Scalable ultrarobust thermoconductive nonflammable bioinspired papers of graphene nanoplatelet crosslinked aramid nanofibers for thermal management and electromagnetic shielding

Author(s):  
Minh Canh Vu ◽  
Pyeong Jun Park ◽  
Sa-Rang Bae ◽  
Soo Young Kim ◽  
Young-Min Kang ◽  
...  

Graphene nanoplatelets are chemically crosslinked to aramid nanofibers through a phosphorus trimer to fabricate ultratough, thermoconductive, flame retardant, and EMI shielding films.

Nanoscale ◽  
2021 ◽  
Author(s):  
Bing Zhou ◽  
Qingtao Li ◽  
Penghui Xu ◽  
Yuezhan Feng ◽  
Jianmin Ma ◽  
...  

Flexible cellulose-based conductive films reveal the high potential in electromagnetic interference (EMI) shielding and thermal management applications. However, the high contact electrical/thermal resistance in these films is still one of...


2021 ◽  
Vol 28 (3) ◽  
Author(s):  
Halima Saadiya Ababsa ◽  
Zitouni Safidine ◽  
Ahmed Mekki ◽  
Yves Grohens ◽  
Amina Ouadah ◽  
...  

Molecules ◽  
2021 ◽  
Vol 26 (13) ◽  
pp. 4094
Author(s):  
Imran Ali ◽  
Nam Kyeun Kim ◽  
Debes Bhattacharyya

The integration of intumescent flame-retardant (IFR) additives in natural fiber-based polymer composites enhances the fire-retardant properties, but it generally has a detrimental effect on the mechanical properties, such as tensile and flexural strengths. In this work, the feasibility of graphene as a reinforcement additive and as an effective synergist for IFR-based flax-polypropylene (PP) composites was investigated. Noticeable improvements in tensile and flexural properties were achieved with the addition of graphene nanoplatelets (GNP) in the composites. Furthermore, better char-forming ability of GNP in combination with IFR was observed, suppressing HRR curves and thus, lowering the total heat release (THR). Thermogravimetric analysis (TGA) detected a reduction in the decomposition rate due to strong interfacial bonding between GNP and PP, whereas the maximum decomposition rate was observed to occur at a higher temperature. The saturation point for the IFR additive along with GNP has also been highlighted in this study. A safe and effective method of graphene encapsulation within PP using the fume-hood set-up was achieved. Finally, the effect of flame retardant on the flax–PP composite has been simulated using Fire Dynamics Simulator.


2021 ◽  
Author(s):  
KANAT ANURAKPARADORN ◽  
ALAN TAUB ◽  
ERIC MICHIELSSEN

The proliferation of wireless technology calls for the development of cost-effective Electromagnetic Interference (EMI) shielding materials that reduce the susceptibility of high-speed electronic circuits to undesired incoming radiation. Ideally, such materials offer protection over wide frequency ranges and are insensitive to the polarization or angle of incidence of the impinging fields. Here, next-generation EMI shielding materials composed of polymer composites with conductive and magnetic fillers are introduced. It is shown that careful control of the concentration and dispersion of the polymers’ conductive and magnetic constituents permits tuning of the composites’ intrinsic electrical and magnetic properties. The resulting EMI shields are lightweight, cheap and offer greater protection than traditional metal gaskets and foams. In this work, cobalt ferrite magnetic nanoparticles (CoFe2O4) decorated on graphene-based material were dispersed in polylactic acid (PLA) matrix for high EM absorption level in X-band (8-12 GHz). The decoration of the magnetic particles was performed on the as-prepared conductive graphene nanoplatelets (GNP) and reduced graphene oxide (rGO). GNP composites exhibited higher DC conductivity, and permittivity than rGO composites. This is attributed to issues associated with the reduction process, including a lack of conductivity due to the insulated oxygen functional groups and the reduction in the lateral size. Compared with rGOs, the lack of out-plane functional groups causes the cobalt ferrite nanoparticles to agglomerate and not cover the entire surface of the GNPs. These morphological differences improve the magnetization and EM absorption of the composite system. The compatibilizer (pyrene-PLA-OH) was added to the composites to enhance dispersion of the GNPs in the polymer matrix which benefits in higher absorption of the shield. The influence of the compatibilizer on parameter, the reflection loss (RL) of the composite were determined from the characterized intrinsic properties


2018 ◽  
Vol 6 (38) ◽  
pp. 10292-10300 ◽  
Author(s):  
Biao Zhao ◽  
Chongxiang Zhao ◽  
Mahdi Hamidinejad ◽  
Chongda Wang ◽  
Ruosong Li ◽  
...  

The electrical conductivity and the EMI shielding properties could be effectively tuned by the foaming degree.


RSC Advances ◽  
2020 ◽  
Vol 10 (3) ◽  
pp. 1535-1543 ◽  
Author(s):  
Biao Zhao ◽  
Xi Zhang ◽  
Jiushuai Deng ◽  
Chun Zhang ◽  
Yang Li ◽  
...  

Graphene/PEBAX composite films present high-efficiency EMI shielding properties and good sensitivity as well as sensing stability.


RSC Advances ◽  
2017 ◽  
Vol 7 (5) ◽  
pp. 2796-2803 ◽  
Author(s):  
Quan Wang ◽  
Yuming Wang ◽  
Qingguo Meng ◽  
Tinglan Wang ◽  
Weihong Guo ◽  
...  

High antistatic HDPE composites were firstly prepared by solution blending with polyaniline encapsulated graphene nanoplatelets nanocomposites.


2014 ◽  
Vol 492 ◽  
pp. 268-272 ◽  
Author(s):  
Rui Wang ◽  
Hui Yang ◽  
Jing Ling Wang ◽  
Zong Qing Ma ◽  
Feng Xiu Li

In present work, two conductive filler (carbon fiber with Nickel (Ni) coatings and carbon fiber with Nickel/Fe3O4 nanoparticle (Ni/Fe3O4-NPs) composite coatings) were prepared by electrodeposition. Microstructure observation indicated that the coatings were deposited uniformly on the surface of fiber. Vibrating sample magnetometer (VSM) and electromagnetic interference (EMI) shielding test showed that the two conductive filler has good saturation magnetization and EMI shielding effectiveness.The conductive filler of carbon fiber with Ni/Fe3O4-NPs composite coatings was more excellent. They are promising for application in electromagnetic shielding materials.


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