Direct conversion of metal organic frameworks into ultrafine phosphide nanocomposites in multicomponent plasma for wide pH hydrogen evolution

2020 ◽  
Vol 8 (20) ◽  
pp. 10402-10408 ◽  
Author(s):  
Yanru Guo ◽  
Chunmei Zhang ◽  
Yong Wu ◽  
Hongen Yu ◽  
Shaojun Zhang ◽  
...  
Keyword(s):  
Low Temperature ◽  
Hydrogen Evolution ◽  
Metal Organic Frameworks ◽  
Direct Conversion ◽  
Red Phosphorus ◽  
Carbon Removal ◽  
Multicomponent Plasma ◽  
Metal Organic

Multicomponent NH3 plasma enhances the carbon removal effect and activates red phosphorus to PH radicals, resulting in simultaneous MOF decomposition and phosphorization at low temperature.

Recent progress in pristine MOF-based catalysts for electrochemical hydrogen evolution, oxygen evolution and oxygen reduction

2021 ◽  
Author(s):  
Lili Fan ◽  
Zixi Kang ◽  
Mengfei Li ◽  
Daofeng Sun
Keyword(s):  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Hydrogen Evolution ◽  
Oxygen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Oxygen Evolution Reaction ◽  
Recent Progress ◽  
Metal Organic Frameworks ◽  
Reduction Reaction ◽  
Metal Organic

Among various kinds of materials that have been investigated as electrocatalysts for hydrogen evolution reaction (HER), oxygen evolution reaction (OER) and oxygen reduction reaction (ORR), metal-organic frameworks (MOFs) emerge as...

scholarly journals Modulating electronic structure of metal-organic frameworks by introducing atomically dispersed Ru for efficient hydrogen evolution

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Yamei Sun ◽  
Ziqian Xue ◽  
Qinglin Liu ◽  
Yaling Jia ◽  
Yinle Li ◽  
...  
Keyword(s):  
Electronic Structure ◽  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Density Functional ◽  
Metal Organic Frameworks ◽  
Catalyst Design ◽  
Single Atom ◽  
Hydrogen Energy ◽  
Structure Of Metal ◽  
Metal Organic

AbstractDeveloping high-performance electrocatalysts toward hydrogen evolution reaction is important for clean and sustainable hydrogen energy, yet still challenging. Herein, we report a single-atom strategy to construct excellent metal-organic frameworks (MOFs) hydrogen evolution reaction electrocatalyst (NiRu0.13-BDC) by introducing atomically dispersed Ru. Significantly, the obtained NiRu0.13-BDC exhibits outstanding hydrogen evolution activity in all pH, especially with a low overpotential of 36 mV at a current density of 10 mA cm−2 in 1 M phosphate buffered saline solution, which is comparable to commercial Pt/C. X-ray absorption fine structures and the density functional theory calculations reveal that introducing Ru single-atom can modulate electronic structure of metal center in the MOF, leading to the optimization of binding strength for H2O and H*, and the enhancement of HER performance. This work establishes single-atom strategy as an efficient approach to modulate electronic structure of MOFs for catalyst design.

Dual Metal UiO-Type Metal–Organic Frameworks for Solar-Driven Photocatalytic Hydrogen Evolution

2021 ◽  
Vol 125 (37) ◽  
pp. 20320-20330
Author(s):  
Xianxian Kong ◽  
Qianqian Pan ◽  
Shuang Song ◽  
Zhiqiao He ◽  
Tao Zeng ◽  
...  
Keyword(s):  
Hydrogen Evolution ◽  
Metal Organic Frameworks ◽  
Photocatalytic Hydrogen Evolution ◽  
Metal Organic ◽  
Dual Metal

Direct Conversion of Benzothiadiazole to Benzimidazole: New Benzimidazole‐Derived Metal–Organic Frameworks with Adjustable Honeycomb‐Like Cavities

2019 ◽  
Vol 25 (20) ◽  
pp. 5246-5250
Author(s):  
Yingnan Zhao ◽  
Xiao Han ◽  
Feihu Yu ◽  
Donghui Wei ◽  
Qing Cheng ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Direct Conversion ◽  
Metal Organic

Plasma modification of a Ni based metal–organic framework for efficient hydrogen evolution

2019 ◽  
Vol 7 (14) ◽  
pp. 8129-8135 ◽  
Author(s):  
Yanru Guo ◽  
Xing Gao ◽  
Chunmei Zhang ◽  
Yong Wu ◽  
Xinghua Chang ◽  
...  
Keyword(s):  
Low Temperature ◽  
Thin Layer ◽  
Hydrogen Evolution ◽  
Metal Organic Framework ◽  
3D Structure ◽  
Plasma Modification ◽  
Highly Efficient ◽  
Metal Organic ◽  
Organic Framework

Low temperature NH3 plasma modification of Ni MOF-74 yields a highly efficient hydrogen evolution catalyst with a carambola-like hierarchical 3D structure, which is composed of ultrafine Ni nanocrystals encapsulated in a thin layer of N doped carbon.

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