Significantly enhanced energy storage performance of flexible composites using sodium bismuth titanate based lead-free fillers

2020 ◽  
Vol 8 (42) ◽  
pp. 14910-14918
Author(s):  
Pingan Yang ◽  
Lili Li ◽  
Hongbin Yuan ◽  
Fei Wen ◽  
Peng Zheng ◽  
...  
Keyword(s):  
Energy Storage ◽  
Energy Density ◽  
Bismuth Titanate ◽  
High Energy ◽  
High Energy Density ◽  
Lead Free ◽  
Sodium Bismuth Titanate ◽  
Flexible Composites ◽  
Storage Performance

A new lead-free antiferroelectric ceramic NBT–SBT was introduced into PVDF polymer to fabricate composites films, achieving record-high energy density of 15.3 J cm−3 at 500 MV m−1 and meeting the requirement of miniaturization and lightweight device.

scholarly journals Development on Thermochemical Energy Storage Based on CaO-Based Materials: A Review

2018 ◽  
Vol 10 (8) ◽  
pp. 2660 ◽  
Author(s):  
Yi Yuan ◽  
Yingjie Li ◽  
Jianli Zhao
Keyword(s):  
Renewable Energy ◽  
Energy Storage ◽  
Energy Density ◽  
Circulating Fluidized Bed ◽  
High Energy ◽  
High Energy Density ◽  
Hydration Reaction ◽  
Initial Sample ◽  
Storage Performance ◽  
Low Activity

The intermittent and inconsistent nature of some renewable energy, such as solar and wind, means the corresponding plants are unable to operate continuously. Thermochemical energy storage (TES) is an essential way to solve this problem. Due to the advantages of cheap price, high energy density, and ease to scaling, CaO-based material is thought as one of the most promising storage mediums for TES. In this paper, TES based on various cycles, such as CaO/CaCO3 cycles, CaO/Ca(OH)2 cycles, and coupling of CaO/Ca(OH)2 and CaO/CaCO3 cycles, were reviewed. The energy storage performances of CaO-based materials, as well as the modification approaches to improve their performance, were critically reviewed. The natural CaO-based materials for CaO/Ca(OH)2 TES experienced the multiple hydration/dehydration cycles tend to suffer from severe sintering which leads to the low activity and structural stability. It is found that higher dehydration temperature, lower initial sample temperature of the hydration reaction, higher vapor pressure in the hydration reactor, and the use of circulating fluidized bed (CFB) reactors all can improve the energy storage performance of CaO-based materials. In addition, the energy storage performance of CaO-based materials for CaO/Ca(OH)2 TES can be effectively improved by the various modification methods. The additions of Al2O3, Na2Si3O7, and nanoparticles of nano-SiO2 can improve the structural stabilities of CaO-based materials, while the addition of LiOH can improve the reactivities of CaO-based materials. This paper is devoted to a critical review on the development on thermochemical energy storage based on CaO-based materials in the recent years.

scholarly journals Strategies to Improve the Energy Storage Properties of Perovskite Lead-Free Relaxor Ferroelectrics: A Review

Materials ◽  
2020 ◽  
Vol 13 (24) ◽  
pp. 5742
Author(s):  
Vignaswaran Veerapandiyan ◽  
Federica Benes ◽  
Theresa Gindel ◽  
Marco Deluca
Keyword(s):  
Energy Storage ◽  
Energy Density ◽  
Electrical Energy ◽  
High Energy ◽  
Relaxor Ferroelectrics ◽  
High Energy Density ◽  
Lead Free ◽  
Chemical Additives ◽  
Energy Storage Properties ◽  
Novel Processing

Electrical energy storage systems (EESSs) with high energy density and power density are essential for the effective miniaturization of future electronic devices. Among different EESSs available in the market, dielectric capacitors relying on swift electronic and ionic polarization-based mechanisms to store and deliver energy already demonstrate high power densities. However, different intrinsic and extrinsic contributions to energy dissipations prevent ceramic-based dielectric capacitors from reaching high recoverable energy density levels. Interestingly, relaxor ferroelectric-based dielectric capacitors, because of their low remnant polarization, show relatively high energy density and thus display great potential for applications requiring high energy density properties. In this study, some of the main strategies to improve the energy density properties of perovskite lead-free relaxor systems are reviewed, including (i) chemical modification at different crystallographic sites, (ii) chemical additives that do not target lattice sites, and (iii) novel processing approaches dedicated to bulk ceramics, thick and thin films, respectively. Recent advancements are summarized concerning the search for relaxor materials with superior energy density properties and the appropriate choice of both composition and processing routes to match various applications’ needs. Finally, future trends in computationally-aided materials design are presented.

