Design and development of HMS@ZIF-8/fluorinated polybenzoxazole composite films with excellent low-k performance, mechanical properties and thermal stability

2020 ◽  
Vol 8 (22) ◽  
pp. 7476-7484 ◽  
Author(s):  
Xudong Zhou ◽  
Xiaoyun Liu ◽  
Zhongkai Cui ◽  
Jinlou Gu ◽  
Shaoliang Lin ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Thermal Stability ◽  
Composite Film ◽  
Composite Films ◽  
Design And Development ◽  
Hollow Silica ◽  
New Type ◽  
Low K

A new-type of hollow silica@ZIF-8 (HMS@ZIF-8) particle was successfully designed, fabricated and introduced into the fluorinated polybenzoxazole (6FPBO) matrix to prepare the HMS@ZIF-8/6FPBO composite film.

Fabrication of Composite Films Based on Chitosan and Vegetable-Tanned Collagen Fibers Crosslinked with Genipin

2021 ◽  
Vol 116 (10) ◽  
Author(s):  
Jie Liu ◽  
Yanchun Liu ◽  
Eleanor M. Brown ◽  
Zhengxin Ma ◽  
Cheng-Kung Liu
Keyword(s):  
Mechanical Properties ◽  
Thermal Stability ◽  
Water Vapor ◽  
Composite Film ◽  
Composite Films ◽  
Value Added ◽  
Water Vapor Permeability ◽  
Vapor Permeability ◽  
Leather Industry ◽  
Compact Structure

The leather industry generates considerable amounts of solid waste and raises many environmental concerns during its disposal. The presence of collagen in these wastes provides a potential protein source for the fabrication of bio-based value-added products. Herein, a novel composite film was fabricated by incorporating vegetable-tanned collagen fiber (VCF), a mechanically ground powder-like leather waste, into a chitosan matrix and crosslinked with genipin. The obtained composite film showed a compact structure and the hydrogen bonding interactions were confirmed by FTIR analysis, indicating a good compatibility between chitosan and VCF. The optical properties, water absorption capacity, thermal stability, water vapor permeability and mechanical properties of the composite films were characterized. The incorporation of VCF into chitosan led to significant decreases in opacity and solubility of the films. At the same time, the mechanical properties, water vapor permeability and thermal stability of the films were improved. The composite film exhibited antibacterial activity against food-borne pathogens. Results from this research indicated the potential of the genipin-crosslinked chitosan/VCF composites for applications in antimicrobial packaging. 

scholarly journals The Effects of Coupling Agents on the Properties of Polyimide/Nano-Al2O3Three-Layer Hybrid Films

2010 ◽  
Vol 2010 ◽  
pp. 1-5 ◽  
Author(s):  
Lizhu Liu ◽  
Ling Weng ◽  
Yuxia Song ◽  
Lin Gao ◽  
Qingquan Lei
Keyword(s):  
Mechanical Properties ◽  
Thermal Stability ◽  
Tensile Strength ◽  
Composite Film ◽  
Breakdown Strength ◽  
Composite Films ◽  
Coupling Agents ◽  
Hybrid Films ◽  
Mechanical Method ◽  
Elongation At Break

PI/nano-Al2O3hybrid films were prepared by ultrasonic-mechanical method. Before addition, nano-Al2O3particles were firstly modified with different coupling agents. The micromorphology, thermal stability, mechanical properties, and electric breakdown strength of hybrid films were characterized and investigated. Results indicated that nano-Al2O3particles were homogeneously dispersed in the PI matrix by the addition of coupling agents. The thermal stability and mechanical properties of PI/nano-Al2O3composite films with KH550 were the best. The tensile strength and elongation at break of PI composite film were 119.1 MPa and 19.1%, which were 14.2% and 78.5% higher than unmodified PI composite film, respectively.

