Hierarchical Cu2S@NiCo-LDH double-shelled nanotube arrays with enhanced electrochemical performance for hybrid supercapacitors

2020 ◽  
Vol 8 (42) ◽  
pp. 22163-22174
Author(s):  
Ze Yuan ◽  
Haiyan Wang ◽  
Junling Shen ◽  
Pengcheng Ye ◽  
Jiqiang Ning ◽  
...  
Keyword(s):  
Energy Density ◽  
Electrochemical Performance ◽  
Rate Capability ◽  
High Energy ◽  
High Energy Density ◽  
Nanotube Arrays ◽  
Hybrid Supercapacitor ◽  
Hybrid Supercapacitors ◽  
Enhanced Electrochemical Performance

Hierarchical Cu2S@NiCo-LDH double-shelled nanotube arrays (Cu2S@NiCo-LDH DSNAs) are prepared by a multi-step approach, and the fabricated Cu2S@NiCo-LDH DSNAs//NPC hybrid supercapacitor exhibits a high energy density and remarkable rate capability.

scholarly journals Wire-Shaped 3D-Hybrid Supercapacitors as Substitutes for Batteries

2020 ◽  
Vol 12 (1) ◽  
Author(s):  
Kyeong-Nam Kang ◽  
Ananthakumar Ramadoss ◽  
Jin-Wook Min ◽  
Jong-Chul Yoon ◽  
Deokjung Lee ◽  
...  
Keyword(s):  
Energy Density ◽  
Active Sites ◽  
Rate Capability ◽  
High Energy ◽  
High Energy Density ◽  
Easy Access ◽  
Nickel Wire ◽  
Hybrid Supercapacitor ◽  
Hybrid Supercapacitors ◽  
Volumetric Capacitance

Abstract We report a wire-shaped three-dimensional (3D)-hybrid supercapacitor with high volumetric capacitance and high energy density due to an interconnected 3D-configuration of the electrode allowing for large number of electrochemical active sites, easy access of electrolyte ions, and facile charge transport for flexible wearable applications. The interconnected and compact electrode delivers a high volumetric capacitance (gravimetric capacitance) of 73 F cm−3 (2446 F g−1), excellent rate capability, and cycle stability. The 3D-nickel cobalt-layered double hydroxide onto 3D-nickel wire (NiCo LDH/3D-Ni)//the 3D-manganese oxide onto 3D-nickel wire (Mn3O4/3D-Ni) hybrid supercapacitor exhibits energy density of 153.3 Wh kg−1 and power density of 8810 W kg−1. The red light-emitting diode powered by the as-prepared hybrid supercapacitor can operate for 80 min after being charged for tens of seconds and exhibit excellent electrochemical stability under various deformation conditions. The results verify that such wire-shaped 3D-hybrid supercapacitors are promising alternatives for batteries with long charge–discharge times, for smart wearable and implantable devices.

Novel zinc–iodine hybrid supercapacitors with a redox iodide ion electrolyte and B, N dual-doped carbon electrode exhibit boosted energy density

2019 ◽  
Vol 7 (42) ◽  
pp. 24400-24407 ◽  
Author(s):  
Lu Han ◽  
Hailong Huang ◽  
Junfeng Li ◽  
Zhongli Yang ◽  
Xinlu Zhang ◽  
...  
Keyword(s):  
Energy Density ◽  
High Energy ◽  
High Energy Density ◽  
Carbon Electrode ◽  
Hybrid Supercapacitor ◽  
Hybrid Supercapacitors ◽  
Iodide Ion

A novel high-energy-density zinc–iodine hybrid supercapacitor was designed via the introduction of a redox iodide ion electrolyte and B, N dual-doped carbon electrode.

scholarly journals Ultra-High Energy Density Hybrid Supercapacitors Using MnO2/Reduced Graphene Oxide Hybrid Nanoscrolls

Nanomaterials ◽  
2020 ◽  
Vol 10 (10) ◽  
pp. 2049 ◽  
Author(s):  
Janardhanan. R. Rani ◽  
Ranjith Thangavel ◽  
Minjae Kim ◽  
Yun Sung Lee ◽  
Jae-Hyung Jang
Keyword(s):  
Graphene Oxide ◽  
Energy Storage ◽  
Energy Density ◽  
Storage Systems ◽  
High Energy ◽  
High Energy Density ◽  
Ultra High Energy ◽  
Hybrid Supercapacitor ◽  
Hybrid Supercapacitors ◽  
Reduced Graphene