Energy storage performance of ferroelectric ZrO2 film capacitors: effect of HfO2:Al2O3 dielectric insert layer

2020 ◽  
Vol 8 (28) ◽  
pp. 14171-14177
Author(s):  
J. P. B. Silva ◽  
J. M. B. Silva ◽  
K. C. Sekhar ◽  
H. Palneedi ◽  
M. C. Istrate ◽  
...  
Keyword(s):  
Energy Storage ◽  
Energy Density ◽  
High Energy ◽  
High Energy Density ◽  
Zro2 Film ◽  
Storage Performance

High energy density of 54.3 J cm−3 with an efficiency of 51.3% was obtained for the ZrO2 film capacitors with 2 nm-thick HAO insert layer.

High-performance quasi-solid-state asymmetric supercapacitors based on BiMn2O5 nanoparticles and redox-additive electrolytes

2019 ◽  
Vol 6 (8) ◽  
pp. 2061-2070 ◽  
Author(s):  
Jai Bhagwan ◽  
Bhimanaboina Ramulu ◽  
Jae Su Yu
Keyword(s):  
Energy Storage ◽  
Solid State ◽  
Energy Density ◽  
High Performance ◽  
High Energy ◽  
High Energy Density ◽  
Asymmetric Supercapacitors ◽  
Storage Performance

The investigation of nanomaterials with improved energy storage performance is essential in the development of high energy density supercapacitors.

Lead-free BaTiO3–Bi(Zn2/3Nb1/3)O3 weakly coupled relaxor ferroelectric materials for energy storage

RSC Advances ◽  
2016 ◽  
Vol 6 (17) ◽  
pp. 14273-14282 ◽  
Author(s):  
Longwen Wu ◽  
Xiaohui Wang ◽  
Longtu Li
Keyword(s):  
Energy Efficiency ◽  
Energy Storage ◽  
Energy Density ◽  
High Energy ◽  
Ferroelectric Materials ◽  
Relaxor Ferroelectric ◽  
High Energy Density ◽  
Lead Free ◽  
Weakly Coupled ◽  
High Energy Efficiency

High energy density BaTiO3–Bi(Zn2/3Nb1/3)O3 materials with concurrently high energy efficiency.

scholarly journals Perspectives and challenges for lead-free energy-storage multilayer ceramic capacitors

2021 ◽  
Vol 10 (6) ◽  
pp. 1153-1193
Author(s):  
Peiyao Zhao ◽  
Ziming Cai ◽  
Longwen Wu ◽  
Chaoqiong Zhu ◽  
Longtu Li ◽  
...  
Keyword(s):  
Free Energy ◽  
High Temperature ◽  
Energy Storage ◽  
Energy Density ◽  
State Of The Art ◽  
High Energy ◽  
High Energy Density ◽  
Lead Free ◽  
Multilayer Ceramic Capacitors ◽  
Multilayer Ceramic

AbstractThe growing demand for high-power-density electric and electronic systems has encouraged the development of energy-storage capacitors with attributes such as high energy density, high capacitance density, high voltage and frequency, low weight, high-temperature operability, and environmental friendliness. Compared with their electrolytic and film counterparts, energy-storage multilayer ceramic capacitors (MLCCs) stand out for their extremely low equivalent series resistance and equivalent series inductance, high current handling capability, and high-temperature stability. These characteristics are important for applications including fast-switching third-generation wide-bandgap semiconductors in electric vehicles, 5G base stations, clean energy generation, and smart grids. There have been numerous reports on state-of-the-art MLCC energy-storage solutions. However, lead-free capacitors generally have a low-energy density, and high-energy density capacitors frequently contain lead, which is a key issue that hinders their broad application. In this review, we present perspectives and challenges for lead-free energy-storage MLCCs. Initially, the energy-storage mechanism and device characterization are introduced; then, dielectric ceramics for energy-storage applications with aspects of composition and structural optimization are summarized. Progress on state-of-the-art energy-storage MLCCs is discussed after elaboration of the fabrication process and structural design of the electrode. Emerging applications of energy-storage MLCCs are then discussed in terms of advanced pulsed power sources and high-density power converters from a theoretical and technological point of view. Finally, the challenges and future prospects for industrialization of lab-scale lead-free energy-storage MLCCs are discussed.

