scholarly journals Photoredox-Enabled 1,2-Dialkylation of α-Substituted Acrylates via Ireland–Claisen Rearrangement

2021 ◽  
Author(s):  
Roman Kleinmans ◽  
Leon E. Will ◽  
J. Luca Schwarz ◽  
Frank Glorius
Keyword(s):  
Carboxylic Acids ◽  
Claisen Rearrangement ◽  
Radical Addition ◽  
Type Radical

Herein, we report the 1,2-dialkylation of simple feedstock acrylates for the synthesis of valuable tertiary carboxylic acids by merging Giese-type radical addition with an Ireland–Claisen rearrangement. Key to success is...

Radical addition to acrylonitrile via catalytic photochemical decarboxylation of aliphatic carboxylic acids

2013 ◽  
Vol 54 (32) ◽  
pp. 4324-4326 ◽  
Author(s):  
Yasuharu Yoshimi ◽  
Sonoka Washida ◽  
Yoshiki Okita ◽  
Keisuke Nishikawa ◽  
Kousuke Maeda ◽  
...  
Keyword(s):  
Carboxylic Acids ◽  
Radical Addition ◽  
Aliphatic Carboxylic Acids

Expanding the Scope of the Acyl-Type Radical Addition Reactions Promoted by SmI2

2006 ◽  
Vol 71 (21) ◽  
pp. 8219-8226 ◽  
Author(s):  
Jakob Karaffa ◽  
Karl B. Lindsay ◽  
Troels Skrydstrup
Keyword(s):  
Radical Addition ◽  
Addition Reactions ◽  
Type Radical

scholarly journals Synthesis of Functionalized Cyclopropanes from Carboxylic Acids by a Radical Addition–Polar Cyclization Cascade

2018 ◽  
Vol 57 (47) ◽  
pp. 15430-15434 ◽  
Author(s):  
Chao Shu ◽  
Riccardo S. Mega ◽  
Björn J. Andreassen ◽  
Adam Noble ◽  
Varinder K. Aggarwal
Keyword(s):  
Carboxylic Acids ◽  
Radical Addition

Transition metal-free, visible-light-mediated construction of α,β-diamino esters via decarboxylative radical addition at room temperature

2019 ◽  
Vol 6 (13) ◽  
pp. 2245-2249 ◽  
Author(s):  
Guibing Wu ◽  
Jingwen Wang ◽  
Chengyu Liu ◽  
Maolin Sun ◽  
Lei Zhang ◽  
...  
Keyword(s):  
Transition Metal ◽  
Visible Light ◽  
Carboxylic Acids ◽  
Room Temperature ◽  
Radical Addition ◽  
Metal Free ◽  
Radical Coupling

A metal-free photoredox catalyzed decarboxylative radical coupling of free-carboxylic acids and glyoxylic oximes was developed to synthesize α,β-diamino acids.

ChemInform Abstract: Radical Addition to Acrylonitrile via Catalytic Photochemical Decarboxylation of Aliphatic Carboxylic Acids.

ChemInform ◽  
2013 ◽  
Vol 44 (46) ◽  
pp. no-no
Author(s):  
Yasuharu Yoshimi ◽  
Sonoka Washida ◽  
Yoshiki Okita ◽  
Keisuke Nishikawa ◽  
Kousuke Maeda ◽  
...  
Keyword(s):  
Carboxylic Acids ◽  
Radical Addition ◽  
Aliphatic Carboxylic Acids
Sign in / Sign up

Export Citation Format

Share Document