Understanding the effect of H2O on CO2 adsorption capture: mechanism explanation, quantitative approach and application

2020 ◽  
Vol 4 (12) ◽  
pp. 5970-5986
Author(s):  
Jie Zhao ◽  
Shuai Deng ◽  
Li Zhao ◽  
Xiangzhou Yuan ◽  
Zhenyu Du ◽  
...  
Keyword(s):  
Adsorption Energy ◽  
Competitive Adsorption ◽  
Co2 Adsorption ◽  
Quantitative Approach ◽  
Adsorption Behavior ◽  
Capture Mechanism

Competitive adsorption behavior of CO2 and H2O on MFI according to the Gibbs free adsorption energy.

Adsorption Behavior of Anionic Reactive Dyes on H‐type Activated Carbon: Competitive Adsorption and Desorption Studies

2007 ◽  
Vol 42 (10) ◽  
pp. 2195-2220 ◽  
Author(s):  
Musa I. El‐Barghouthi ◽  
Amjad H. El‐Sheikh ◽  
Yahya S. Al‐Degs ◽  
Gavin M. Walker
Keyword(s):  
Activated Carbon ◽  
Competitive Adsorption ◽  
Reactive Dyes ◽  
Adsorption Behavior ◽  
Adsorption And Desorption

Polyetheramine improves the CO2 adsorption behavior of tetraethylenepentamine-functionalized sorbents

2019 ◽  
Vol 364 ◽  
pp. 475-484 ◽  
Author(s):  
Xia Wang ◽  
Wulan Zeng ◽  
Mingjun Song ◽  
Fengli Wang ◽  
Xiude Hu ◽  
...  
Keyword(s):  
Co2 Adsorption ◽  
Adsorption Behavior

CO2 adsorption behavior and kinetics on polyethylenimine modified porous phenolic resin

2017 ◽  
Vol 24 (5) ◽  
pp. 1335-1342 ◽  
Author(s):  
Fenglei Liu ◽  
Shuixia Chen ◽  
Yanting Gao ◽  
Yufang Xie
Keyword(s):  
Phenolic Resin ◽  
Co2 Adsorption ◽  
Adsorption Behavior

Competitive adsorption behavior of hydrocarbon(s)/CO2 mixtures in a double-nanopore system using molecular simulations

Fuel ◽  
2019 ◽  
Vol 252 ◽  
pp. 612-621 ◽  
Author(s):  
Yueliang Liu ◽  
Xiaomin Ma ◽  
Huazhou Andy Li ◽  
Jian Hou
Keyword(s):  
Competitive Adsorption ◽  
Molecular Simulations ◽  
Adsorption Behavior

scholarly journals Removal Effect of Atrazine in Co-Solution with Bisphenol A or Humic Acid by Different Activated Carbons

Materials ◽  
2018 ◽  
Vol 11 (12) ◽  
pp. 2558 ◽  
Author(s):  
Zhansheng Wu ◽  
Xinhui Wei ◽  
Yongtao Xue ◽  
Xiufang He ◽  
Xia Yang
Keyword(s):  
Humic Acid ◽  
Bisphenol A ◽  
Adsorption Kinetics ◽  
Competitive Adsorption ◽  
Activated Carbons ◽  
Second Order ◽  
Adsorption Behavior ◽  
Single Solution ◽  
Pseudo Second Order ◽  
Kinetics Of

Activated carbons (ACs) based on apricot shells (AS), wood (W), and walnut shells (WS) were applied to adsorb atrazine in co-solutions. To study the effect of Bisphenol A (BPA) on the adsorption behavior of atrazine, the adsorption performance of ACs for BPA in single solution was studied. The results demonstrated that the adsorption kinetics of BPA fitted the pseudo-second-order model, the adsorption isotherms of BPA followed the Langmuir model. Meanwhile, the adsorption kinetics of atrazine fitted the pseudo-second-order kinetics model and the isotherm was consistent with the Freundlich model both in single solution and co-solution. In addition, competitive adsorption was observed when atrazine coexisted with BPA or humic acid. For the adsorption capacity, the adsorption amount of ASAC, WAC, and WSAC for atrazine obviously decreased by 18.0%, 30.0%, and 30.3% in the presence of BPA, respectively, which was due to the π−π interactions, hydrophobic interactions, and H-bonds, resulting in the competitive adsorption between atrazine and BPA. This study contributes to the further understanding of the adsorption behavior for atrazine in co-solution.

Adsorption behavior of tautomeric forms of 2-aminino-5-mercato-1,3,4 – thiadizole as corrosion inhibitor on copper surface

2016 ◽  
Vol 63 (6) ◽  
pp. 452-460 ◽  
Author(s):  
Sang Xiong ◽  
Jianlin Sun ◽  
Yang Xu ◽  
Xundong Yan
Keyword(s):  
Weight Loss ◽  
Corrosion Inhibitor ◽  
Adsorption Energy ◽  
Copper Surface ◽  
Adsorption Behavior ◽  
Weight Loss Measurement ◽  
Content Type ◽  
Loss Measurement ◽  
Polar Groups ◽  
Tautomeric Forms

Purpose The purpose of this study is to evaluate the effect of the four tautomeric forms of 2-amino-5-mercatpo-1,3,4-thiadizole (AMT) absorbed on copper surface by the polar or non-polar groups. Polar group of AMT is mostly electronegative with larger N and S atoms as central atoms. 5-amino-1,3,4-thiadiazole-2(3H)-thion (AMT-c) has the highest adsorption energy and is easy to react with copper. The interaction between AMT-c and copper conforms to chemisorption, which is to be further verified by the experiment on the weight loss measurement. Design/methodology/approach Adsorption behavior of AMT as corrosion inhibitor on copper surface in oil field was studied by weight loss measurement, and the corrosion inhibition mechanism was analyzed. Reactive sites and distributions of tautomeric forms of AMT as inhibitor on Cu(100) crystal plane were calculated by density functional theory. Findings All atoms of AMT are in the same plane, and AMT is an aromatic ring structure by large p-chain adsorbed on the metal surface by a plane configuration. AMT-c has the highest adsorption energy and also the most stable isomerized product. The determinate locations of AMT on the Cu(100) surface are the bridge and the hollow sites using molecular dynamics. Corrosion of copper can be effectively inhibited by AMT, which is a kind of excellent corrosion inhibitor, and this property is attributed to the polar groups and non-polar groups of AMT that play a role as absorption and shielding on copper surface, respectively. Inhibition efficiency is increased with the increase in the concentration of the inhibitor. The maximum efficiency of 92 per cent is obtained for 50 ppm AMT concentration at 373 K, which is attributed to the presence of extensively delocalized electrons of the phenyl rings, planarity and the presence of lone pair of electrons on N and S atoms, which favored a greater adsorption of inhibitors on copper surface. Originality/value Corrosion of copper can be effectively inhibited by AMT, which is a kind of excellent corrosion inhibitor, and this property is attributed to the polar groups and non-polar groups of AMT that play a role as absorption and shielding on copper surface, respectively. Adsorption of AMT as corrosion inhibitor on copper surface obeys Langmuir isotherm. The interaction between AMT and copper conforms to chemisorption, which is to be further verified by the experiment on the weight loss measurement.

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