scholarly journals Defect chemistry and transport properties of perovskite-type oxides La1−xCaxFeO3−δ

Author(s):  
Jia Song ◽  
Shaochen Zhu ◽  
De Ning ◽  
Henny J. M. Bouwmeester

Correlating the migration enthalpy of oxygen in perovskite-type oxides La1−xCaxFeO3−δ with the formation enthalpy of oxygen vacancies.

2014 ◽  
Vol 33 (3-4) ◽  
pp. 221-229 ◽  
Author(s):  
Christoph Slouka ◽  
Lukas Andrejs ◽  
Jürgen Fleig

2018 ◽  
Vol 20 (26) ◽  
pp. 17871-17880 ◽  
Author(s):  
Urmimala Dey ◽  
Swastika Chatterjee ◽  
A. Taraphder

It has been realized lately that disorder, primarily in the form of oxygen vacancies, cation stoichiometry, atomic inter-diffusion and antisite defects, has a major effect on the electronic and transport properties of a 2D electron liquid at oxide hetero-interfaces – the first and the last being the two key players.


1992 ◽  
pp. 553-561 ◽  
Author(s):  
E.J. Opila ◽  
G. Pfundtner ◽  
J. Maier ◽  
H.L. Tuller ◽  
B.J. Wuensch

1989 ◽  
Vol 5 (1) ◽  
pp. 43-46 ◽  
Author(s):  
P. Antoine ◽  
R. Assabaa ◽  
P. L'Haridon ◽  
R. Marchand ◽  
Y. Laurent ◽  
...  

Science ◽  
2017 ◽  
Vol 358 (6364) ◽  
pp. 734-738 ◽  
Author(s):  
Kei Hirose ◽  
Ryosuke Sinmyo ◽  
John Hernlund

Silicate perovskite-type phases are the most abundant constituent inside our planet and are the predominant minerals in Earth’s lower mantle more than 660 kilometers below the surface. Magnesium-rich perovskite is a major lower mantle phase and undergoes a phase transition to post-perovskite near the bottom of the mantle. Calcium-rich perovskite is proportionally minor but may host numerous trace elements that record chemical differentiation events. The properties of mantle perovskites are the key to understanding the dynamic evolution of Earth, as they strongly influence the transport properties of lower mantle rocks. Perovskites are expected to be an important constituent of rocky planets larger than Mars and thus play a major role in modulating the evolution of terrestrial planets throughout the universe.


2015 ◽  
Vol 17 (19) ◽  
pp. 12587-12597 ◽  
Author(s):  
Markus Kessel ◽  
Roger A. De Souza ◽  
Manfred Martin

Oxygen isotope experiments reveal a surface space-charge layer and a migration enthalpy of oxygen vacancies of 0.7 eV.


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