Prolongation of the singlet exciton lifetime of nonfullerene acceptor films by the replacement of the central benzene core with naphthalene

Author(s):  
Tomokazu Umeyama ◽  
Kensho Igarashi ◽  
Yasunari Tamai ◽  
Tatsuho Wada ◽  
Taiki Takeyama ◽  
...  

The replacement of benzene with naphthalene in the central core of an acceptor achieved a longer singlet lifetime and a higher power conversion efficiency.

2018 ◽  
Vol 42 (14) ◽  
pp. 11458-11464 ◽  
Author(s):  
Hong Chul Lim ◽  
Jang-Joo Kim ◽  
Jyongsik Jang ◽  
Jong-In Hong

The bulk heterojunction organic photovoltaic (OPV) devices based on 3T : PC71BM (2 wt%, 1 : 1.75 w/w) exhibited a higher power conversion efficiency of 2.58% than DTT-based OPV devices.


2020 ◽  
Vol 8 (12) ◽  
pp. 5995-6003 ◽  
Author(s):  
Shungang Liu ◽  
Wenyan Su ◽  
Xianshao Zou ◽  
Xiaoyan Du ◽  
Jiamin Cao ◽  
...  

Isomers of non-fullerene acceptors with pyrene as cores but fused at different positions were studied. FPIC6 possessed ∼119 nm of red-shift absorption and much higher power conversion efficiency of 11.55% as compared to its structural isomer FPIC5.


2020 ◽  
Vol 8 (33) ◽  
pp. 11638-11646 ◽  
Author(s):  
Wenxiao Gong ◽  
Heng Guo ◽  
Haiyan Zhang ◽  
Jian Yang ◽  
Haiyuan Chen ◽  
...  

Both wetting and non-wetting tin oxide SnO2 were spin-coated and the non-wetting electron transport layer demonstrated a larger perovskite and higher power conversion efficiency.


2021 ◽  
Vol 13 ◽  
Author(s):  
Soorya Sasi ◽  
Arya Sajeev ◽  
Sunish K. Sugunan ◽  
Pankajakshan Radhakrishnan Nair ◽  
Suresh Mathew

Background: Electrolyte is an essential constituent of a dye-sensitized solar cell (DSSC) as it mediates charge transport and regeneration of the oxidized dye. Iodide/triiodide (I- /I3-) based electrolytes are the ones widely being used in DSSCs. These types of electrolytes are usually made by dissolving high concentrations of triiodide and polyiodide species in solvents such as acetonitrile or methoxypropionitrile. These solvents face evaporation issues and lead to stability problems, thus reduce the life span of the DSSC. For solving these issues, various types of electrolytes such as ionic liquids, and gelated liquid electrolytes have been used to replace the conventional volatile electrolytes. Objective: To solve the solvent evaporation issue and increase in electric resistance, we aim to synthesis a nonvolatile electrolyte with excellent open-circuit voltage and stability. Method: A new genre of nonvolatile Co(II)/Co(III) redox electrolyte was synthesized by the reaction of tris(2-(1H-pyrazol-1-yl)pyridine)cobalt(II) and tris(2-(1H-pyrazol-1-yl)pyridine) cobalt(III) with 2,4,6-tris(dodecyloxy)benzaldehyde. As a proof-of-principle experiment, a DSSC was fabricated using the as-synthesized electrolyte, N-719 dye as the light harvester, and TiO2 as the photoanode and their performances were analyzed in room light conditions. Results: The DSSCs deliver a remarkable power conversion efficiency of 22.1%, an open circuit voltage of 1 V and a power output of 88.5 μW cm–2 at 1000 lux, under illumination from a deltron LED light. Conclusion: Cobalt based non-volatile electrolytes are efficient candidates that can replace the conventional volatile electrolytes in DSSCs. Further research into this new type of electrolyte could pave ways to deliver high open circuit voltage as well as good current density with high stability.


2019 ◽  
Vol 11 (31) ◽  
pp. 28078-28087 ◽  
Author(s):  
Loïc Tanguy ◽  
Prateek Malhotra ◽  
Surya Prakash Singh ◽  
Gessie Brisard ◽  
Ganesh D. Sharma ◽  
...  

2019 ◽  
Vol 7 (16) ◽  
pp. 9798-9806 ◽  
Author(s):  
Feilong Pan ◽  
Lianjie Zhang ◽  
Haiying Jiang ◽  
Dong Yuan ◽  
Yaowen Nian ◽  
...  

PBDB-T-SF : IDIC : ID4F ternary blend films show 11.52% power conversion efficiency, higher than 9.39% and 10.35% for the corresponding binary devices.


2014 ◽  
Vol 16 (37) ◽  
pp. 19874-19883 ◽  
Author(s):  
Yu Jin Kim ◽  
Kwang Hun Park ◽  
Jong-jin Ha ◽  
Dae Sung Chung ◽  
Yun-Hi Kim ◽  
...  

Compared toBDTO-TTPD,BDTEH-TTPDshowed stronger light absorption and longer-range ordering, which results in higher power conversion efficiency.


2020 ◽  
Vol 8 (46) ◽  
pp. 24543-24552
Author(s):  
Dongdong Cai ◽  
Jianqi Zhang ◽  
Jin-Yun Wang ◽  
Yunlong Ma ◽  
Shuo Wan ◽  
...  

The synergistic effect of end-group fluorination and side-chain engineering leads to a nonfullerene acceptor with an outstanding power conversion efficiency of 14.75%.


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