scholarly journals Kinetic origins of the metastable zone width in the manganese oxide Pourbaix diagram

2021 ◽  
Vol 9 (12) ◽  
pp. 7857-7867
Author(s):  
Bor-Rong Chen ◽  
Wenhao Sun ◽  
Daniil A. Kitchaev ◽  
Kevin H. Stone ◽  
Ryan C. Davis ◽  
...  
Keyword(s):  
Phase Diagram ◽  
Phase Transformation ◽  
Manganese Oxide ◽  
Reaction Conditions ◽  
Pourbaix Diagram ◽  
Metastable Zone Width ◽  
Zone Width ◽  
Metastable Zone

The metastable zone width is the region on a phase diagram where a phase transformation is thermodynamically favored but kinetically hindered. Reaction conditions may need to be far beyond the Pourbaix phase diagram boundaries to initiate nucleation.

Effect of thermal history of aqueous solutions of KCl on the metastable zone width

1984 ◽  
Vol 49 (3) ◽  
pp. 559-569 ◽  
Author(s):  
Jaroslav Nývlt
Keyword(s):  
Aqueous Solution ◽  
Aqueous Solutions ◽  
Thermal History ◽  
Equilibrium Solubility ◽  
Metastable Zone Width ◽  
Zone Width ◽  
Preceding Experiment ◽  
History Of ◽  
Metastable Zone ◽  
The Given

The metastable zone width of an aqueous solution of KCI was measured as a function of the time and temperature of overheating above the equilibrium solubility temperature. It has been found that when the experiments follow close upon one another, the parameters of the preceding experiment affect the results of the experiment to follow.The results are interpreted in terms of hypotheses advanced in the literature to account for the effect of thermal history of solution. The plausibility and applicability of these hypotheses are assessed for the given cause of aqueous solution of a well soluble electrolyte.

scholarly journals Solubility and Seeded Metastable Zone width of functional sugar L-arabinose

2015 ◽  
Vol 35 (1) ◽  
pp. 51-57 ◽  
Author(s):  
Biao Hu ◽  
Kai Huang ◽  
Xinlin Zhang ◽  
Pingjun Zhang ◽  
Shujuan Yu
Keyword(s):  
Metastable Zone Width ◽  
Zone Width ◽  
Metastable Zone

A model for determination of the interfacial energy from the induction time or metastable zone width data based on turbidity measurements

CrystEngComm ◽  
2014 ◽  
Vol 16 (41) ◽  
pp. 9743-9752 ◽  
Author(s):  
Lie-Ding Shiau ◽  
Tsan-Sheng Lu
Keyword(s):  
Interfacial Energy ◽  
Induction Time ◽  
Metastable Zone Width ◽  
Zone Width ◽  
Metastable Zone

A model is developed to recover the interfacial energy from the induction time and the metastable zone width data.

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