Highly efficient self-healing materials with excellent shape memory and unprecedented mechanical properties

2020 ◽  
Vol 8 (32) ◽  
pp. 16203-16211 ◽  
Author(s):  
Chaoxian Chen ◽  
Siwen Chen ◽  
Zhihao Guo ◽  
Wanruo Hu ◽  
Zhangpei Chen ◽  
...  

Novel dual-physical cross-linked elastomers with unprecedented mechanical, highly efficient self-healing, and excellent shape memory properties are designed, which will offer new guild for future body-sensors, stimulating reactive and wound healing.

Author(s):  
Shishan Xue ◽  
Yuanpeng Wu ◽  
Guanfei Liu ◽  
Meiling Guo ◽  
Yuhan Liu ◽  
...  

A hierarchically reversible crosslinked hydrogel has been designed with excellent mechanical properties, efficient self-healability and double-driven shape memory effect (pH, Ca2+). A soft catcher actuator was constructed, which could catch a plastic fish in Ca2+ solution.


2021 ◽  
Vol 329 ◽  
pp. 115581
Author(s):  
Chaoxian Chen ◽  
Zhongcun Li ◽  
Siwen Chen ◽  
Lingzhi Kong ◽  
Zhihao Guo ◽  
...  

2021 ◽  
Vol 171 ◽  
pp. 113978
Author(s):  
Ya-zhou Xu ◽  
Pan Fu ◽  
Song-lin Dai ◽  
Hai-bo Zhang ◽  
Liang-wu Bi ◽  
...  

Polymers ◽  
2019 ◽  
Vol 11 (5) ◽  
pp. 807 ◽  
Author(s):  
Lin Xia ◽  
Han Gao ◽  
Weina Bi ◽  
Wenxin Fu ◽  
Guixue Qiu ◽  
...  

Shape memory composites of trans-1,4-polyisoprene (TPI) and low-density polyethylene (LDPE) with easily achievable transition temperatures were prepared by a simple physical blending method. Carbon black (CB) was introduced to improve the mechanical properties of the TPI/LDPE composites. The mechanical, cure, thermal and shape memory properties of the TPI/LDPE/CB composites were investigated in this study. In these composites, the crosslinked network generated in both the TPI and LDPE portions acted as a fixed domain, while the crystalline regions of the TPI and LDPE portions acted as a reversible domain in shape memory behavior. We found the mechanical properties of composites were promoted significantly with an increase of CB content, accompanied with the deterioration of shape memory properties of composites. When CB dosage was 5 parts per hundred of rubber composites (phr), best shape memory property of composites was obtained with a shape fixity ratio of 95.1% and a shape recovery ratio of 95.0%.


2021 ◽  
Vol 45 (1) ◽  
pp. 314-320
Author(s):  
Yuewen Chen ◽  
Shengping Dai ◽  
Hao Zhu ◽  
Hongwei Hu ◽  
Ningyi Yuan ◽  
...  

Shape memory hydrogels offer new opportunities for the development of smart wearables due to their intelligent responsiveness.


Author(s):  
Jianfeng Ban ◽  
Linjiang Zhu ◽  
Shaojun Chen ◽  
Yiping Wang

To better understand the shape memory materials and self-healing materials, a new series of liquid-crystalline shape memory polyurethane (LC-SMPU) composites, named SMPU-OOBAm, were successfully prepared by incorporating 4-octyldecyloxybenzoic acid (OOBA) into the PEG-based SMPU. The effect of OOBA on the structure, morphology and properties has been carefully investigated. The results demonstrate that SMPU-OOBAm have liquid crystalline properties, triple-shape memory properties and self-healing properties. The incorporated OOBA promotes the crystallizability of both soft and hard segments of SMPU, and the crystallization rate of the hard segment of SMPU decreases when the OOBA-content increases. Additionally, the SMPU-OOBAm forms a two-phase separated structure (SMPU phase and OOBA phase), and it shows two-step modulus changes upon heating. Therefore, the SMPU-OOBAm shows triple-shape memory behavior, and the shape recovery ratio decreases with an increase in the OOBA content. Finally, SMPU-OOBAm shows self-healing properties. The new mechanism can be ascribed to the heating-induced “bleeding” of OOBA in the liquid crystalline state and the subsequent re-crystallization upon cooling. This successful combination of liquid crystalline properties, triple-shape memory properties and self-healing properties make the SMPU-OOBAm composites with many promise applications in smart optical devices, smart electronic devices and smart sensors.


2020 ◽  
Vol 38 (8A) ◽  
pp. 1178-1186
Author(s):  
Raad S. Ahmed Adnan

This study examines the effect of Sn additions on Cu-14%Al-4.5%Ni shape memory alloy. Sn was added in three different percentages (0.3,1,3) %. The alloys were mechanically tested both in compression test and micro hardness test. Also, a thermo-mechanical test was performed on the alloys. Results showed an increase in the transformation temperature outside the domain and also a better recovery strain with the increase of Sn percentage of 3% Sn addition showed the best results in mechanical properties while the 3% Sn showed a better Shape Memory Properties near to super elastic.


2015 ◽  
Vol 3 (6) ◽  
pp. 2924-2933 ◽  
Author(s):  
Shaojun Chen ◽  
Funian Mo ◽  
Yan Yang ◽  
Florian J. Stadler ◽  
Shiguo Chen ◽  
...  

Novel zwitterionic polyurethanes containing sulfobetaines, featuring excellent multi-shape-memory properties and self-healing properties, are prepared from N-methyldiethanolamine, hexamethylene diisocyanate and 1,3-propanesultone.


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