Instantaneous tension measurements in droplet interface bilayers using an inexpensive, integrated pendant drop camera

Soft Matter ◽  
2020 ◽  
Vol 16 (18) ◽  
pp. 4484-4493
Author(s):  
Justin Rofeh ◽  
Luke Theogarajan

Adding an inexpensive horizontal camera to a microscope stage yields faster, simpler, and more accurate measurements of droplet interface bilayers. Measurements of monolayer tension, bilayer tension, and specific capacitance are all improved.

Author(s):  
Mickey E. Gunter ◽  
F. Donald Bloss

A single, reasonably homogeneous, nonopaque 30-to-300 μm crystal, mounted on a spindle stage and studied by immersion methods under a polarizing microscope, yields optical data frequently sufficient to identify and characterize a substance unequivocally. The data obtainable include (1) the orientation of the crystal's principal vibration axes and (2) its principal refractive indices, to within 0.0002 if desired, for light vibrating along these principal vibration axes. Spindle stages tend to be simple and relatively inexpensive, some costing less than $50. They permit rotation of the crystal about a single axis which is parallel to the microscope stage. This spindle or S-axis is thus perpendicular to the M-axis, namely the microscope stage's axis of rotation.A spindle stage excels when studying anisotropic crystals. It orients uniaxial crystals within minutes and biaxial crystals almost as quickly so that their principal refractive indices - ɛ and ω (uniaxial); α, β and γ (biaxial) - can be determined without significant error from crystal misorientation.


2020 ◽  
Vol 13 (02) ◽  
pp. 2051007
Author(s):  
Jie Dong ◽  
Qinghao Yang ◽  
Qiuli Zhao ◽  
Zhenzhong Hou ◽  
Yue Zhou ◽  
...  

Electrode materials with a high specific capacitance, outstanding reversibility and excellent cycle stability are constantly pursued for supercapacitors. In this paper, we present an approach to improve the electrochemical performance by combining the advantages of both inorganic and organic. Ni-MnO2/PANi-co-PPy composites are synthesized, with the copolymer of aniline/pyrrole being coated on the surface of Ni-doped manganese dioxide nanospheres. The inorganic–organic composite enables a substantial increase in its specific capacitance and cycle stability. When the mass ratio of Ni-MnO2 to aniline and pyrrole mixed monomer is 1:5, the composite delivers high specific capacitance of 445.49[Formula: see text]F/g at a scan rate of 2[Formula: see text]mV/s and excellent cycle stability of 61.65% retention after 5000 cycles. The results indicate that the Ni-MnO2/PANi-co-PPy composites are promising electrode materials for future supercapacitors application.


2021 ◽  
Vol 27 ◽  
pp. 102292
Author(s):  
Wei Zeng ◽  
Qiannan Feng ◽  
Jiongliang Yuan

Author(s):  
Sudipta Biswas ◽  
Vikas Sharma ◽  
Trilok Singh ◽  
Amreesh Chandra

External vibrations can destroy the specific capacitance in supercapacitors. Carbon based supercapacitors show a higher ability to absorb the impacts of external vibrations, in comparison to metal oxide based pseudocapacitors.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Jeongpil Kim ◽  
Jeong-Hyun Eum ◽  
Junhyeok Kang ◽  
Ohchan Kwon ◽  
Hansung Kim ◽  
...  

AbstractHerein, we introduce a simple method to prepare hierarchical graphene with a tunable pore structure by activating graphene oxide (GO) with a two-step thermal annealing process. First, GO was treated at 600 °C by rapid thermal annealing in air, followed by subsequent thermal annealing in N2. The prepared graphene powder comprised abundant slit nanopores and micropores, showing a large specific surface area of 653.2 m2/g with a microporous surface area of 367.2 m2/g under optimized conditions. The pore structure was easily tunable by controlling the oxidation degree of GO and by the second annealing process. When the graphene powder was used as the supercapacitor electrode, a specific capacitance of 372.1 F/g was achieved at 0.5 A/g in 1 M H2SO4 electrolyte, which is a significantly enhanced value compared to that obtained using activated carbon and commercial reduced GO. The performance of the supercapacitor was highly stable, showing 103.8% retention of specific capacitance after 10,000 cycles at 10 A/g. The influence of pore structure on the supercapacitor performance was systematically investigated by varying the ratio of micro- and external surface areas of graphene.


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