A robust metal–organic framework for post-combustion carbon dioxide capture

2020 ◽  
Vol 8 (24) ◽  
pp. 12028-12034 ◽  
Author(s):  
Omid T. Qazvini ◽  
Shane G. Telfer
Keyword(s):  
Carbon Dioxide ◽  
Carbon Dioxide Capture ◽  
Metal Organic Framework ◽  
Low Energy ◽  
Separation And Purification ◽  
Energy Footprint ◽  
Metal Organic ◽  
Organic Framework

Separation and purification technologies for capturing carbon dioxide (CO2) with a low energy footprint are sought after.

A versatile metal–organic framework for carbon dioxide capture and cooperative catalysis

2012 ◽  
Vol 48 (80) ◽  
pp. 9995 ◽  
Author(s):  
Jinhee Park ◽  
Jian-Rong Li ◽  
Ying-Pin Chen ◽  
Jiamei Yu ◽  
Andrey A. Yakovenko ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Carbon Dioxide Capture ◽  
Metal Organic Framework ◽  
Cooperative Catalysis ◽  
Metal Organic ◽  
Organic Framework

Application of the piperazine-grafted CuBTTri metal-organic framework in postcombustion carbon dioxide capture

2013 ◽  
Vol 174 ◽  
pp. 74-80 ◽  
Author(s):  
Anita Das ◽  
Mohammad Choucair ◽  
Peter D. Southon ◽  
Jarad A. Mason ◽  
Ming Zhao ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Carbon Dioxide Capture ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

A polyhedral metal–organic framework based on the supermolecular building block strategy exhibiting high performance for carbon dioxide capture and separation of light hydrocarbons

2015 ◽  
Vol 51 (83) ◽  
pp. 15287-15289 ◽  
Author(s):  
Dongmei Wang ◽  
Bing Liu ◽  
Shuo Yao ◽  
Tao Wang ◽  
Guanghua Li ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Building Block ◽  
High Performance ◽  
Carbon Dioxide Capture ◽  
Metal Organic Framework ◽  
Light Hydrocarbons ◽  
Metal Organic ◽  
Organic Framework

A PMOF was assembled by the SBB strategy, which exhibited high performance for CO2capture and separation towards CO2, C2H6and C3H8over CH4.

scholarly journals Carbon dioxide capture and conversion by an acid-base resistant metal-organic framework

2017 ◽  
Vol 8 (1) ◽  
Author(s):  
Linfeng Liang ◽  
Caiping Liu ◽  
Feilong Jiang ◽  
Qihui Chen ◽  
Linjie Zhang ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Carbon Dioxide Capture ◽  
Metal Organic Framework ◽  
Acid Base ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Synthesis of FeCo-MIL-88B and Investigate Its Potential for CO2 Capture

2019 ◽  
Vol 35 (1) ◽  
Author(s):  
Le Minh Cam ◽  
Le Van Khu ◽  
Nguyen Thi Thu Ha ◽  
Nguyen Ngoc Ha
Keyword(s):  
Carbon Dioxide ◽  
Surface Area ◽  
Mesoporous Materials ◽  
Co2 Capture ◽  
Carbon Capture ◽  
Co2 Adsorption ◽  
Carbon Dioxide Capture ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

Cobalt dopping Fe-MIL-88B were successfully synthesized -in solvothermal procedure using DMF as solvent and with/without NaOH. The samples were characterized using SEM, BET and TGA techniques. The partly substitution of Fe by Co does not change the octahedral shape of their parent Fe-MIL-88B. Crystallizations conducted in NaOH medium, however, results in rod like with 2-end octahedral shape crystals. The BET specific surface area is 139cm2/g. The TGA data indicated that the presence of Co resulted in an increase in thermal stability of synthesized samples compared to parent Fe-MIL-88B. The CO2 adsorption isotherms in Fe-MIL-88B-Co samples were measured volumetrically at five temperatures:278K, 288K, 298K, 308K, 318K. The obtained results showed that Fe-MIL-88B-Co is a potential adsorbent with a maximum adsortption capacity of 1.2312 mmol/g (at T= 278K). The sample synthesized in alkali medium exhibited a better adsorbent for CO2 storage. Keywords MIL, adsorption, CO2 References [1] S. Chu, Carbon Capture and Sequestration, Science325(2009)1599 [2] R.S. Haszeldine,Carbon Capture and Storage: How Green Can Black Be?, Science325(2009) 1647[3] D.M. D’Alessandro, B. Smit, J.R. Long,Carbon Dioxide Capture: Prospects for New Materials, Angewandte Chemie International Edition. 49(2010) 6058[4] S. Bai, J. Liu, J. Gao, Q. Yang Can Li,Hydrolysis controlled synthesis of amine-functionalized hollow ethane–silica nanospheres as adsorbents for CO2 capture, Microporous and Mesoporous Materials151(2012) 474[5] K. Sumida, D.L. Rogow, J.A. Mason, T.M. McDonald, E.D. Bloch, Z.R. Herm, T.H. Bae, J.R.[6] Long,Carbon Dioxide Capture in Metal–Organic Frameworks, Chemical Reviews, 112(2012) 724[7] J.D. Carruthers, M.A. Petruska, E.A. Sturm, S.M. Wilson,Molecular sieve carbons for CO2 capture, Microporous and Mesoporous Materials,154 (2012) 62[8] X. Yan, L. Zhang, Y. Zhang, K. Qiao, Z. Yan, S. Komarneni,Amine-modified mesocellular silica foams for CO2 capture, Chemical Engineering Journal,168 (2011), 918[9] A. Zukal, C.O. Arean, M.R. Delgado, P. Nachtigall, A. Pulido, J. Mayerova, J. Cˇejka,Combined volumetric, infrared spectroscopic and theoretical investigation of CO2 adsorption on Na-A zeolite,Microporous and Mesoporous Materials 146 (2011) 97[10] S. Keskin, T.M. van Heest, D.S. Sholl, Can Metal–Organic Framework Materials Play a Useful Role in Large‐Scale Carbon Dioxide Separations?, ChemSusChem3 (2010) 879[11] T.M. McDonald, W.R. Lee, J.A. Mason, B.M. Wiers, C.S. Hong, J.R. Long, Capture of Carbon Dioxide from Air and Flue Gas in the Alkylamine-Appended Metal–Organic Framework mmen-Mg2(dobpdc), Journal of the American Chemical Society134 (2012) 7056[12] X. Yan, S. Komarneni, Z. Zhang, Z. Yan(2014),Extremely enhanced CO2 uptake by HKUST-1 metal–organic framework via a simple chemical treatment, Microporous and Mesoporous Materials183 (2014) 69–73[13] Gia-Thanh Vuong, Minh-Hao Pham and Trong-On Do*, Direct synthesis and mechanism of the formation of mixed metal Fe2Ni-MIL-88B†, CrystEngComm, DOI: 10.1039/c3ce41453a[14] Lê Văn Khu, Nguyễn Quốc Anh, Nguyễn Ngọc Hà, Lê Minh Cầm, Tổng hợp, đặc trưng và khảo sát khả năng hấp phụ CO2 của Fe-MIL-88B, Tạp chí xúc tác và hấp phụ 4 (1) (2015) 52[15] K. S. W. Sing, D. H. Everett, R. A. W. Hau et.al, Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity, Pure and Applied Chemistry 57 (1985) 603

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