scholarly journals Understanding the role of crystallographic shear on the electrochemical behavior of niobium oxyfluorides

2020 ◽  
Vol 8 (25) ◽  
pp. 12623-12632 ◽  
Author(s):  
Nicholas H. Bashian ◽  
Molleigh B. Preefer ◽  
JoAnna Milam-Guerrero ◽  
Joshua J. Zak ◽  
Charlotte Sendi ◽  
...  
Keyword(s):  
Electrochemical Behavior ◽  
Structural Evolution ◽  
Crystallographic Shear ◽  
Shear Planes

The effects of shear planes in perovskitic materials have been studied in order to identify their role in the electrochemical behavior and structural evolution of Li+ intercalation hosts.

Microstructure and reactivity of small metal particles: The role of Ce additives

1992 ◽  
Vol 50 (1) ◽  
pp. 318-319
Author(s):  
L.D. Schmidt ◽  
K. R. Krause ◽  
J. M. Schwartz ◽  
X. Chu
Keyword(s):  
Atmospheric Pressure ◽  
Noble Metals ◽  
Mixed Oxides ◽  
Catalytic Properties ◽  
Chemical Shifts ◽  
Catalytic Converter ◽  
Structural Evolution ◽  
Single Particles ◽  
Small Metal Particles

The evolution of microstructures of 10- to 100-Å diameter particles of Rh and Pt on SiO2 and Al2O3 following treatment in reducing, oxidizing, and reacting conditions have been characterized by TEM. We are able to transfer particles repeatedly between microscope and a reactor furnace so that the structural evolution of single particles can be examined following treatments in gases at atmospheric pressure. We are especially interested in the role of Ce additives on noble metals such as Pt and Rh. These systems are crucial in the automotive catalytic converter, and rare earths can significantly modify catalytic properties in many reactions. In particular, we are concerned with the oxidation state of Ce and its role in formation of mixed oxides with metals or with the support. For this we employ EELS in TEM, a technique uniquely suited to detect chemical shifts with ∼30Å resolution.

scholarly journals The role of mergers and interactions in driving the evolution of dwarf galaxies over cosmic time

2020 ◽  
Vol 500 (4) ◽  
pp. 4937-4957 ◽  
Author(s):  
G Martin ◽  
R A Jackson ◽  
S Kaviraj ◽  
H Choi ◽  
J E G Devriendt ◽  
...  
Keyword(s):  
Star Formation ◽  
Dwarf Galaxies ◽  
Large Fraction ◽  
Structural Evolution ◽  
Cosmic Time ◽  
Stellar Mass ◽  
High Mass ◽  
Key Drivers ◽  
Mass Assembly

ABSTRACT Dwarf galaxies (M⋆ < 109 M⊙) are key drivers of mass assembly in high-mass galaxies, but relatively little is understood about the assembly of dwarf galaxies themselves. Using the NewHorizon cosmological simulation (∼40 pc spatial resolution), we investigate how mergers and fly-bys drive the mass assembly and structural evolution of around 1000 field and group dwarfs up to z = 0.5. We find that, while dwarf galaxies often exhibit disturbed morphologies (5 and 20 per cent are disturbed at z = 1 and z = 3 respectively), only a small proportion of the morphological disturbances seen in dwarf galaxies are driven by mergers at any redshift (for 109 M⊙, mergers drive under 20 per cent morphological disturbances). They are instead primarily the result of interactions that do not end in a merger (e.g. fly-bys). Given the large fraction of apparently morphologically disturbed dwarf galaxies which are not, in fact, merging, this finding is particularly important to future studies identifying dwarf mergers and post-mergers morphologically at intermediate and high redshifts. Dwarfs typically undergo one major and one minor merger between z = 5 and z = 0.5, accounting for 10 per cent of their total stellar mass. Mergers can also drive moderate star formation enhancements at lower redshifts (3 or 4 times at z = 1), but this accounts for only a few per cent of stellar mass in the dwarf regime given their infrequency. Non-merger interactions drive significantly smaller star formation enhancements (around two times), but their preponderance relative to mergers means they account for around 10 per cent of stellar mass formed in the dwarf regime.

scholarly journals Effect of tungsten disulfide nanotubes on crystallization of polylactide under uniaxial deformation and annealing

