scholarly journals High performance conjugated terpolymers as electron donors in nonfullerene organic solar cells

2020 ◽  
Vol 8 (38) ◽  
pp. 13422-13429
Author(s):  
Sri Harish Kumar Paleti ◽  
Nicola Gasparini ◽  
Christos L. Chochos ◽  
Derya Baran

Three pi-conjugated terpolymers based on the nonconventional molecular design strategy D1–D2–D1–A comprising two different multi-fused ladder-type arene electron-donating units and an electron-withdrawing unit are synthesized for organic photovoltaics.

2021 ◽  
Author(s):  
Lin Lin ◽  
Zeping Huang ◽  
Yuanqi Luo ◽  
Tingen Peng ◽  
Baitian He ◽  
...  

The synthesis and application as a cathode interlayer in organic photovoltaics of a fluorene derivative with pyridyl functional chains are presented.


2021 ◽  
Author(s):  
Junzhen Ren ◽  
Pengqing Bi ◽  
Jianqi Zhang ◽  
Jiao Liu ◽  
Jingwen Wang ◽  
...  

Abstract Developing photovoltaic materials with simple chemical structures and easy synthesis still remains a major challenge in the industrialization process of organic solar cells (OSCs). Herein, an ester substituted poly(thiophene vinylene) derivative, PTVT-T, was designed and synthesized in very few steps by adopting commercially available raw materials. The ester groups on the thiophene units enable PTVT-T to have a planar and stable conformation. Moreover, PTVT-T presents a wide absorption band and strong aggregation effect in solution, which are the key characteristics needed to realize high performance in non-fullerene-acceptor (NFA)-based OSCs. We then prepared OSCs by blending PTVT-T with three representative fullerene- and NF-based acceptors, PC71BM, IT-4F and BTP-eC9. It was found that PTVT-T can work well with all the acceptors, showing great potential to match new emerging NFAs. Particularly, a remarkable power conversion efficiency of 16.20% is achieved in a PTVT-T:BTP-eC9-based device, which is the highest value among the counterparts based on PTV derivatives. This work demonstrates that PTVT-T shows great potential for the future commercialization of OSCs.


2015 ◽  
Vol 51 (77) ◽  
pp. 14439-14442 ◽  
Author(s):  
Song Chen ◽  
Liangang Xiao ◽  
Xunjin Zhu ◽  
Xiaobing Peng ◽  
Wai-Kwok Wong ◽  
...  

A series of new A–D–A structural 5,15-dialkylated porphyrin-cored small molecules have been developed as donors in bulk heterojunction organic solar cells, and the highest power conversion efficiency of 6.49% has been achieved.


Author(s):  
Ya-Nan Chen ◽  
Rui Zheng ◽  
Jing Wang ◽  
Hang Wang ◽  
Miao Li ◽  
...  

The side chain engineering of the photoactive materials is one of the most commonly used molecular design strategies for developing high performance organic solar cells (OSCs). Herein, two alkyl (or...


2019 ◽  
Vol 48 (6) ◽  
pp. 1596-1625 ◽  
Author(s):  
Andrew Wadsworth ◽  
Maximilian Moser ◽  
Adam Marks ◽  
Mark S. Little ◽  
Nicola Gasparini ◽  
...  

A critical analysis of the molecular design strategies employed in the recent progress of non-fullerene electron acceptors for organic photovoltaics.


2020 ◽  
Vol 4 (6) ◽  
pp. 2680-2685 ◽  
Author(s):  
Tongle Xu ◽  
Yuying Chang ◽  
Cenqi Yan ◽  
Qianguang Yang ◽  
Zhipeng Kan ◽  
...  

Two oligothiophenes were synthesized and used as electron donors in organic solar cells. The devices with a fluorinated donor (2FDC5T) achieved power conversion efficiencies of up to ca. 9.02% (vs. ca. 7.03% for the non-halogenated donor DC5T).


2018 ◽  
Vol 28 (7) ◽  
pp. 1870042
Author(s):  
Jong-Hong Lu ◽  
Yi-Hung Lin ◽  
Bing-Huang Jiang ◽  
Chun-Hung Yeh ◽  
Jui-Chih Kao ◽  
...  

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