Manganese oxide (MnO2) is a promising material for supercapacitor applications, with a theoretical ultra-high energy density of 308 Wh/kg. However, such ultra-high energy density has not been achieved experimentally in MnO2-based supercapacitors because of several practical issues, such as low electrical conductivity of MnO2, incomplete utilization of MnO2, and dissolution of MnO2. The present study investigates the potential of MnO2/reduced graphene oxide (rGO) hybrid nanoscroll (GMS) structures as electrode material for overcoming the difficulties and for developing ultra-high-energy storage systems. A hybrid supercapacitor, comprising MnO2/rGO nanoscrolls as anode material and activated carbon (AC) as a cathode, is fabricated. The GMS/AC hybrid supercapacitor exhibited enhanced energy density, superior rate performance, and promising Li storage capability that bridged the energy–density gap between conventional Li-ion batteries (LIBs) and supercapacitors. The fabricated GMS/AC hybrid supercapacitor demonstrates an ultra-high lithium discharge capacity of 2040 mAh/g. The GMS/AC cell delivered a maximum energy density of 105.3 Wh/kg and a corresponding power density of 308.1 W/kg. It also delivered an energy density of 42.77 Wh/kg at a power density as high as 30,800 W/kg. Our GMS/AC cell’s energy density values are very high compared with those of other reported values of graphene-based hybrid structures. The GMS structures offer significant potential as an electrode material for energy-storage systems and can also enhance the performance of the other electrode materials for LIBs and hybrid supercapacitors.

scholarly journals Oxygen-Defect Enhanced Anion Adsorption Energy Toward Super-Rate and Durable Cathode for Ni–Zn Batteries

2021 ◽  
Vol 13 (1) ◽  
Author(s):  
Jia Yao ◽  
Houzhao Wan ◽  
Chi Chen ◽  
Jie Ji ◽  
Nengze Wang ◽  
...  
Keyword(s):  
Energy Density ◽  
Active Sites ◽  
Theoretical Calculations ◽  
Rate Capability ◽  
High Energy ◽  
High Energy Density ◽  
Nanotube Arrays ◽  
Performance Limit ◽  
Oxygen Defects ◽  
Transport Path

AbstractThe alkaline zinc-based batteries with high energy density are becoming a research hotspot. However, the poor cycle stability and low-rate performance limit their wide application. Herein, ultra-thin CoNiO2 nanosheet with rich oxygen defects anchored on the vertically arranged Ni nanotube arrays (Od-CNO@Ni NTs) is used as a positive material for rechargeable alkaline Ni–Zn batteries. As the highly uniform Ni nanotube arrays provide a fast electron/ion transport path and abundant active sites, the Od-CNO@Ni NTs electrode delivers excellent capacity (432.7 mAh g−1) and rate capability (218.3 mAh g−1 at 60 A g−1). Moreover, our Od-CNO@Ni NTs//Zn battery is capable of an ultra-long lifespan (93.0% of initial capacity after 5000 cycles), extremely high energy density of 547.5 Wh kg−1 and power density of 92.9 kW kg−1 (based on the mass of cathode active substance). Meanwhile, the theoretical calculations reveal that the oxygen defects can enhance the interaction between electrode surface and electrolyte ions, contributing to higher capacity. This work opens a reasonable idea for the development of ultra-durable, ultra-fast, and high-energy Ni–Zn battery."Image missing"

Potassium Pre-Inserted K1.04Mn8O16 Cathode Materials for Aqueous Li-Ion and Na-Ion Hybrid Capacitors

2019 ◽  
Author(s):  
Yamin Zhang ◽  
Lina Chen ◽  
Chongyang Hao ◽  
Xiaowen Zheng ◽  
Yixuan Guo ◽  
...  
Keyword(s):  
Cycling Performance ◽  
High Energy ◽  
High Energy Density ◽  
Potassium Ions ◽  
Tunnel Structure ◽  
Hybrid Supercapacitor ◽  
Hybrid Supercapacitors ◽  
Li Ion ◽  
Power Densities ◽  
Hybrid Capacitors

For the applications of aqueous Li-ion hybrid capacitors and Na-ion hybrid capacitors, potassium ions are pre-inserted into MnO<sub>2</sub> tunnel structure, the as-prepared K<sub>1.04</sub>Mn<sub>8</sub>O<sub>16</sub> materials consist of <a>nanoparticles</a> and nanorods were prepared by facile high-temperature solid-state reaction. <a></a>The as-prepared materials were well studied andthey show outstanding electrochemical behavior. We assembled hybrid supercapacitors with commercial activated carbon (YEC-8A) as anode and K<sub>1.04</sub>Mn<sub>8</sub>O<sub>16 </sub>as cathode. It has high energy densities and power densities. Li-ion capacitors reach a high energy density of 127.61 Wh kg<sup>-1 </sup>at the power density of 99.86 W kg<sup>-1</sup> and Na-ion capacitor obtains 170.96 Wh kg<sup>-1 </sup>at 133.79 W kg<sup>-1</sup>. In addition, the <a>hybrid supercapacitor</a>s demonstrate excellent cycling performance which maintain 97 % capacitance retention for Li-ion capacitor and 85 % for Na-ion capacitor after 10,000 cycles.

Sign in / Sign up

Export Citation Format

Share Document