Quasi-2D perovskite emitters: a boon for efficient blue light-emitting diodes

2020 ◽  
Vol 8 (41) ◽  
pp. 14334-14347
Author(s):  
Gundam Sandeep Kumar ◽  
Ranadeep Raj Sumukam ◽  
Banavoth Murali

A deeper understanding of the quasi-2D perovskites crystal growth mechanism, orientation, phase purity, blocking halide ion migration and phase segregation can possibly open up a new paradigm for the development of high-performance blue PeLEDs.

Author(s):  
Necip Güven ◽  
Rodney W. Pease

Morphological features of montmorillonite aggregates in a large number of samples suggest that they may be formed by a dendritic crystal growth mechanism (i.e., tree-like growth by branching of a growth front).


RSC Advances ◽  
2015 ◽  
Vol 5 (6) ◽  
pp. 4707-4715 ◽  
Author(s):  
Qiwei Zhang ◽  
Haiqin Sun ◽  
Tao Kuang ◽  
Ruiguang Xing ◽  
Xihong Hao

Materials emitting red light (∼611 nm) under excitation with blue light (440–470 nm) are highly desired for fabricating high-performance white light-emitting diodes (LEDs).


2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Changjiu Sun ◽  
Yuanzhi Jiang ◽  
Minghuan Cui ◽  
Lu Qiao ◽  
Junli Wei ◽  
...  

AbstractSerious performance decline arose for perovskite light-emitting diodes (PeLEDs) once the active area was enlarged. Here we investigate the failure mechanism of the widespread active film fabrication method; and ascribe severe phase-segregation to be the reason. We thereby introduce L-Norvaline to construct a COO−-coordinated intermediate phase with low formation enthalpy. The new intermediate phase changes the crystallization pathway, thereby suppressing the phase-segregation. Accordingly, high-quality large-area quasi-2D films with desirable properties are obtained. Based on this, we further rationally adjusted films’ recombination kinetics. We reported a series of highly-efficient green quasi-2D PeLEDs with active areas of 9.0 cm2. The peak EQE of 16.4% is achieved in <n > = 3, represent the most efficient large-area PeLEDs yet. Meanwhile, high brightness device with luminance up to 9.1 × 104 cd m−2 has achieved in <n> = 10 film.


2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Fumiya Osawa ◽  
Kazuhiro Marumoto

Abstract Spin-states and charge-trappings in blue organic light-emitting diodes (OLEDs) are important issues for developing high-device-performance application such as full-color displays and white illumination. However, they have not yet been completely clarified because of the lack of a study from a microscopic viewpoint. Here, we report operando electron spin resonance (ESR) spectroscopy to investigate the spin-states and charge-trappings in organic semiconductor materials used for blue OLEDs such as a blue light-emitting material 1-bis(2-naphthyl)anthracene (ADN) using metal–insulator–semiconductor (MIS) diodes, hole or electron only devices, and blue OLEDs from the microscopic viewpoint. We have clarified spin-states of electrically accumulated holes and electrons and their charge-trappings in the MIS diodes at the molecular level by directly observing their electrically-induced ESR signals; the spin-states are well reproduced by density functional theory. In contrast to a green light-emitting material, the ADN radical anions largely accumulate in the film, which will cause the large degradation of the molecule and devices. The result will give deeper understanding of blue OLEDs and be useful for developing high-performance and durable devices.


2017 ◽  
Vol 5 (37) ◽  
pp. 9680-9686 ◽  
Author(s):  
Feng Peng ◽  
Na Li ◽  
Lei Ying ◽  
Wenkai Zhong ◽  
Ting Guo ◽  
...  

We developed a series of high-performance blue light-emitting polymers that contain hole-transport moieties comprising carbazole or triphenylamine substituents in the side chains of random copolymer poly(fluorene-co-dibenzothiophene-S,S-dioxide) (PFSO).


2009 ◽  
Vol 469 (15-20) ◽  
pp. 1414-1417 ◽  
Author(s):  
S. Funaki ◽  
Y. Yoshida ◽  
Y. Ichino ◽  
Y. Takai ◽  
A. Ichinose ◽  
...  

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