Remarkable performance of the unique catalyst Pd-Fe2O3 toward EOR and ORR: Non-Pt and non-carbon electrode material for low temperature fuel cell

Author(s):  
Rajib Adhikary ◽  
Dipankar Sarkar ◽  
Manabendra Mukherjee ◽  
Jayati Datta

The present investigation deals with Pd NPs casted over Fe2O3 support in formulating Pd/Fe2O3 catalyst with a complete non Pt and non carbon approach toward accomplishing electro-catalysis of ethanol oxidation...

2017 ◽  
Vol 31 (27) ◽  
pp. 1750193 ◽  
Author(s):  
Ghazanfar Abbas ◽  
Rizwan Raza ◽  
M. Ashfaq Ahmad ◽  
M. Ajmal Khan ◽  
M. Jafar Hussain ◽  
...  

Zinc-based nanostructured nickel (Ni) free metal oxide electrode material Zn[Formula: see text]/Cu[Formula: see text]Mn[Formula: see text] oxide (CMZO) was synthesized by solid state reaction and investigated for low temperature solid oxide fuel cell (LTSOFC) applications. The crystal structure and surface morphology of the synthesized electrode material were examined by XRD and SEM techniques respectively. The particle size of ZnO phase estimated by Scherer’s equation was 31.50 nm. The maximum electrical conductivity was found to be 12.567 S/cm and 5.846 S/cm in hydrogen and air atmosphere, respectively at 600[Formula: see text]C. The activation energy of the CMZO material was also calculated from the DC conductivity data using Arrhenius plots and it was found to be 0.060 and 0.075 eV in hydrogen and air atmosphere, respectively. The CMZO electrode-based fuel cell was tested using carbonated samarium doped ceria composite (NSDC) electrolyte. The three layers 13 mm in diameter and 1 mm thickness of the symmetric fuel cell were fabricated by dry pressing. The maximum power density of 728.86 mW/cm2 was measured at 550[Formula: see text]C.


2016 ◽  
Vol 38 (11) ◽  
pp. 1333-1341 ◽  
Author(s):  
Eduardo D. Penteado ◽  
Carmen M. Fernandez-Marchante ◽  
Marcelo Zaiat ◽  
Ernesto R. Gonzalez ◽  
Manuel A. Rodrigo

Author(s):  
J. Lobato ◽  
P. Can˜izares ◽  
M. A. Rodrigo ◽  
J. J. Linares ◽  
B. Sa´nchez-Rivera

With the aim of improving the ethanol oxidation in fuel cells, researchers have developed numerous catalysts to break up the C-C bond. Most of the tests have been carried out at low temperature, using Nafion membrane as electrolyte. The cell performance of the Direct Ethanol Fuel Cells (DEFCs) at low temperature is still far from its industrial application. To improve the DEFC power density, high temperature operation (150–200 °C) has been suggested to promote the complete oxidation of ethanol. Thus, three different catalysts (Pt-Ru (1:1), Pt-Sn (1:1) and Pt-Sn-Ru (1:1:0.3), all of them supported on both non-activated and activated carbon were tested in H3PO4 doped PBI-based fuel cell, using vapour fed ethanol, operating in the range of 150–200 °C, and high ethanol concentration 6.7 M. The catalyst were synthesized using NaBH4 as reducing agent and were characterized by XRD, ICP-AES and TPR analyses. The best performance was reached at the highest temperature and with the catalyst based on Pt-Ru. The best results for the Ru-based catalyst can be explained by the higher level of alloying reached for the Ru than for Sn, which modifies the crystalline structure of Pt and enhances the activity oxidation of ethanol and of intermediates that are generated during the oxidation of ethanol.


Author(s):  
Siti H. Osman ◽  
S. K. Kamarudin ◽  
Nabila A. Karim ◽  
Sahriah Basri

2021 ◽  
pp. 2101219
Author(s):  
Fu Yang ◽  
Lirong Dong ◽  
Dongju Jang ◽  
Begench Saparov ◽  
Kai Cheong Tam ◽  
...  

2009 ◽  
Vol 192 (1) ◽  
pp. 208-215 ◽  
Author(s):  
Vanesa M. García ◽  
Eduardo López ◽  
Maria Serra ◽  
Jordi Llorca

Energies ◽  
2021 ◽  
Vol 14 (8) ◽  
pp. 2182
Author(s):  
Artem Chesalkin ◽  
Petr Kacor ◽  
Petr Moldrik

Hydrogen is one of the modern energy carriers, but its storage and practical use of the newest hydrogen technologies in real operation conditions still is a task of future investigations. This work describes the experimental hydrogen hybrid energy system (HHS). HHS is part of a laboratory off-grid system that stores electricity gained from photovoltaic panels (PVs). This system includes hydrogen production and storage units and NEXA Ballard low-temperature proton-exchange membrane fuel cell (PEMFC). Fuel cell (FC) loses a significant part of heat during converting chemical energy into electricity. The main purpose of the study was to explore the heat distribution phenomena across the FC NEXA Ballard stack during load with the next heat transfer optimization. The operation of the FC with insufficient cooling can lead to its overheating or even cell destruction. The cause of this undesirable state is studied with the help of infrared thermography and computational fluid dynamics (CFD) modeling with heat transfer simulation across the stack. The distribution of heat in the stack under various loads was studied, and local points of overheating were determined. Based on the obtained data of the cooling air streamlines and velocity profiles, few ways of the heat distribution optimization along the stack were proposed. This optimization was achieved by changing the original shape of the FC cooling duct. The stable condition of the FC stack at constant load was determined.


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