Terrylene diimide-based middle-low bandgap electron acceptors for organic photovoltaics

2020 ◽  
Vol 8 (13) ◽  
pp. 4441-4446 ◽  
Author(s):  
Fei Tang ◽  
Danlei Zhu ◽  
Ningning Liang ◽  
Jianhui Hou ◽  
Zhaohui Wang

The impact of intramolecular conformational locks on molecular conformation, packing arrangement and photovoltaic performance was investigated for TDI-based electron acceptors.

2018 ◽  
Vol 39 (14) ◽  
pp. 1800086 ◽  
Author(s):  
Geert Pirotte ◽  
Jurgen Kesters ◽  
Tom Cardeynaels ◽  
Pieter Verstappen ◽  
Jan D'Haen ◽  
...  

2017 ◽  
Vol 7 (1) ◽  
Author(s):  
Alejandro Nicolas Filippin ◽  
Manuel Macias-Montero ◽  
Zineb Saghi ◽  
Jesús Idígoras ◽  
Pierre Burdet ◽  
...  

2019 ◽  
Vol 26 (4) ◽  
pp. 1351-1358 ◽  
Author(s):  
Anannya Bhattacharya ◽  
Jenifar Sultana ◽  
Subhrajit Sikdar ◽  
Rajib Saha ◽  
Sanatan Chattopadhyay

2017 ◽  
Vol 8 (7) ◽  
pp. 5095-5100 ◽  
Author(s):  
Wisnu Tantyo Hadmojo ◽  
Dajeong Yim ◽  
Havid Aqoma ◽  
Du Yeol Ryu ◽  
Tae Joo Shin ◽  
...  

We developed a novel NIR-harvesting n-type porphyrin derivative, PDI–PZn–PDI, that shows a low bandgap of 1.27 eV. Panchromatic absorption was extended to the NIR area with a significantly low energy loss of 0.54 eV which led to promising photovoltaic performance.


RSC Advances ◽  
2020 ◽  
Vol 10 (65) ◽  
pp. 39916-39921
Author(s):  
Bo Liu ◽  
Xiaobo Wang ◽  
Lang Li ◽  
Gang Wang

The new low bandgap benzo[1,2-b:4,5-b′]difuran (BDF)-based organic small molecule, namely B1, was synthesized by Stille coupling polymerization reactions.


2019 ◽  
Vol 43 (13) ◽  
pp. 5187-5195 ◽  
Author(s):  
Maryam Nazari ◽  
Edward Cieplechowicz ◽  
Thomas A. Welsh ◽  
Gregory C. Welch

A systematic structure–property-function evaluation of four structurally related organic photoactive materials based on the perylene diimide chromophore.


Materials ◽  
2020 ◽  
Vol 13 (11) ◽  
pp. 2660
Author(s):  
Emi Nakatsuka ◽  
Yo Kumoda ◽  
Kiyohito Mori ◽  
Takashi Kobayashi ◽  
Takashi Nagase ◽  
...  

Electronic transport measurement using modulated photocurrent (MPC) spectroscopy is demonstrated herein in working organic photovoltaics (OPVs) before and after AM1.5G irradiation. OPVs with bulk heterojunction (BHJ) using prototypical donor and acceptor materials, poly[[4,8-bis[(2-ethylhexyl)oxy]benzo[1–2-b:4,5-b′]dithiophene-2,6-diyl][3-fluoro-2-[(2-ethylhexyl)carbonyl] = hieno [3–4-b]thiophenediyl]] (PTB7) and [6,6]-phenyl-C71-butyric acid methyl ester (PC71BM), were fabricated. The OPVs had inverted structures (BHJs are formed on transparent conductive oxide substrates). The photovoltaic performance of PTB7:PC71BM OPVs was characterized and the best power conversion efficiency was obtained at PTB7 content of 40 wt%. Electron and hole mobility were determined with MPC spectroscopy in PTB7:PC71BM OPVs and were well balanced at PTB7 content of 40 wt%. Degradation of the photovoltaic performance of PTB7:PC71BM OPVs with PTB7 content of 40 wt% caused by AM1.5G irradiation was studied. MPC spectroscopy showed that the well-balanced mobility was not affected by AM1.5G irradiation. The degradation of OPVs was not due to changes in the electronic transport properties, but mainly to the reduced short circuit current (Jsc) and fill factor (FF). The origin of this reduction is discussed.


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