scholarly journals Nanoscale Electrochemistry in a Copper/Aqueous/Oil Three-phase System: Surface Structure-Activity-Corrosion Potential Relationships 

2021 ◽  
Author(s):  
Enrico Daviddi ◽  
Viacheslav Shkirskiy ◽  
Paul Kirkman ◽  
Mathew P Robin ◽  
Cameron Luke Bentley ◽  
...  

Practically important metal electrodes are usually polycrystalline, comprising surface grains of many different crystallographic orientations, as well as grain boundaries. In this study, scanning electrochemical cell microscopy (SECCM) is applied...

2018 ◽  
Vol 54 (24) ◽  
pp. 3053-3056 ◽  
Author(s):  
Sharel P. E ◽  
Minkyung Kang ◽  
Paul Wilson ◽  
Lingcong Meng ◽  
David Perry ◽  
...  

A strong relationship between the surface structure and the redox activity of Li2O2 is visualized directly using scanning electrochemical cell microscopy, employing a dual-barrel nanopipette containing a unique gel polymer electrolyte.


2017 ◽  
Vol 4 (1) ◽  
pp. 1386364 ◽  
Author(s):  
S. Asha Kiranmai ◽  
A. Jaya Laxmi ◽  
Qingsong Ai

1981 ◽  
Vol 59 (1) ◽  
pp. 127-131 ◽  
Author(s):  
Alan N. Campbell

The properties named in the title have been determined by standard methods. Viscosity, molar volume, and orientation polarisation all indicate abnormalities of the nature of association between the components.The most interesting result is that of surface tension which indicates that, in the case of the binary system triethylamine–water, a surface layer of constant composition is formed over a wide range of total composition. When, by a rise in temperature of two or three degrees, this layer becomes unstable, it splits into two phases of different composition. The surface layer may then be instantaneously reformed and so on. A mechanism for the generation of a two-phase system is thus established. The data for the three-phase, isothermal, system are not so convincing, for reasons that are suggested.


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