2021 ◽  
Vol 2 (1) ◽  
Author(s):  
Fausta Loffredo ◽  
Loredana Tammaro ◽  
Tiziana Di Luccio ◽  
Carmela Borriello ◽  
Fulvia Villani ◽  
...  
Keyword(s):  
Biomedical Applications ◽  
Structural Evolution ◽  
Tungsten Disulfide ◽  
Fine Tuning ◽  
Nanocomposite Films ◽  
Uniaxial Deformation ◽  
Scanning Calorimetry ◽  
X Ray ◽  
X Ray Scattering

AbstractTungsten disulfide (WS2) nanotubes (NTs) are examined here as a filler for polylactide (PLA) for their ability to accelerate PLA crystallization and for their promising biocompatibility in relevant to biomedical applications of PLA-WS2 nanocomposites. In this work, we have studied the structural and thermal properties of PLA-WS2 nanocomposite films varying the concentration of WS2 NTs from 0 (neat PLA) to 0.6 wt%. The films were uniaxially drawn at 90 °C and annealed at the same temperature for 3 and 10 min. Using wide angle x-ray scattering, Raman spectroscopy and differential scanning calorimetry, we probed the effects of WS2 NT addition on the structure of the PLA films at various stages of processing (unstretched, stretching, annealing). We found that 0.6 wt% of WS2 induces the same level of crystallinity in as stretched PLA-WS2 as annealing in neat PLA for 10 min. These data provide useful insights into the role of WS2 NTs on the structural evolution of PLA-WS2 composites under uniaxial deformation, and extend their applicability to situations where fine tuning of PLA crystallinity is desirable.

scholarly journals Application of paleoseismological techniques to the study of Late Pleistocene-Holocene deep-seated gravitational movements at the Mortirolo Pass (central Alps, Italy)

2001 ◽  
Vol 80 (3-4) ◽  
pp. 209-227 ◽  
Author(s):  
M. Onida ◽  
F. Galadini ◽  
F. Forcella
Keyword(s):  
Late Pleistocene ◽  
Large Scale ◽  
Vertical Displacement ◽  
Central Alps ◽  
Glacial Retreat ◽  
Activation Mechanisms ◽  
Loading And Unloading ◽  
Shear Planes ◽  
Geometry And Kinematics

AbstractPaleoseismological techniques have been used to investigate gravitational deformations at the Mortirolo Pass (Valtellina region, central Alps), in order to improve the knowledge on the activation mechanisms and the evolution of deep-seated gravitational slope movements. The deformation has been responsible for mass sliding towards the Valtellina depression through the activation of several-hundred-metre-long shear planes. Minor shear planes dipping towards the mountain played the role of antithetic structures. Four trenches were excavated across scarps representing the surficial expression of shear planes affecting the bedrock and Late Pleistocene-Holocene deposits. The excavations enabled to investigate the stratigraphy of Quaternary deposits and the geometry and kinematics of the shear planes affecting them. Radiocarbon analyses on organic material contained in sediments and paleosols enabled to define a succession of displacement events which occurred during the Late Pleistocene-Holocene. Collected data indicate the persistence of the activity until recent times (last movement related to 1810-1540 cal. BP). A sudden movement has been detected along one of the main shear surfaces (dipping towards the valley) with a vertical displacement of several metres. In contrast, numerous displacements (with lower vertical offset) have been detected along the antithetic shear planes. Different hypotheses have been proposed in the past to define the origin of huge gravitational movements (glacial retreat, uplift of the Alpine chain, fault activity). However, the Late Pleistocene cycles of glacial loading and unloading on the mountain slopes seem to be the most probable factors causing deep-seated gravitational movements in the investigated region. A recent dramatic landslide in an area adjacent to the investigated one (Mt. Zandila-Valpola) testifies to the paroxistic evolution of the large scale gravitational deformations. The densely inhabited Valtellina region is affected by a large number of gravitational structures similar to those of the Mortirolo area. In consideration of the possible effects of the paroxistic activation of these structures, detailed studies on the chronology and kinematics of the deformations through the application of paleoseismological techniques should therefore be encouraged.