The Nanostructure and Properties of the Nano TiO2/PVA Composite Film

2013 ◽  
Vol 320 ◽  
pp. 611-614
Author(s):  
Wei Hong ◽  
Qing Shan Li ◽  
Jing Sun ◽  
Xin Chun Wang ◽  
Guo Wei Wang ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Thermal Stability ◽  
Optical Properties ◽  
Infrared Spectroscopy ◽  
Polyvinyl Alcohol ◽  
Composite Film ◽  
Composite Films ◽  
Solution Casting ◽  
Uv Shielding

In order to improve the performance of polyvinyl alcohol (PVA), the nanometer TiO2/PVA composite film prepared by solution casting, effects of nanotitanium dioxide (TiO2) PVA film. The structures, mechanical properties, and optical properties of the composite films were detected by infrared spectroscopy, TG, DSC, XRD. The results show that: nanoTiO2 fill added to the PVA matrix to improve the mechanical properties of PVA, thermal stability and UV shielding performance.

Expanded vermiculite-filled flexible polymer composites

2021 ◽  
pp. 009524432110290
Author(s):  
Mukaddes Sevval Cetin ◽  
Ozan Toprakci ◽  
Omer Suat Taskin ◽  
Abdullah Aksu ◽  
Hatice Aylin Karahan Toprakci
Keyword(s):  
Mechanical Properties ◽  
Thermal Stability ◽  
Contact Angle ◽  
Polymer Composites ◽  
Flame Retardancy ◽  
Composite Films ◽  
Filler Concentration ◽  
High Shear ◽  
Flexible Polymer ◽  
Shear Mixing

This study focuses on the fabrication and characterization of vermiculite-filled flexible polymer composites. Exfoliated vermiculite was incorporated into triblock thermoplastic elastomer copolymer, styrene- b-(ethylene- co-butylene)- b-styrene (SEBS), at various levels from 1 to 15 wt% by a high shear mixer. The composite films were obtained by the combination of solvent casting and compression molding. The morphological, structural, thermal, and mechanical properties and contact angle of the composites were determined. Some micro-morphological differences were observed between the samples and the difference was assumed to be caused by high shear mixing and filler concentration. High shear mixing was found effective in terms of the detachment of vermiculite layers at all concentrations. However, at low filler loading, that behavior was more obvious. At 1 wt% filler concentration, mechanical properties increased that was probably caused by good filler-matrix interaction stemmed from smaller particle size. At higher vermiculite concentrations, fillers found to show agglomerations that led to a decrease in mechanical strength and strain at break. Elastic and secant modulus showed an increasing trend. Contact angle measurements were carried out to determine the oleophilic character of the samples. An increase in the vermiculite content resulted in higher oleophilic character and the lowest contact angle was obtained at 15 wt% VMT loading. In addition to these, thermal stability, thermal dimensional stability and flame retardancy were improved by the incorporation of VMT. 15 wt% vermiculite-filled sample showed the best performance in terms of thermal stability and flame retardancy.

scholarly journals Ecofriendly Preparation and Characterization of a Cassava Starch/Polybutylene Adipate Terephthalate Film

Processes ◽  
2020 ◽  
Vol 8 (3) ◽  
pp. 329
Author(s):  
Tan Yi ◽  
Minghui Qi ◽  
Qi Mo ◽  
Lijie Huang ◽  
Hanyu Zhao ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Contact Angle ◽  
Water Vapor ◽  
Composite Film ◽  
Water Absorption ◽  
Composite Films ◽  
Thermoplastic Starch ◽  
Light Transmittance ◽  
Infrared Spectrometry ◽  
Nano Zno

