P–Fe bond oxygen reduction catalysts toward high-efficiency metal–air batteries and fuel cells

2020 ◽  
Vol 8 (18) ◽  
pp. 9121-9127 ◽  
Author(s):  
Huihui Jin ◽  
Zongkui Kou ◽  
Weiwei Cai ◽  
Huang Zhou ◽  
Pengxia Ji ◽  
...  
Keyword(s):  
Fuel Cells ◽  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
High Efficiency ◽  
Catalytic Performance ◽  
Reduction Reaction ◽  
Carbon Framework ◽  
Oxygen Reduction Catalysts ◽  
Reduction Catalysts ◽  
Co Doped

An Fe, N, P co-doped carbon framework catalyst (CPFeNPC) with a novel C–P–Fe–Nx–P–C system exhibits superior oxygen reduction reaction (ORR) catalytic performance and shines new light on the real application of metal–N–C catalysts in fuel cells.

Treasure Map for Nonmetallic Catalyst: Optimal Nitrogen and Fluorine Distribution of Biomass-Derived Carbon Materials for High-Performance Oxygen Reduction Catalysts

2021 ◽  
Author(s):  
Yaling Zhao ◽  
Yang Liu ◽  
Ye Chen ◽  
Xupo Liu ◽  
Xiaoge Li ◽  
...  
Keyword(s):  
Fuel Cells ◽  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
High Throughput ◽  
Porous Carbon ◽  
High Performance ◽  
Carbon Materials ◽  
Reduction Reaction ◽  
Oxygen Reduction Catalysts ◽  
Reduction Catalysts

Heteroatom-doped porous carbon materials have shown promising prospects in the field of Zn-air batteries (ZABs) and fuel cells. However, the high-throughput preparation and instant screening of excellent oxygen reduction reaction...

N and S Co-doped Ordered Mesoporous Carbon: An Efficient Electrocatalyst for Oxygen Reduction Reaction in Microbial Fuel Cells

2020 ◽  
Vol 16 (4) ◽  
pp. 625-638
Author(s):  
Leila Samiee ◽  
Sedigheh Sadegh Hassani
Keyword(s):  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Microbial Fuel Cells ◽  
Carbon Materials ◽  
Reduction Reaction ◽  
Carbon Substrate ◽  
Promising Candidate ◽  
X Ray ◽  
Carbon Framework ◽  
Co Doped

Background: Porous carbon materials are promising candidate supports for various applications. In a number of these applications, doping of the carbon framework with heteroatoms provides a facile route to readily tune the carbon properties. The oxygen reduction reaction (ORR), where the reaction can be catalyzed without precious metals is one of the common applications for the heteroatom-doped carbons. Therefore, heteroatom doped catalysts might have a promising potential as a cathode in Microbial fuel cells (MFCs). MFCs have a good potential to produce electricity from biological oxidization of wastes at the anode and chemical reduction at the cathode. To the best of our knowledge, no studies have been yet reported on utilizing Sulfur trioxide pyridine (STP) and CMK-3 for the preparation of (N and S) doped ordered porous carbon materials. The presence of highly ordered mesostructured and the synergistic effect of N and S atoms with specific structures enhance the oxygen adsorption due to improving the electrocatalytic activity. So the optimal catalyst, with significant stability and excellent tolerance of methanol crossover can be a promising candidate for even other storage and conversion devices. Methods: The physico-chemical properties of the prepared samples were determined by Small Angle X-ray Diffraction (SAXRD), N2 sorption-desorption, Transmission Electron Microscopy (TEM), Field Emission Scanning Electron Microscopy (FESEM) and X-ray Photoelectron Spectroscopy (XPS). The prepared samples were further applied for oxygen reduction reaction (ORR) and the optimal cathode was tested with the Microbial Fuel Cell (MFC) system. Furthermore, according to structural analysis, The HRTEM, and SAXRD results confirmed the formation of well-ordered hexagonal (p6mm) arrays of mesopores in the direction of (100). The EDS and XPS approved that N and S were successfully doped into the CMK-3 carbon framework. Results: Among all the studied CMK-3 based catalysts, the catalyst prepared by STP precursor and pyrolysis at 900°C exhibited the highest ORR activity with the onset potential of 1.02 V vs. RHE and 4 electron transfer number per oxygen molecule in 0.1 M KOH. The high catalyst durability and fuel-crossover tolerance led to stable performance of the optimal cathode after 5000 s operation, while the Pt/C cathode-based was considerably degraded. Finally, the MFC system with the optimal cathode displayed 43.9 mW·m-2 peak power density showing even reasonable performance in comparison to a Pt/C 20 wt.%.cathode. Conclusions: The results revealed that the synergistic effect of nitrogen and sulfur co-doped on the carbon substrate structure leads to improvement in catalytic activity. Also, it was clearly observed that the porous structure and order level of the carbon substrate could considerably change the ORR performance.