Structural evolution in lead substituted Bi–Sr–Ca–Cu–O superconductors

1991 ◽  
Vol 6 (2) ◽  
pp. 278-288 ◽  
Author(s):  
R. Ramesh ◽  
K. Remschnig ◽  
J.M. Tarascon ◽  
S.M. Green
Keyword(s):  
Structural Evolution ◽  
Homogeneous Sample ◽  
X Ray ◽  
Thermodynamics And Kinetics ◽  
Transmission Electron ◽  
Incommensurate Modulation ◽  
Kinetics Of ◽  
Pb Substitution ◽  
Microstructural Homogeneity

The structural evolution and cationic stoichiometry of Bi(Pb)–Sr–Ca–Cu–O superconductors have been studied using transmission electron microscopy and x-ray microanalysis. The nature of the incommensurate modulation changes systematically as increasing amounts of lead are added. X-ray microanalysis studies reveal that lead replaces Bi in the structure. Pb addition improves the microstructural homogeneity leading to the formation of a nearly homogeneous sample consisting of the “2223” phase. Based upon all the experimental results, it is inferred that the role of Pb substitution is related to the thermodynamics and kinetics of the formation of the n = 3 phase.

Structural evolution and the role of native defects in subnanometer MoS nanowires

2019 ◽  
Vol 100 (23) ◽  
Author(s):  
Daniel F. Souza ◽  
Andréia L. Rosa ◽  
Pedro Venezuela ◽  
José E. Padilha ◽  
Adalberto Fazzio ◽  
...  
Keyword(s):  
Structural Evolution ◽  
Native Defects

scholarly journals The Role of Debris-Rich Ice in Flow Near the Margins of Glaciers (Abstract)

1986 ◽  
Vol 8 ◽  
pp. 201 ◽  
Author(s):  
R.W. Baker
Keyword(s):  
Shear Plane ◽  
Conveyor Belt ◽  
Physical Geography ◽  
Supporting Evidence ◽  
Ice Caps ◽  
Considerable Controversy ◽  
Flow And Sediment Transport ◽  
The Subject ◽  
Shear Planes

The margins of many ice sheets and ice caps are marked by the presence of alternating layers of debris-laden and clean ice. The role of this ice in flow and sediment transport near the margins of glaciers has been the subject of considerable controversy between glacial geologists and glaciologists for over three decades. Glacial geologists (Goldthwait, 1951, 1960, 1971, 1975; Bishop, 1957; Souchez, 1967, Boulton, 1970, 1972; Hambrey, 1976) commonly refer to the debris-bearing ice bands as “thrust planes” or “shear planes”, apparently seeing them as reverse faults which transport rock debris from the glacier bed to the surface in a “conveyor-belt-like” manner (Goldthwait, 1975, p. 192). As supporting evidence for the shear-plane mechanism, glacial geologists have offered only qualitative observations and none seem to have actually observed it in action. Glaciologists on the other hand, particularly Weertman (1961), Hooke (1968; 1973), and Hooke and Hudleston (1978), have objected to this concept on physical grounds and have presented convincing arguments for doubting that it is mechanically sound. In spite of the controversy surrounding it, the shear-plane mechanism has gained wide acceptance among geologists and physical geographers and has been perpetuated in recent years through a number of popular introductory geology and physical geography textbooks (e.g. Embleton and King, 1975; Judson, Deffeyes, and Hargraves, 1976; Leet, Judson, and Kauffman, 1978; Press and Siever, 1982; Hamblin; 1982).

scholarly journals The Origin of Morainic Deposits and the Characteristics of Glacial Erosion in the Western Sør-Rondane, Antarctica

1966 ◽  
Vol 6 (44) ◽  
pp. 249-254 ◽  
Author(s):  
R. A. Souchez
Keyword(s):  
Ice Sheet ◽  
Polar Ice ◽  
Glacial Erosion ◽  
Glacier Fluctuations ◽  
Lithological Composition ◽  
Shear Planes ◽  
Periglacial Process

AbstractTwo types of morainic deposits can be found in western Sør-Rondane mountains: the super-glacial morainic ridge the material of which comes from slope evolution, and the hillocky moraine whose origin is related to shear planes in the glacier and therefore subglacial. A hypothesis of the formation of the hillocky moraine is given and the lithological composition of this deposit allows us to deduce the importance of glacial erosion at the level of the ice falls which frequently exist at the beginning of outlet glaciers where they leave the polar ice sheet. On this step, the role of glacier fluctuations is of importance in relation to a special periglacial process: greenhouse frost shattering.

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