structures and physical properties. K2[Co(C2O4)2(H2O)2]·4H2O (1) is obtained from K2C2O4·2H2O, CoCl2·6H2O in H2O with a yield of 60%. It is crystallized in the triclinic with space group P1 and cell parameters: a = 7.684(1) Å, b = 9.011(1) Å, c = 10.874(1) Å, α = 72.151(2)°, β = 70.278(2)°, γ = 80.430(2)°, V = 670.0(1) Å3, Z = 2 at 100 K. 1 is composed of K+, mononuclear anion [Co(C2O4)2(H2O)22−] and H2O. Co2+ is coordinated by two bidentated oxalate anion and two H2O in an octahedron environment. There is a hydrogen bond between mononuclear anion [Co(C2O4)2(H2O)22−] and H2O. K2[Co(μ-C2O4)(C2O4)] (2) is obtained from 1 by dehydration. The cell parameters of 2 are a = 8.460(5) Å, b = 6.906 (4) Å, c = 14.657(8) Å, β = 93.11(1)°, V = 855.0(8) Å3 at 100 K, with space group in P2/c. It is composed of K+ and zigzag [Co(μ-C2O4)(C2O42−]n chain. Co2+ is coordinated by two bisbendentate oxalate and one bidentated oxalate anion in trigonal-prism. 1 is an antiferromagnetic molecular crystal. The antiferromagnetic ordering at 8.2 K is observed in 2.

scholarly journals Supramolecular Frameworks Based on Rhenium Clusters Using the Synthons Approach

Molecules ◽  
2021 ◽  
Vol 26 (9) ◽  
pp. 2662
Author(s):  
Nathalie Audebrand ◽  
Antoine Demont ◽  
Racha El Osta ◽  
Yuri V. Mironov ◽  
Nikolay G. Naumov ◽  
...  
Keyword(s):  
Aqueous Solutions ◽  
Crystal Structures ◽  
Ligand Exchange ◽  
Alkaline Earth ◽  
Room Temperature ◽  
Hydration Rate ◽  
Rhenium Cluster ◽  
New Compounds ◽  
Cluster Unit

The reaction of the K4[{Re6Si8}(OH)a6]·8H2O rhenium cluster salt with pyrazine (Pz) in aqueous solutions of alkaline or alkaline earth salts at 4 °C or at room temperature leads to apical ligand exchange and to the formation of five new compounds: [trans-{Re6Si8}(Pz)a2(OH)a2(H2O)a2] (1), [cis-{Re6Si8}(Pz)a2(OH)a2(H2O)a2] (2), (NO3)[cis-{Re6Si8}(Pz)a2(OH)a(H2O)a3](Pz)·3H2O (3), [Mg(H2O)6]0.5[cis-{Re6Si8}(Pz)a2(OH)a3(H2O)a]·8.5H2O (4), and K[cis-{Re6Si8}(Pz)a2(OH)a3(H2O)a]·8H2O (5). Their crystal structures are built up from trans- or cis-[{Re6Si8}(Pz)a2(OH)a4−x(H2O)ax]x−2 cluster units. The cohesions of the 3D supramolecular frameworks are based on stacking and H bonding, as well as on H3O2−bridges in the cases of (1), (2), (4), and (5) compounds, while (3) is built from stacking and H bonding only. This evidences that the nature of the synthons governing the cluster unit assembly is dependent on the hydration rate of the unit.

scholarly journals PHYSICAL PROPERTIES AND CRYSTAL STRUCTURES OF POLY (META, PARA-XYLYLENE ADIPAMIDE) COPOLYMER

1973 ◽  
Vol 29 (9) ◽  
pp. T392-T404
Author(s):  
Youichi Kawaguchi ◽  
Masayoshi Shimada ◽  
Fumihide Fujimoto
Keyword(s):  
Physical Properties ◽  
Crystal Structures

Syntheses, crystal structures and physical properties of three new chalcogenides: NaGaGe3Se8, K3Ga3Ge7S20, and K3Ga3Ge7Se20

2016 ◽  
Vol 45 (2) ◽  
pp. 532-538 ◽  
Author(s):  
Xiaoshuang Li ◽  
Chao Li ◽  
Pifu Gong ◽  
Zheshuai Lin ◽  
Jiyong Yao ◽  
...  
Keyword(s):  
Physical Properties ◽  
Crystal Structures ◽  
Layered Structure

NaGaGe3Se8 has a layered structure, while K3Ga3Ge7Q20 (Q = S, Se) are constructed by incompletely isolated quasi-2D layers, leading to large channels loosely occupied by K+ cations.

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