Dispersing nano- and micro-sized portlandite particulates via electrosteric exclusion at short screening lengths

Soft Matter ◽  
2020 ◽  
Vol 16 (14) ◽  
pp. 3425-3435 ◽  
Author(s):  
Jason Timmons ◽  
Iman Mehdipour ◽  
Shang Gao ◽  
Hakan Atahan ◽  
Narayanan Neithalath ◽  
...  
Keyword(s):  
Layer Thickness ◽  
Steric Hindrance ◽  
Debye Length ◽  
Charge Screening ◽  
Coulombic Repulsion

Coulombic repulsion alone is insufficient to mitigate aggregation of suspensions with strong charge screening, while superior interparticle separations are created via steric hindrance when dispersant layer thickness exceeds the Debye length.

scholarly journals Going beyond the Debye Length: Overcoming Charge Screening Limitations in Next-Generation Bioelectronic Sensors

ACS Nano ◽  
2020 ◽  
Vol 14 (12) ◽  
pp. 16194-16201
Author(s):  
Vladimir Kesler ◽  
Boris Murmann ◽  
H. Tom Soh
Keyword(s):  
Debye Length ◽  
Next Generation ◽  
Charge Screening

scholarly journals Comparison Study on the Adsorption Behavior of Chemically Functionalized Graphene Oxide and Graphene Oxide on Cement

Materials ◽  
2020 ◽  
Vol 13 (15) ◽  
pp. 3274
Author(s):  
Min Wang ◽  
Hao Yao
Keyword(s):  
Graphene Oxide ◽  
Layer Thickness ◽  
Steric Hindrance ◽  
Adsorption Layer ◽  
Adsorption Behavior ◽  
Functionalized Graphene ◽  
Comparison Study ◽  
Chemical Functionalization ◽  
Adsorption Amount ◽  
Branched Chain

Chemical functionalization of graphene oxide (GO) is one kind of advanced strategy to eliminate the negative effects on the flowability of cement with GO. The adsorption behavior of admixture on cement plays a vital role in the flowability of cement-based materials. Herein, the comparison study on the adsorption behavior (including adsorption amount, adsorption kinetics, adsorption isotherms and adsorption layer thickness) of three kinds of chemically functionalized graphene oxides (CFGOs) with different polyether amine branched-chain lengths and GO on cement is reported. The results of CFGOs and GO adsorption data on cement particles were all best fitted with the pseudo-second-order kinetic model, and also conformed to the Freundlich isothermal model, indicating that the adsorption of CFGOs and GO on cement both were multilayer type and took place in a heterogeneous manner. The adsorption of CFGOs and GO on cement was not just physical adsorption, but also engaged chemical adsorption. In contrast to GO, the adsorption behavior of CFGOs on cement represented a lesser adsorption amount, weaker adsorption capacity and thinner adsorption layer thickness. Moreover, the longer the branched-chain length of CFGOs, the greater the decreasing degrees of adsorption amount, adsorption capacity and adsorption layer thickness. Due to the consumption of the carboxyl group (-COOH) by chemical functionalization, the anchoring effect of CFGOs was weaker than GO, and the steric hindrance effect generated from branched-chains which weakened the van der Waals forces among CFGOs layers. Moreover, the steric hindrance effect strengthened with the increasing branched-chain length, thus preventing the cement particles from aggregation, which resulted in satisfactory flowability of CFGOs with incorporation of cement rather than GO.

