Structure and chemistry of the solid electrolyte interphase (SEI) on a high capacity conversion-based anode: NiO

2021 ◽  
Vol 9 (1) ◽  
pp. 523-537
Author(s):  
Benjamin Ng ◽  
Ehsan Faegh ◽  
Saheed Lateef ◽  
Stavros G. Karakalos ◽  
William E. Mustain

Electroanalytical techniques are specialized tools with high-sensitivity that when combined with electron transfer theory can shed light on the mechanisms of highly complex, heterogeneous, multi-step reactions – including SEI formation on LiB anodes.

1991 ◽  
Vol 95 (25) ◽  
pp. 10485-10492 ◽  
Author(s):  
Keisuke Tominaga ◽  
Gilbert C. Walker ◽  
Tai Jong Kang ◽  
Paul F. Barbara ◽  
Teresa Fonseca

Nature ◽  
1988 ◽  
Vol 333 (6169) ◽  
pp. 114-114 ◽  
Author(s):  
Jim Barber

2006 ◽  
Vol 05 (03) ◽  
pp. 685-692 ◽  
Author(s):  
PING HAN ◽  
RUI-XUE XU ◽  
PING CUI ◽  
YAN MO ◽  
GUOZHONG HE ◽  
...  

The effect of solvation on ET rate processes has been investigated on the basis of the exact theory constructed in J. Phys. Chem. B110:11438, 2006. The nature of solvation has been studied in close relation with the mechanism of ET processes. The resulting Kramers' turnover and Marcus' inversion characteristics have been analyzed accordingly. The classical picture of solvation has been found to be invalid when the solvent longitudinal relaxation time is short compared with the inverse temperature.


1975 ◽  
Vol 30 (12) ◽  
pp. 1661-1666 ◽  
Author(s):  
P. J. P. De Maayer ◽  
J. D. Mackenzie

Abstract Thin films of metallically conductive titanium mononitride and carbide were prepared by means of electron beam evaporation. The composition of the samples could be changed over appreciable ranges by introducing nitrogen in the system or adding carbon to the pure starting material, respectively. The transport properties of the resulting compounds were studied as a function of nonstoichiometry and defect structure. A plausible explanation for the different behavior of the films compared to corresponding bulk samples is given and a correlation between the change in electron concentration and the electron transfer theory is presented.


2019 ◽  
Vol 32 (1) ◽  
pp. 448-458 ◽  
Author(s):  
Jing Zhang ◽  
Kai Zhang ◽  
Junghoon Yang ◽  
Vincent Wing-hei Lau ◽  
Gi-Hyeok Lee ◽  
...  

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