Composite films of polybutylene adipate terephthalate (PBAT) were prepared by adding thermoplastic starch (TPS) (TPS/PBAT) and nano-zinc oxide (nano-ZnO) (TPS/PBAT/nano-ZnO). The changes of surface morphology, thermal properties, crystal types and functional groups of starch during plasticization were analyzed by scanning electron microscopy, synchronous thermal analysis, X-ray diffraction, infrared spectrometry, mechanical property tests, and contact Angle and transmittance tests. The relationship between the addition of TPS and the tensile strength, transmittance, contact angle, water absorption, and water vapor barrier of the composite film, and the influence of nano-ZnO on the mechanical properties and contact angle of the 10% TPS/PBAT composite film. Experimental results show that, after plasticizing, the crystalline form of starch changed from A-type to V-type, the functional group changed and the lipophilicity increased; the increase of TPS content, the light transmittance and mechanical properties of the composite membrane decreased, while the water vapor transmittance and water absorption increased. The mechanical properties of the composite can be significantly improved by adding nano-ZnO at a lower concentration (optimum content is 1 wt%).

The Preparation and Property Research on Laponite-Poly (L-Lactide) Composite Film

2013 ◽  
Vol 750-752 ◽  
pp. 1919-1923 ◽  
Author(s):  
Guo Xian Zhou ◽  
Ming Wei Yuan ◽  
Lin Jiang ◽  
Ming Long Yuan ◽  
Hong Li Li
Keyword(s):  
Electron Microscopy ◽  
Thermal Stability ◽  
Tensile Strength ◽  
Composite Film ◽  
Composite Films ◽  
Complexing Agent ◽  
Solution Blending ◽  
Method Of Solution ◽  
Thermal Stability Of ◽  
Scanning Electron

The laponite-poly (L-lactide) composite films are prepared by the method of solution blending with polylactide (PLA) and laponite. The result shows that the homogeneous and smooth composite film is prepared with 1, 4-dioxane. Thermogravimetry analysis (TG) and tensile strength studies demonstrate that the thermal stability and tensile strength are improved with the laponite added. The scanning electron microscopy (SEM) measurement indicates that the pores of composite films get uniform and network structure is more and more compact with compared to pure PLA film. The present study reveals that the laponite as a complexing agent can improve the mechanical properties and thermal stability of PLA.

scholarly journals Effect of High Pressure Treatment on Poly(lactic acid)/Nano–TiO2 Composite Films

Molecules ◽  
2018 ◽  
Vol 23 (10) ◽  
pp. 2621 ◽  
Author(s):  
Hai Chi ◽  
Wenhui Li ◽  
Chunli Fan ◽  
Cheng Zhang ◽  
Lin Li ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
High Pressure ◽  
Lactic Acid ◽  
Composite Film ◽  
Composite Films ◽  
Barrier Properties ◽  
Poly Lactic Acid ◽  
Pressure Treatment ◽  
Nano Tio2 ◽  
High Pressure Treatment

The microstructure, thermal properties, mechanical properties and oxygen and water vapor barrier properties of a poly(lactic acid) (PLA)/nano-TiO2 composite film before and after high pressure treatment were studied. Structural analysis showed that the functional group structure of the high pressure treated composite film did not change. It was found that the high pressure treatment did not form new chemical bonds between the nanoparticles and the PLA. The micro-section of the composite film after high pressure treatment became very rough, and the structure was depressed. Through the analysis of thermal and mechanical properties, high pressure treatment can not only increase the strength and stiffness of the composite film, but also increase the crystallinity of the composite film. Through the analysis of barrier properties, it is found that the barrier properties of composite films after high pressure treatment were been improved by the applied high pressure treatment.

scholarly journals Mechanically Robust Flexible Multilayer Aramid Nanofibers and MXene Film for High-Performance Electromagnetic Interference Shielding and Thermal Insulation

Nanomaterials ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 3041
Author(s):  
Jun Zhou ◽  
Junsheng Yu ◽  
Dongyu Bai ◽  
Huili Liu ◽  
Lu Li
Keyword(s):  
Mechanical Properties ◽  
Composite Film ◽  
Electromagnetic Interference ◽  
Multilayer Structure ◽  
High Performance ◽  
Composite Films ◽  
Next Generation ◽  
Shielding Effectiveness ◽  
Breaking Strain ◽  
Practical Applications