The 2D Debye length: An analytical study of weak charge screening in 2D semiconductors

2021 ◽  
Vol 129 (2) ◽  
pp. 024301
Author(s):  
Adina R. Bechhofer ◽  
Akiko Ueda ◽  
Ankur Nipane ◽  
James T. Teherani
Keyword(s):  
Analytical Study ◽  
Debye Length ◽  
Weak Charge ◽  
Charge Screening ◽  
2D Semiconductors

Structure and Orientation of As Precipitates in LT-MBE Grown GaAs

1991 ◽  
Vol 49 ◽  
pp. 900-901 ◽  
Author(s):  
Alain Claverie ◽  
Zuzanna Liliental-Weber
Keyword(s):  
Transport Properties ◽  
Layer Thickness ◽  
Growth Temperature ◽  
Low Temperatures ◽  
Lattice Parameter ◽  
Crystalline Quality ◽  
Insulating Properties ◽  
Lt Gaas

GaAs layers grown by MBE at low temperatures (in the 200°C range, LT-GaAs) have been reported to have very interesting electronic and transport properties. Previous studies have shown that, before annealing, the crystalline quality of the layers is related to the growth temperature. Lowering the temperature or increasing the layer thickness generally results in some columnar polycrystalline growth. For the best “temperature-thickness” combinations, the layers may be very As rich (up to 1.25%) resulting in an up to 0.15% increase of the lattice parameter, consistent with the excess As. Only after annealing are the technologically important semi-insulating properties of these layers observed. When annealed in As atmosphere at about 600°C a decrease of the lattice parameter to the substrate value is observed. TEM studies show formation of precipitates which are supposed to be As related since the average As concentration remains almost unchanged upon annealing.

The stabilization of B.C.C. Cu in Cu/Nb nanolayered composites

1996 ◽  
Vol 54 ◽  
pp. 228-229
Author(s):  
H. Kung ◽  
A.J. Griffin ◽  
Y.C. Lu ◽  
K.E. Sickafus ◽  
T.E. Mitchell ◽  
...  
Keyword(s):  
Electrical Resistivity ◽  
Layer Thickness ◽  
Volume Fraction ◽  
Ion Beam ◽  
High Strength ◽  
Cross Sectional ◽  
Metastable Structure ◽  
High Resolution Tem ◽  
Potential Improvement ◽  
Two Phases

Materials with compositionally modulated structures have gained much attention recently due to potential improvement in electrical, magnetic and mechanical properties. Specifically, Cu-Nb laminate systems have been extensively studied mainly due to the combination of high strength, and superior thermal and electrical conductivity that can be obtained and optimized for the different applications. The effect of layer thickness on the hardness, residual stress and electrical resistivity has been investigated. In general, increases in hardness and electrical resistivity have been observed with decreasing layer thickness. In addition, reduction in structural scale has caused the formation of a metastable structure which exhibits uniquely different properties. In this study, we report the formation of b.c.c. Cu in highly textured Cu/Nb nanolayers. A series of Cu/Nb nanolayered films, with alternating Cu and Nb layers, were prepared by dc magnetron sputtering onto Si {100} wafers. The nominal total thickness of each layered film was 1 μm. The layer thickness was varied between 1 nm and 500 nm with the volume fraction of the two phases kept constant at 50%. The deposition rates and film densities were determined through a combination of profilometry and ion beam analysis techniques. Cross-sectional transmission electron microscopy (XTEM) was used to examine the structure, phase and grain size distribution of the as-sputtered films. A JEOL 3000F high resolution TEM was used to characterize the microstructure.

Steric hindrance influence of a diazo link upon mesogenic properties of some ligands and related copper complexes

1997 ◽  
Vol 94 ◽  
pp. 1695-1714 ◽  
Author(s):  
P Lesot ◽  
F Perez ◽  
P Judeinstein ◽  
JP Bayle ◽  
H Allouchi ◽  
...  
Keyword(s):  
Steric Hindrance ◽  
Copper Complexes

On the Effect of 2-Layer Thickness by High-Specific Gravity Armor Blocks on Wave Reflection

1999 ◽  
Author(s):  
Masahiro Ito ◽  
Yuitch Iwagaki ◽  
Hiroshi Murakami ◽  
Kenji Nemoto ◽  
Masato Yamamoto ◽  
...  
Keyword(s):  
Specific Gravity ◽  
Layer Thickness ◽  
Wave Reflection ◽  
High Specific Gravity
Sign in / Sign up

Export Citation Format

Share Document