Recent advances in conjugated microporous polymers for photocatalysis: designs, applications, and prospects

2020 ◽  
Vol 8 (14) ◽  
pp. 6434-6470 ◽  
Author(s):  
Songhao Luo ◽  
Zhuotong Zeng ◽  
Guangming Zeng ◽  
Zhifeng Liu ◽  
Rong Xiao ◽  
...  

Conjugated microporous polymers (CMPs) provide a platform to construct light harvesting systems and catalytic centers to realize solar energy conversion.

2016 ◽  
Vol 18 (9) ◽  
pp. 6885-6892 ◽  
Author(s):  
Jianfeng Lu ◽  
Hao Li ◽  
Shuangshuang Liu ◽  
Yu-Cheng Chang ◽  
Hui-Ping Wu ◽  
...  

Accelerated inner charge transfer in porphyrins promotes a broad light-harvesting ability up to 840 nm and a conversion efficiency of 9.2%.


2021 ◽  
pp. 17-50
Author(s):  
Gaozhong Shen ◽  

This chapter focuses on the solar energy conversion in light harvesting and light-driven electron transport for production of reducing power for CO2 fixation in prokaryotic cyanobacteria and eukaryotic microalgae.


Author(s):  
Huilin Hou ◽  
Gang Shao ◽  
Weiyou Yang

As one of fascinating visible-light-responsive photocatalysts, the two-dimensional (2D) graphitic carbon nitride (g-C3N4) has drawn broad attention in the field of solar energy conversion and environmental remediation. However, its intrinsic...


2016 ◽  
Vol 45 (3) ◽  
pp. 612-630 ◽  
Author(s):  
M. Rudolf ◽  
S. V. Kirner ◽  
D. M. Guldi

In this review article, we highlight recent advances in the field of solar energy conversion at a molecular level.


2019 ◽  
Vol 48 (18) ◽  
pp. 5861-5868 ◽  
Author(s):  
Andrea Pannwitz ◽  
Oliver S. Wenger

Fundamental aspects of PCET continue to attract attention. Understanding this reaction type is desirable for small-molecule activation and solar energy conversion.


2019 ◽  
Author(s):  
Juntai Liu ◽  
Vincent M. Friebe ◽  
Raoul N. Frese ◽  
Michael R. Jones

Natural photosynthesis can be divided between the chlorophyll-containing plants, algae and cyanobacteria that make up the oxygenic phototrophs and a diversity of bacteriochlorophyll-containing bacteria that make up the anoxygenic phototrophs. Photosynthetic light harvesting and reaction centre proteins from both groups of organisms have been exploited in a wide range of biohybrid devices for solar energy conversion, solar fuel synthesis and a variety of sensing technologies, but the energy harvesting abilities of these devices are limited by each protein’s individual palette of (bacterio)chlorophyll, carotenoid and bilin pigments. In this work we demonstrate a range of genetically-encoded, self-assembling photosystems in which recombinant plant light harvesting complexes are covalently locked with reaction centres from a purple photosynthetic bacterium, producing macromolecular chimeras that display mechanisms of polychromatic solar energy harvesting and conversion not present in natural systems. Our findings illustrate the power of a synthetic biology approach in which bottom-up construction of a novel photosystem using naturally disparate but mechanistically complementary components is achieved in a predictable fashion through the genetic encoding of adaptable, plug-and-play covalent interfaces.ToC image


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