A novel polyoxovanadate-based Co-MOF: highly efficient and selective oxidation of a mustard gas simulant by two-site synergetic catalysis

2020 ◽  
Vol 8 (25) ◽  
pp. 12398-12405 ◽  
Author(s):  
Hong-Rui Tian ◽  
Zhong Zhang ◽  
Shu-Mei Liu ◽  
Tian-Yi Dang ◽  
Xiao-Hui Li ◽  
...  

A polyoxovanadate-based cobalt organic framework (V–Co-MOF) was synthesized and it, as a heterogeneous catalyst, can catalyze the rapid selective oxidation of a mustard gas simulant to a non-toxic product by the two-site synergistic effect of VV and CoII.

RSC Advances ◽  
2016 ◽  
Vol 6 (101) ◽  
pp. 99096-99104 ◽  
Author(s):  
H. Ramezanalizadeh ◽  
F. Manteghi

In this work, a novel metal–organic framework based composite with BiFeO3 noted as MOF/BiFeO3 has been synthesized and successfully employed as a highly efficient heterogeneous and recoverable catalyst for oxidation of alcohols under mild conditions.


2015 ◽  
Vol 51 (72) ◽  
pp. 13818-13821 ◽  
Author(s):  
Carlos M. Granadeiro ◽  
Susana O. Ribeiro ◽  
Mohamed Karmaoui ◽  
Rita Valença ◽  
Jorge C. Ribeiro ◽  
...  

The porous metal–organic framework UiO-66(Zr) is a remarkable and highly efficient heterogeneous catalyst for the production of sulfur-free diesels.


2019 ◽  
Vol 48 (24) ◽  
pp. 8995-9003 ◽  
Author(s):  
Zheng Deng ◽  
Yi Guo ◽  
Zhuoyi Li ◽  
Xiaobin Wang ◽  
Xinsheng Peng ◽  
...  

Zn–Fc MOF hollow microspheres were prepared for the in situ reduction of Pd2+ into Pd nanoparticles as a highly efficient heterogeneous catalyst.


2019 ◽  
Vol 55 (95) ◽  
pp. 14347-14350 ◽  
Author(s):  
Dingxuan Ma ◽  
Yaowen Zhang ◽  
Shaoshao Jiao ◽  
Jixin Li ◽  
Kang Liu ◽  
...  

A novel tri-functional MOF catalyst was achieved by PSM method. Because of the synergistic effect of Lewis acid, Brønsted acid and Br− anion, MIL-IMAc-Br− displayed an efficient catalytic performance for CO2 conversion.


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