scholarly journals α-DTC70 fullerene performs significantly better than β-DTC70 as electron transporting material in perovskite solar cells

2020 ◽  
Vol 8 (20) ◽  
pp. 6813-6819 ◽  
Author(s):  
Edison Castro ◽  
Olivia Fernandez-Delgado ◽  
Albert Artigas ◽  
Gerardo Zavala ◽  
Fang Liu ◽  
...  

In this work, two new C70 isomers α and β bis(2-(thiophen-2-yl)ethyl)-C70-fullerene mono-adducts (DTC70) were synthesized, characterized and used as electron transporting materials (ETMs) in perovskite solar cells (PSCs).

2018 ◽  
Vol 08 (02) ◽  
pp. 1850009
Author(s):  
Enqi Wang ◽  
Peng Chen ◽  
Xingtian Yin ◽  
Bowen Gao ◽  
Wenxiu Que

It is well known that electron transport layer (ETL) plays an indispensable role in the planar heterojunction perovskite solar cells (PSCs). TiO2 is widely used as an ETL material due to its excellent transport properties, however, the presence of defects in the TiO2 layer diminishes the power conversion efficiency (PCE) of the devices. Herein, we introduce a method of low-temperature TiCl4 treatment to deposit a TiOx layer on the surface of TiO2 film, which can effectively passivate trap states at the TiO2 surface. Moreover, the treating process is optimized to be 30[Formula: see text]min using a 40[Formula: see text]mM TiCl4 aqueous solution. Benefiting from this, we obtain the champion device with the highest PCE of 18.47%, which is mainly due to the reduction of surface defects and the deposition of the well-crystallized perovskite films. Besides, the modified PSCs exhibit an average PCE of 17.59%, which is much better than the control devices.


2020 ◽  
Vol 4 (1) ◽  
pp. 324-330 ◽  
Author(s):  
Muhammad Sohail Abbas ◽  
Sabir Hussain ◽  
Jinaqi Zhang ◽  
Boxin Wang ◽  
Chen Yang ◽  
...  

A 2D–3D perovskite, in which 3D perovskite phase is bridged by 2D perovskite having periodically repeated vertical orientation is reported. It's PCE and stability is better than 3D MAPbI3 and it is an excellent structural strategy to improve stability of perovskite solar cells.


RSC Advances ◽  
2020 ◽  
Vol 10 (59) ◽  
pp. 35898-35905
Author(s):  
Chun-Hsiao Kuan ◽  
Po-Tsun Kuo ◽  
Cheng-Hung Hou ◽  
Jing-Jong Shyue ◽  
Ching-Fuh Lin

The growth process control (GPC) method, a new method which is better than thermal evaporation, for producing high-crystallinity perovskites by controlling the growth time in a low vacuum, is explored in this work.


2020 ◽  
Vol 15 (1) ◽  
Author(s):  
Xi Zhang ◽  
Wenyao Yang ◽  
Jingjing Qi ◽  
Yinggang Hu

Abstract Although the power conversion efficiency (PCE) of perovskite solar cells (PSCs) increases rapidly, there are still some issues that limit their commercialization. The perovskite is sensitive to the water molecules, increasing the difficulty in the preparation of perovskite films in ambient condition. Most high-performance PSCs based on conventional method are required to be prepared in inert atmosphere condition, which increase the fabrication cost. To fabricate the high-quality perovskite in ambient condition, we preheated the substrates and selected the proper anti-solvent. As a result, the target perovskite films show a better crystallinity compared with perovskite film prepared via the conventional one-step deposition method in ambient condition. The PSCs prepared in ambient condition yield the improved PCE of 16.89% from a PCE of 11.59%. Compared with the reference devices, the performance stability of target PSCs is much better than that of reference PSCs.


Nanoscale ◽  
2019 ◽  
Vol 11 (45) ◽  
pp. 21824-21833 ◽  
Author(s):  
Jyoti V. Patil ◽  
Sawanta S. Mali ◽  
Chang Kook Hong

Controlling the grain size of the organic–inorganic perovskite thin films using thiourea additives now crossing 2 μm size with >20% power conversion efficiency.


Author(s):  
Lucas Scalon ◽  
Francineide Lopes de Araújo ◽  
Caio Costa Oliveira ◽  
Ana Flávia Nogueira

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