Achieved High Energy Density and Excellent Thermal Stability in (1-x)(Bi0.5Na0.5)0.94Ba0.06TiO3-xBi(Mg0.5Ti0.5)O3 Relaxor Ferroelectric Thin Films

2021 ◽  
Author(s):  
Hao Yan ◽  
Baijie Song ◽  
Kun Zhu ◽  
Liuxue Xu ◽  
Bo Shen ◽  
...  
Keyword(s):  
Thin Film ◽  
Thin Films ◽  
Energy Storage ◽  
Energy Density ◽  
High Energy ◽  
High Energy Density ◽  
Lead Free ◽  
Relaxor Behavior ◽  
Moderate Amount ◽  
Excellent Thermal Stability

Abstract In this work, lead-free (1-x)(Bi0.5Na0.5)0.94Ba0.06TiO3-xBi(Mg0.5Ti0.5)O3 (abbreviated as BNBT-xBMT, x = 0.3, 0.4, 0.5 and 0.6) thin films were prepared on Pt/Ti/SiO2/Si substrates using sol-gel method. The microstructures, dielectric and energy storage properties were investigated. The results showed that the addition of BMT disrupted the long-range ferroelectric order and enhanced the relaxor behavior of BNBT-xBMT thin films. In addition, the leakage current density of thin films was also reduced by the doping of moderate amount of BMT. A high recoverable energy density of 34.36 J/cm3 with an efficiency of 56.63% was achieved in the BNBT-0.5BMT thin film under the electric field of 2149 kV/cm. Furthermore, BNBT-0.5BMT thin film exhibited superior stability in the temperature range of 30°C − 145°C and frequency range of 500 Hz − 5 kHz, as well as long-term fatigue durability after 1 × 105 cycles. These results suggest that BNBT-0.5BMT thin film may be a promising material for lead-free dielectric energy storage applications.

scholarly journals Improved Energy Storage Performance of Linear Dielectric Polymer Nanodielectrics with Polydopamine coated BN Nanosheets

Polymers ◽  
2018 ◽  
Vol 10 (12) ◽  
pp. 1349 ◽  
Author(s):  
Jian Wang ◽  
Yunchuan Xie ◽  
Jingjing Liu ◽  
Zhicheng Zhang ◽  
Qiang Zhuang ◽  
...  
Keyword(s):  
Energy Storage ◽  
Energy Density ◽  
Surface Coating ◽  
Breakdown Strength ◽  
High Energy ◽  
Low Energy ◽  
High Energy Density ◽  
Storage Performance ◽  
2D Structure ◽  
Dielectric Polymer

Polymer-based nanodielectrics have been intensively investigated for their potential application as energy storage capacitors. However, their relatively low energy density (Ue) and discharging efficiency (η) may greatly limit their practical usage. In present work, high insulating two-dimensional boron nitride nanosheets (BNNS), were introduced into a linear dielectric polymer (P(VDF-TrFE-CTFE)-g-PMMA) matrix to enhance the energy storage performance of the composite. Thanks to the surface coating of polydopamine (PDA) on BN nanosheets, the composite filled with 6 wt% coated BNNS (mBNNS) exhibits significantly improved breakdown strength (Eb) of 540 MV/m and an energy density (Ue) of 11 J/cm3, which are increased by 23% and 100%, respectively as compared with the composite filled with the same content of pristine BNNS. Meanwhile, η of both composites is well retained at around 70% even under a high voltage of 400 MV/m, which is superior to most of the reported composites. This work suggests that complexing polymer matrix with linear dielectric properties with surface coated BNNS fillers with high insulating 2D structure might be a facile strategy to achieve composite dielectrics with simultaneously high energy density and high discharging efficiency.

Enhanced antiferroelectric phase stability in La-doped AgNbO3: perspectives from the microstructure to energy storage properties

2019 ◽  
Vol 7 (5) ◽  
pp. 2225-2232 ◽  
Author(s):  
Jing Gao ◽  
Yichi Zhang ◽  
Lei Zhao ◽  
Kai-Yang Lee ◽  
Qing Liu ◽  
...  
Keyword(s):  
Energy Storage ◽  
Energy Density ◽  
Phase Stability ◽  
High Energy ◽  
High Energy Density ◽  
Lead Free ◽  
Antiferroelectric Phase ◽  
Energy Storage Properties ◽  
La Doped ◽  
Storage Properties

High energy density was achieved in lead-free La-doped AgNbO3 antiferroelectric ceramics.

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