In order to overcome the various defects caused by the limitations of solid metal as a shielding material, the development of electromagnetic shielding materials with flexibility and excellent mechanical properties is of great significance for the next generation of intelligent electronic devices. Here, the aramid nanofiber/Ti3C2Tx MXene (ANF/MXene) composite films with multilayer structure were successfully prepared through a simple alternate vacuum-assisted filtration (AVAF) process. With the intervention of the ANF layer, the multilayer-structure film exhibits excellent mechanical properties. The ANF2/MXene1 composite film exhibits a tensile strength of 177.7 MPa and a breaking strain of 12.6%. In addition, the ANF5/MXene4 composite film with a thickness of only 30 μm exhibits an electromagnetic interference (EMI) shielding efficiency of 37.5 dB and a high EMI-specific shielding effectiveness value accounting for thickness (SSE/t) of 4718 dB·cm2 g−1. Moreover, the composite film was excellent in heat-insulation performance and in avoiding light-to-heat conversion. No burning sensation was produced on the surface of the film with a thickness of only 100 μm at a high temperature of 130 °C. Furthermore, the surface of the film was only mild when touched under simulated sunlight. Therefore, our multilayer-structure film has potential significance in practical applications such as next-generation smart electronic equipment, communications, and military applications.

scholarly journals Patterned Metal/Polymer Composite Film with Good Mechanical Stability and Repeatability for Flexible Electronic Devices Using Nanoimprint Technology

Micromachines ◽  
2019 ◽  
Vol 10 (10) ◽  
pp. 651
Author(s):  
Xu Zheng ◽  
Qing Wang ◽  
Jinjin Luan ◽  
Yao Li ◽  
Ning Wang
Keyword(s):  
Mechanical Properties ◽  
Composite Film ◽  
Polymer Composite ◽  
Interfacial Adhesion ◽  
Metal Film ◽  
Mechanical Stability ◽  
Electronic Devices ◽  
Composite Films ◽  
Polymer Composite Film ◽  
Metal Polymer

Mechanical stability and repeatability are significant factors for the application of metal film flexible electronic devices. In this work, patterned metal/polymer composite films with good mechanical stability and repeatability were fabricated through nanoimprint technology. The mechanical properties characteristic of metal/polymer composite films were exhibited by resistance change (ΔR/R0) after cyclic tension and bending loading. It was found that the ΔR/R0 and error line of patterned metal/polymer composite film was far lower than the other control groups for repeated experiments, which indicates that patterned metal film has excellent mechanical properties and repeatability. The double cantilever beam method was employed to measure the interfacial adhesion properties of composite films. The average interfacial adhesion of patterned metal/polymer composite films is shown to be over 2.9 and 2.2 times higher than that of metal film deposited on bare polymer and metal nanowire-treated polymer substrates, respectively.

Structure and Properties of Composite Films of Cellulose and Chitosan from Ionic Liquid

2012 ◽  
Vol 499 ◽  
pp. 80-84
Author(s):  
Huai Fang Wang ◽  
Wei Han Huang ◽  
Zhi Kai Wang
Keyword(s):  
Mechanical Properties ◽  
Thermal Stability ◽  
Ionic Liquid ◽  
Antimicrobial Property ◽  
Composite Films ◽  
Antibacterial Properties ◽  
Strong Interactions ◽  
Structure And Properties ◽  
Blend Films ◽  
Methyl Imidazole

A series of blend films of cellulose and chitosan were prepared from 1-ethyl-3-methyl imidazole acetate ([Emim] Ac) by coagulating with ethanol. Structure, mechanical properties, thermal stability and antibacterial properties were investigated. The results showed that there were strong interactions and good compatibility between cellulose and chitosan in blend films. The blend films possess good mechanical properties and thermal stability, and the existence of chitosan endows blend films with antimicrobial property.

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