scholarly journals Synthesis, Bonding Properties and Ether Activation Reactivity of Cyclobutadienyl-Ligated Hybrid Uranocenes

2021 ◽  
Author(s):  
Nikolaos Tsoureas ◽  
Akseli Mansikkamäki ◽  
Richard Layfield
Keyword(s):  
Bonding Properties

A series of hybrid uranocenes consisting of uranium(IV) sandwiched between cyclobutadienyl (Cb) and cyclo-octatetraenyl (COT) ligands has been synthesized, structurally characterized and studied computationally. The dimetallic species [(η4-Cb'''')(η8-COT)U(μ:η2:η8-COT)U(THF)(η4-Cb'''')] (1) forms...

scholarly journals H2O coordination in macropa complexes of f elements (Ac, La, Lu): feasibility of the 11th coordination site

2021 ◽  
Author(s):  
Attila Kovács ◽  
Zoltán Varga
Keyword(s):  
Aqueous Solution ◽  
Metal Ion ◽  
Density Functional ◽  
Molecular Level ◽  
Density Functional Theory Calculations ◽  
Functional Theory ◽  
Coordination Site ◽  
Additional Ligand ◽  
Ligand Coordination ◽  
Bonding Properties

AbstractThe feasibility of an additional ligand coordination at the 11th coordination site of actinium, lanthanum, and lutetium ions in 10-fold coordinated macropa complexes has been studied by means of density functional theory calculations. The study covered the two main macropa conformers, Δ(δλδ)(δλδ) and Δ(λδλ)(λδλ), favoured by larger (Ac3+, La3+) and smaller (Lu3+) ions, respectively. At the molecular level, the coordination of H2O is the most favourable to the largest Ac3+ while only slightly less to La3+. Protonation of the picoline arms enhances the coordination by shifting the metal ion closer to the open site of the ligand. The choice of macropa conformer has only a slight influence on the strength and bonding properties of the H2O coordination. Aqueous solution environment decreases considerably the energy gain of H2O coordination at the 11th coordination site.

scholarly journals Wave functions, electronic localization, and bonding properties for correlated materials beyond the Kohn-Sham formalism

2021 ◽  
Vol 103 (3) ◽  
Author(s):  
A. D. N. James ◽  
E. I. Harris-Lee ◽  
A. Hampel ◽  
M. Aichhorn ◽  
S. B. Dugdale
Keyword(s):  
Wave Functions ◽  
Bonding Properties ◽  
Electronic Localization

scholarly journals Time efficient laser modification of steel surfaces for advanced bonding in hybrid materials

2020 ◽  
Author(s):  
D. Voswinkel ◽  
D. Kloidt ◽  
O. Grydin ◽  
M. Schaper
Keyword(s):  
Adhesive Bonding ◽  
Scanning Speed ◽  
Laser Source ◽  
Lap Shear ◽  
Carbon Fibre Reinforced Polymer ◽  
Bonding Properties ◽  
Fibre Reinforced Polymer ◽  
Yvo4 Laser ◽  
Steel Surfaces ◽  
High Scanning Speed

AbstractLaser surface treatment of metals is one option to improve their properties for adhesive bonding. In this paper, a pulsed YVO4 Laser source with a wavelength of 1064 nm and a maximum power of 25 W was utilized to increase the surface area of the steel HCT490X in order to improve its bonding properties with a carbon fibre reinforced polymer (CFRP). Investigated was the influence of the scanning speed of the laser source on the bonding properties. For this purpose, the steel surfaces were ablated at a scanning speed between 1500 and 4500 mm/s. Afterwards the components were bonded with the adhesive HexBond™ 677. After lap shear tests were carried out on the specimen, the surfaces were inspected using scanning electron microscopy (SEM). The experiments revealed that the bonding quality can be improved with a high scanning speed, even when the surface is not completely ablated.

The hydrogen-bonding properties of a room temperature phosphorescence cellulose substrate

1986 ◽  
Vol 90 (21) ◽  
pp. 4941-4945 ◽  
Author(s):  
Georg W. Suter ◽  
Alan J. Kallir ◽  
Urs P. Wild ◽  
Tuan Vo-Dinh
Keyword(s):  
Hydrogen Bonding ◽  
Room Temperature ◽  
Room Temperature Phosphorescence ◽  
Cellulose Substrate ◽  
Bonding Properties

New Research on the Use of Hardening Plastics for Aircraft Construction

1940 ◽  
Vol 44 (349) ◽  
pp. 44-73
Author(s):  
Wilhelm Kuech
Keyword(s):  
Strength Properties ◽  
Dynamic Loads ◽  
Absorbed Energy ◽  
Good Strength ◽  
Different Temperatures ◽  
Bonding Properties ◽  
Static And Dynamic Loads ◽  
Impact Bending ◽  
New Research ◽  
Laminated Materials

Laminated materials incorporating plastics seem to be especially well suited lor highly stressed aircraft components, by reason of their good strength properties. Paper, fabric and wood veneers treated with plastics on a phenolic basis were tested with regard to their strength, especially in bending, shear, absorbed energy in impact bending, notching strength and in their resistance against moisture. Further, the behaviour of compressed plastics was studied at different temperatures under static and dynamic loads. A part of the research was extended to pure phenol resin and to thermoplastics based on methacrylate and polyvinylchloride. The bonding properties of laminated compressed plastics were established. Concluding, some experiments relating to the practical manufacture of aeroplane components are communicated.

scholarly journals Uranium(iv) cyclobutadienyl sandwich compounds: synthesis, structure and chemical bonding

2020 ◽  
Vol 56 (6) ◽  
pp. 944-947 ◽  
Author(s):  
Nikolaos Tsoureas ◽  
Akseli Mansikkamäki ◽  
Richard A. Layfield
Keyword(s):  
Chemical Bonding ◽  
Molecular Structures ◽  
Sandwich Complexes ◽  
Sandwich Complex ◽  
Sandwich Compounds ◽  
Bonding Properties ◽  
Half Sandwich

The synthesis, molecular structures and bonding properties of two uranium(iv) cyclobutadienyl half-sandwich complexes and a doubly activated cyclobutadienyl sandwich complex are described.

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