Enhanced oxygen reduction reaction through Ca and Co Co-doped YFeO3 as cathode for protonic ceramic fuel cells

2019 ◽  
Vol 413 ◽  
pp. 148-157 ◽  
Author(s):  
Jiajia Cui ◽  
Junkai Wang ◽  
Xiongwen Zhang ◽  
Guojun Li ◽  
Kai Wu ◽  
...  
Keyword(s):  
Fuel Cells ◽  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Reduction Reaction ◽  
Ceramic Fuel ◽  
Ceramic Fuel Cells ◽  
Co Doped

scholarly journals Metallic Organic Framework-Derived Fe, N, S co-doped Carbon as a Robust Catalyst for the Oxygen Reduction Reaction in Microbial Fuel Cells

Energies ◽  
2019 ◽  
Vol 12 (20) ◽  
pp. 3846 ◽  
Author(s):  
Xiao Luo ◽  
Wuli Han ◽  
Han Ren ◽  
Qingzuo Zhuang
Keyword(s):  
Fuel Cells ◽  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Microbial Fuel Cells ◽  
Active Sites ◽  
Reduction Reaction ◽  
Alkaline Media ◽  
X Ray ◽  
Co Doped ◽  
Organic Framework

Oxygen reduction reaction (ORR) provides a vital role for microbial fuel cells (MFCs) due to its slow reaction kinetics compared with the anodic oxidation reaction. How to develop new materials with low cost, high efficacy, and eco-friendliness which could replace platinum-based electrocatalysis is a challenge that we have to resolve. In this work, we accomplished this successfully by means of a facile strategy to synthesize a metallic organic framework-derived Fe, N, S co-doped carbon with FeS as the main phase. The Fe/S@N/C-0.5 catalyst demonstrated outstandingly enhanced ORR activity in neutral PBS and alkaline media, compared to that of commercial 20% Pt-C catalyst. Here, we started-up and operated two parallel single-chamber microbial fuel cells of an air cathode, and those cathode catalysts were Fe/S@N/C-0.5 and commercial Pt-C (20% Pt), respectively. Scanning electron microscopy (SEM) elaborated that the Fe/S@N/C-0.5 composite did not change the polyhedron morphology of ZIF-8. According to X-ray diffractometry(XRD) curves, the main crystal phase of the resulted Fe/S@N/C-0.5 was FeS. The chemical environment of N, S, and Fe which are anticipated to be the high-efficiency active sites of ORR for MFCs were investigated by X-ray photoelectron spectroscopic(XPS). Nitrogen adsorption/desorption techniques were used to calculate the pore diameter distribution. In brief, the obtained Fe/S@N/C-0.5 material exhibited a pronounced reduction potential at 0.861 V (versus Reversible Hydrogen Electrode(RHE)) in 0.1M KOH solution and –0.03 V (vs. SCE) in the PBS solution, which both outperform the benchmark platinum-based catalysts. Fe/S@N/C-0.5-MFC had a higher Open Circuit Voltage(OCV) (0.71 V), stronger maximum power density (1196 mW/m2), and larger output voltage (0.47 V) than the Pt/C-MFC under the same conditions.

Ionic liquid derived carbons as highly efficient oxygen reduction catalysts: first elucidation of pore size distribution dependent kinetics

2014 ◽  
Vol 50 (12) ◽  
pp. 1469-1471 ◽  
Author(s):  
Zhiyong Zhang ◽  
Gabriel M. Veith ◽  
Gilbert M. Brown ◽  
Pasquale F. Fulvio ◽  
Patrick C. Hillesheim ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Oxygen Reduction Reaction ◽  
Pore Size Distribution ◽  
Pore Size ◽  
Oxygen Reduction ◽  
Size Distribution ◽  
Reduction Reaction ◽  
Highly Efficient ◽  
Oxygen Reduction Catalysts ◽  
Reduction Catalysts

Pore size distribution in ionic liquid derived N-doped carbons affects both activity and kinetics in the oxygen reduction reaction.

Porous calcium–manganese oxide/carbon nanotube microspheres as efficient oxygen reduction catalysts for rechargeable zinc–air batteries

2021 ◽  
Author(s):  
Nguk Neng Tham ◽  
Xiaoming Ge ◽  
Aishui Yu ◽  
Bing Li ◽  
Yun Zong ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Carbon Nanotube ◽  
Oxygen Reduction Reaction ◽  
Porous Structure ◽  
Oxygen Reduction ◽  
Reduction Reaction ◽  
Oxygen Reduction Reaction Activity ◽  
Oxygen Reduction Catalysts ◽  
Reduction Catalysts ◽  
Zinc Air Batteries

CaMnO3−δ/carbon nanotubes show excellent oxygen reduction reaction activity benefitting from their unique porous structure and synergistic coupling between CaMnO3−δ and carbon nanotubes.

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