scholarly journals Self-healing and mechanical performance of dynamic glycol chitosan hydrogel nanocomposites

Author(s):  
Spyridon Efstathiou ◽  
Alan M. Wemyss ◽  
Georgios Patias ◽  
Lucas Al-Shok ◽  
Maria Grypioti ◽  
...  

Evaluation of Schiff base nanocomposite hydrogels properties using a benzaldehyde multifunctional amphiphilic polyacrylamide crosslinker in conjunction with glycol chitosan.

Polymers ◽  
2018 ◽  
Vol 10 (12) ◽  
pp. 1362 ◽  
Author(s):  
Bo Xu ◽  
Yuwei Liu ◽  
Jiugang Yuan ◽  
Ping Wang ◽  
Qiang Wang

Hydrogels with outstanding mechanical performance, self-healing capacity, and special functionality are highly desirable for their practical applications. However, it remains a great challenge to achieve such hydrogels by a facile approach. Here, we report a new type of nanocomposite hydrogels by in situ copolymerization of acrylic acid (AA) and 2-acrylamido-2-methylpropane sulfonic acid (AMPS) using alumina nanoparticles (Al2O3 NPs) as the cross-linkers. The obtained hydrogels are highly stretchable and compressible, which could sustain large-scale extension (>1700%) or compression (90%) without failure, and exhibit tensile and compressive strength up to 660 kPa and 8.3 MPa, respectively. Furthermore, this kind of hydrogel also display considerable self-healing capacity due to their noncovalent cross-linking mechanism, as well as the hydrogen-bonding interactions between polymer chains. More interestingly, it was found that the resultant gels possess a long-lasting antifogging property that could prevent the formation of fog on the glass plate above hot water for at least 90 min. It is expected that this novel type of hydrogel would show great promise for various applications, including soft robots, artificial muscles, and optical devices.


RSC Advances ◽  
2016 ◽  
Vol 6 (116) ◽  
pp. 115247-115251 ◽  
Author(s):  
Jiaoyu Ren ◽  
Yanxi Zhu ◽  
Hongyun Xuan ◽  
Xuefan Liu ◽  
Zhichao Lou ◽  
...  

In this study, we report highly transparent self-healing films based on Schiff base linkages between DF-PEG and CS via a layer-by-layer technique.


Soft Matter ◽  
2014 ◽  
Vol 10 (19) ◽  
pp. 3506 ◽  
Author(s):  
Tao Wang ◽  
Shudian Zheng ◽  
Weixiang Sun ◽  
Xinxing Liu ◽  
Shiyu Fu ◽  
...  

2022 ◽  
pp. 2100777
Author(s):  
Xiwei Xu ◽  
Songqi Ma ◽  
Sheng Wang ◽  
Binbo Wang ◽  
Hongzhi Feng ◽  
...  

Polymers ◽  
2020 ◽  
Vol 12 (6) ◽  
pp. 1416 ◽  
Author(s):  
Pejman Heidarian ◽  
Abbas Z. Kouzani ◽  
Akif Kaynak ◽  
Ali Zolfagharian ◽  
Hossein Yousefi

It is an ongoing challenge to fabricate an electroconductive and tough hydrogel with autonomous self-healing and self-recovery (SELF) for wearable strain sensors. Current electroconductive hydrogels often show a trade-off between static crosslinks for mechanical strength and dynamic crosslinks for SELF properties. In this work, a facile procedure was developed to synthesize a dynamic electroconductive hydrogel with excellent SELF and mechanical properties from starch/polyacrylic acid (St/PAA) by simply loading ferric ions (Fe3+) and tannic acid-coated chitin nanofibers (TA-ChNFs) into the hydrogel network. Based on our findings, the highest toughness was observed for the 1 wt.% TA-ChNF-reinforced hydrogel (1.43 MJ/m3), which is 10.5-fold higher than the unreinforced counterpart. Moreover, the 1 wt.% TA-ChNF-reinforced hydrogel showed the highest resistance against crack propagation and a 96.5% healing efficiency after 40 min. Therefore, it was chosen as the optimized hydrogel to pursue the remaining experiments. Due to its unique SELF performance, network stability, superior mechanical, and self-adhesiveness properties, this hydrogel demonstrates potential for applications in self-wearable strain sensors.


2015 ◽  
Vol 3 (27) ◽  
pp. 5511-5522 ◽  
Author(s):  
Shalini V Gohil ◽  
Sarah B. Brittain ◽  
Ho-Man Kan ◽  
Hicham Drissi ◽  
David W. Rowe ◽  
...  

An injectable, enzymatically crosslinkable glycol chitosan hydrogel was developed and evaluated for localized growth factor delivery.


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