scholarly journals Advances in anion binding and sensing using luminescent lanthanide complexes

2021 ◽  
Author(s):  
Samantha E. Bodman ◽  
Stephen J. Butler
Keyword(s):  
Lanthanide Complexes ◽  
Anion Binding

This minireview highlights advances in anion binding and sensing using luminescent lanthanide(iii) complexes.

scholarly journals Using Remote Substituents to Control Solution Structure and Anion Binding in Lanthanide Complexes

2013 ◽  
Vol 19 (49) ◽  
pp. 16566-16571 ◽  
Author(s):  
Manuel Tropiano ◽  
Octavia A. Blackburn ◽  
James A. Tilney ◽  
Leila R. Hill ◽  
Matteo P. Placidi ◽  
...  
Keyword(s):  
Lanthanide Complexes ◽  
Solution Structure ◽  
Anion Binding ◽  
Control Solution

Influence of metal–ligand ratio on benzimidazole based luminescent lanthanide complexes: 3-D network structures and chloride anion binding

2011 ◽  
Vol 35 (2) ◽  
pp. 310-318 ◽  
Author(s):  
Xiaoping Yang ◽  
Richard A. Jones ◽  
Michael M. Oye ◽  
Michael Wiester ◽  
Rachel J. Lai
Keyword(s):  
Lanthanide Complexes ◽  
Chloride Anion ◽  
Anion Binding ◽  
Network Structures ◽  
Ligand Ratio ◽  
Metal Ligand

scholarly journals Tuning the anion binding properties of lanthanide receptors to discriminate nucleoside phosphates in a sensing array

2020 ◽  
Vol 11 (14) ◽  
pp. 3619-3628 ◽  
Author(s):  
Sarah H. Hewitt ◽  
Georgina Macey ◽  
Romain Mailhot ◽  
Mark R. J. Elsegood ◽  
Fernanda Duarte ◽  
...  
Keyword(s):  
Lanthanide Complexes ◽  
Anion Binding ◽  
Binding Properties ◽  
Phosphate Anions

Discrimination of nucleoside phosphate anions in the first supramolecular sensing array using luminescent lanthanide complexes.

scholarly journals Cover Picture: Using Remote Substituents to Control Solution Structure and Anion Binding in Lanthanide Complexes (Chem. Eur. J. 49/2013)

2013 ◽  
Vol 19 (49) ◽  
pp. 16481-16481
Author(s):  
Manuel Tropiano ◽  
Octavia A. Blackburn ◽  
James A. Tilney ◽  
Leila R. Hill ◽  
Matteo P. Placidi ◽  
...  
Keyword(s):  
Lanthanide Complexes ◽  
Solution Structure ◽  
Anion Binding ◽  
Control Solution

The Ability of Thrombin Inhibitors to Reduce the Thrombin Activity Generated in Plasma on Extrinsic and Intrinsic Activation

1997 ◽  
Vol 77 (03) ◽  
pp. 498-503 ◽  
Author(s):  
D Prasa ◽  
L Svendsen ◽  
J Stürzebecher
Keyword(s):  
Active Site ◽  
Thrombin Generation ◽  
Anion Binding ◽  
Thrombin Inhibitors ◽  
Coagulation System ◽  
Thrombin Activity ◽  
Continuous Registration ◽  
High Concentrations ◽  
20 Nm ◽  
Generation Test

SummaryIn a thrombin generation test with continuous registration of thrombin activity in plasma we studied the ability of a variety of thrombin inhibitors of different type and mechanism of action to influence the activity of thrombin after activation of the coagulation system. Depending on the inhibitor, the peak of thrombin activity is delayed and/or reduced.By blocking the active site of generated thrombin inhibitors cause a concentration dependent reduction of the thrombin peak and inhibit feed-back reactions of thrombin resulting in a delay of thrombin generation. Highly potent synthetic active-site directed inhibitors (Ki ≤ 20 nM) reduce the thrombin activity formed in plasma after extrinsic or intrinsic activation with the same efficiency (IC50 0.1 - 0.6 μM) as hirudin. The delay and reduction of thrombin generation by inhibitors of the anion-binding exosite 1 of thrombin is only attributed to an inhibition of feed-back reactions of thrombin. For a 50% reduction of thrombin activity in plasma by this type of inhibitors relatively high concentrations were determined.

Cambiarenes: Single-Step Synthesis and Anion Binding of a Clip- Shaped Macrocycle with a Redox-Active Core

2019 ◽  
Author(s):  
Riley J. Petersen ◽  
Brett J. Rozeboom ◽  
Shalisa Oburn ◽  
Nolan Blythe ◽  
Tanner Rathje ◽  
...  
Keyword(s):  
Electron Density ◽  
Single Step ◽  
Anion Binding ◽  
Host Molecule ◽  
Selective Binding ◽  
The Core ◽  
Redox Active ◽  
Active Core ◽  
Guest Binding

<div>We report the synthesis of a novel macrocyclic host molecule that forms in a single step from commercially available starting materials. The core of the macrocycle backbone possesses two quinone rings and, thus, is redox-active. Host-guest binding involving the clip-shaped cavity indicates selective binding of pyridine <i>N</i>-oxides based of the electron density of and steric bulk of the anionic oxygen.</div>

Lanthanide Complexes in FRET Applications

2011 ◽  
Vol 1 (1) ◽  
pp. 17-35
Author(s):  
Daniel Geibler ◽  
Hildebrandt Niko
Keyword(s):  
Lanthanide Complexes

scholarly journals Effects of anion binding on the deprotonation reactions of halorhodopsin.

1986 ◽  
Vol 261 (6) ◽  
pp. 2690-2696 ◽  
Author(s):  
B Schobert ◽  
J K Lanyi ◽  
D Oesterhelt
Keyword(s):  
Anion Binding
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