Solid-state crystal growth of lead-free ferroelectrics

2020 ◽  
Vol 8 (23) ◽  
pp. 7606-7649 ◽  
Author(s):  
Peter Kabakov ◽  
Christopher Dean ◽  
Valsala Kurusingal ◽  
Zhenxiang Cheng ◽  
Ho-Yong Lee ◽  
...  
Keyword(s):  
Crystal Growth ◽  
Solid State ◽  
Single Crystals ◽  
Review Article ◽  
Lead Free

Review article of the solid-state crystal growth (SSCG) technique and the progress of lead-free ferroelectric single crystals for piezoelectric applications.

scholarly journals Large piezoelectric properties in KNN-based lead-free single crystals grown by a seed-free solid-state crystal growth method

2016 ◽  
Vol 108 (18) ◽  
pp. 182904 ◽  
Author(s):  
Jie Yang ◽  
Faqiang Zhang ◽  
Qunbao Yang ◽  
Zhifu Liu ◽  
Yongxiang Li ◽  
...  
Keyword(s):  
Crystal Growth ◽  
Solid State ◽  
Single Crystals ◽  
Piezoelectric Properties ◽  
Lead Free ◽  
Growth Method

scholarly journals Growth of single crystals in the (Na1/2Bi1/2)TiO3–(Sr1–xCax)TiO3 system by solid state crystal growth

2021 ◽  
Author(s):  
Phan Gia Le ◽  
Huyen Tran Tran ◽  
Jong-Sook Lee ◽  
John G. Fisher ◽  
Hwang-Pill Kim ◽  
...  
Keyword(s):  
Crystal Growth ◽  
Solid State ◽  
Single Crystal ◽  
Single Crystals ◽  
Piezoelectric Properties ◽  
Single Crystal Growth ◽  
Crystal Growth Rate ◽  
Large Strains ◽  
Growth Technique ◽  
The Matrix

AbstractCeramics based on (Na1/2B1/2)TiO3 are promising candidates for actuator applications because of large strains generated by an electric field-induced phase transition. For example, the (1−x)(Na1/2Bi1/2)TiO3-xSrTiO3 system exhibits a morphotropic phase boundary at x = 0.2–0.3, leading to high values of inverse piezoelectric constant d*33, which can be further improved by the use of single crystals. In our previous work, single crystals of (Na1/2B1/2)TiO3-SrTiO3 and (Na1/2B1/2)TiO3-CaTiO3 were grown by the solid state crystal growth technique. Growth in the (Na1/2B1/2)TiO3-SrTiO3 system was sluggish whereas the (Na1/2B1/2)TiO3-CaTiO3 single crystals grew well. In the present work, 0.8(Na1/2Bi1/2)TiO3-0.2(Sr1−xCax)TiO3 single crystals (with x = 0.0, 0.1, 0.2, 0.3, 0.4) were produced by the solid state crystal growth technique in an attempt to improve crystal growth rate. The dependence of mean matrix grain size, single crystal growth distance, and electrical properties on the Ca concentration was investigated in detail. These investigations indicated that at x = 0.3 the matrix grain growth was suppressed and the driving force for single crystal growth was enhanced. Replacing Sr with Ca increased the shoulder temperature Ts and temperature of maximum relative permittivity Tmax, causing a decrease in inverse piezoelectric properties and a change from normal to incipient ferroelectric behavior.

Seed-Free Solid-State Growth of Large Lead-Free Piezoelectric Single Crystals: (Na1/2K1/2)NbO3

2015 ◽  
Vol 98 (10) ◽  
pp. 2988-2996 ◽  
Author(s):  
Minhong Jiang ◽  
Clive A. Randall ◽  
Hanzheng Guo ◽  
Guanghui Rao ◽  
Rong Tu ◽  
...  
Keyword(s):  
Solid State ◽  
Single Crystals ◽  
Lead Free ◽  
State Growth

scholarly journals Precursor Phenomena of Barium Titanate Single Crystals Grown Using a Solid-State Single Crystal Growth Method Studied with Inelastic Brillouin Light Scattering and Birefringence Measurements

Molecules ◽  
2018 ◽  
Vol 23 (12) ◽  
pp. 3171 ◽  
Author(s):  
Soo Han Oh ◽  
Jae-Hyeon Ko ◽  
Ho-Yong Lee ◽  
Iwona Lazar ◽  
Krystian Roleder
Keyword(s):  
Crystal Growth ◽  
Solid State ◽  
Barium Titanate ◽  
Single Crystal ◽  
Single Crystals ◽  
Melting Process ◽  
Point Of View ◽  
Crystal Quality ◽  
Cubic Phase ◽  
Growth Method

The nature of precursor phenomena in the paraelectric phase of ferroelectrics is one of the main questions to be resolved from a fundamental point of view. Barium titanate (BaTiO3) is one of the most representative perovskite-structured ferroelectrics intensively studied until now. The pretransitional behavior of BaTiO3 single crystal grown using a solid-state crystal growth (SSCG) method was investigated for the first time and compared to previous results. There is no melting process in the SSCG method, thus the crystal grown using a SSCG method have inherent higher levels of impurity and defect concentrations, which is a good candidate for investigating the effect of crystal quality on the precursor phenomena. The acoustic, dielectric, and piezoelectric properties, as well as birefringence, of the SSCG-grown BaTiO3 were examined over a wide temperature range. Especially, the acoustic phonon behavior was investigated in terms of Brillouin spectroscopy, which is a complementary technique to Raman spectroscopy. The obtained precursor anomalies of the SSCG-grown BaTiO3 in the cubic phase were similar to those of other single crystals, in particular, of high-quality single crystal grown by top-seeded solution growth method. These results clearly indicate that the observed precursor phenomena are common and intrinsic effect irrespective of the crystal quality.

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