scholarly journals Structure and redox tuning of gas adsorption properties in calixarene-supported Fe(ii)-based porous cages

2020 ◽  
Vol 11 (20) ◽  
pp. 5273-5279 ◽  
Author(s):  
Meaghan M. Deegan ◽  
Tonia S. Ahmed ◽  
Glenn P. A. Yap ◽  
Eric D. Bloch
Keyword(s):  
Gas Adsorption ◽  
Adsorption Properties ◽  
Structural Modifications ◽  
Redox Tuning ◽  
Redox Reactivity ◽  
Coordination Cages

We describe the synthesis of Fe(ii)-based coordination cages whose stability and gas adsorption properties can be tuned through structural modifications and redox reactivity.

scholarly journals Gas Porosimetry by Gas Adsorption as an Efficient Tool for the Assessment of the Shaping Effect in Commercial Zeolites

Nanomaterials ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 1205
Author(s):  
Alejandro Orsikowsky-Sanchez ◽  
Christine Franke ◽  
Alexander Sachse ◽  
Eric Ferrage ◽  
Sabine Petit ◽  
...  
Keyword(s):  
Ir Spectroscopy ◽  
Strong Interaction ◽  
Gas Adsorption ◽  
Co2 Adsorption ◽  
Adsorption Properties ◽  
Preparation Process ◽  
Pore Filling ◽  
Irreversible Adsorption ◽  
Efficient Tool ◽  
4A Zeolite

A set of three commercial zeolites (13X, 5A, and 4A) of two distinct shapes have been characterized: (i) pure zeolite powders and (ii) extruded spherical beads composed of pure zeolite powders and an unknown amount of binder used during their preparation process. The coupling of gas porosimetry experiments using argon at 87 K and CO2 at 273 K allowed determining both the amount of the binder and its effect on adsorption properties. It was evidenced that the beads contain approximately 25 wt% of binder. Moreover, from CO2 adsorption experiments at 273 K, it could be inferred that the binder present in both 13X and 5A zeolites does not interact with the probe molecule. However, for the 4A zeolite, pore filling pressures were shifted and strong interaction with CO2 was observed leading to irreversible adsorption of the probe. These results have been compared to XRD, IR spectroscopy, and ICP-AES analysis. The effect of the binder in shaped zeolite bodies can thus have a crucial impact on applications in adsorption and catalysis.

The synthesis, characterization, and theoretical hydrogen gas adsorption properties of copper(II)-3,3′-thiodipropionate complexes with imidazole derivatives

2013 ◽  
Vol 66 (23) ◽  
pp. 4093-4106 ◽  
Author(s):  
Mürsel Arici ◽  
Okan Zafer Yeşılel ◽  
Seda Keskın ◽  
Onur Şahın ◽  
Orhan Büyükgüngör
Keyword(s):  
Gas Adsorption ◽  
Adsorption Properties ◽  
Hydrogen Gas ◽  
Imidazole Derivatives

Effects of electric field and biaxial strain on the (NO2, NO, O2, and SO2) gas adsorption properties of Sc2CO2 monolayer

2021 ◽  
pp. 107135
Author(s):  
Khang D. Pham ◽  
Pham Cong Dinh ◽  
Do Van Diep ◽  
Tuan V. Vu ◽  
Hai L. Luong ◽  
...  
Keyword(s):  
Electric Field ◽  
Gas Adsorption ◽  
Adsorption Properties ◽  
Biaxial Strain ◽  
So2 Gas

scholarly journals Statistical Thermodynamic Model of Gas Adsorption in a Metal-Organic Framework Harboring a Rotaxane Molecular Shuttle

2019 ◽  
Author(s):  
Jonathan Carney ◽  
David Roundy ◽  
Cory M. Simon
Keyword(s):  
Thermodynamic Model ◽  
Gas Adsorption ◽  
Metal Organic Framework ◽  
Adsorption Properties ◽  
Statistical Thermodynamic ◽  
Temperature Sensitive ◽  
Adsorption Sites ◽  
Metal Organic ◽  
Dynamic Components ◽  
Molecular Shuttle

Metal-organic frameworks (MOFs) are modular and adjustable nano-porous materials with applications in gas storage, separations, and sensing. Flexible/dynamic components that respond to adsorbed gas can give MOFs unique or enhanced adsorption properties. Here, we explore the adsorption properties that could be imparted to a MOF by a rotaxane molecular shuttle (RMS) in its pores. In an RMS-MOF, a macrocyclic wheel is mechanically interlocked with a strut. The wheel shuttles between stations on the strut that are also gas adsorption sites. We pose and analyze a simple statistical thermodynamic model of gas adsorption in an RMS-MOF that accounts for (i) wheel/gas competition for sites on the strut and (ii) the entropy endowed by the shuttling wheel. We determine how the amount of gas adsorbed, position of the wheel, and energy change upon adsorption depend on temperature, pressure, and the interactions of the gas/wheel with the stations. Our model reveals that, compared to an ordinary Langmuir material, the chemistry of the RMS-MOF can be tuned to render adsorption more or less temperature-sensitive and release more or less heat upon adsorption. The model also uncovers a non-monotonic relationship between temperature and the position of the wheel if gas out-competes the wheel for its preferable station.

scholarly journals Statistical Mechanical Model of Gas Adsorption in a Metal-Organic Framework Harboring a Rotaxane Molecular Shuttle

2020 ◽  
Author(s):  
Jonathan Carney ◽  
David Roundy ◽  
Cory M. Simon
Keyword(s):  
Mechanical Model ◽  
Gas Adsorption ◽  
Adsorption Properties ◽  
Temperature Sensitive ◽  
Adsorption Model ◽  
Adsorption Sites ◽  
Statistical Mechanical Model ◽  
Metal Organic ◽  
Statistical Mechanical ◽  
Molecular Shuttle

Metal-organic frameworks (MOFs) are modular and tunable nano-porous materials with applications in gas storage, separations, and sensing. Flexible/dynamic components that respond to adsorbed gas can give MOFs unique or enhanced adsorption properties. Here, we explore the adsorption properties that could be imparted to a MOF by a rotaxane molecular shuttle (RMS) in its pores. In the unit cell of an RMS-MOF, a macrocyclic wheel is mechanically interlocked with a strut of the MOF scaffold. The wheel shuttles between stations on the strut that are also gas adsorption sites. At a level of abstraction similar to the seminal Langmuir adsorption model, we pose and analyze a simple statistical mechanical model of gas adsorption in an RMS-MOF that accounts for (i) wheel/gas competition for sites on the strut and (ii) gas-induced changes in the configurational entropy of the shuttling wheel. We determine how the amount of gas adsorbed, position of the wheel, and differential energy of adsorption depend on temperature, pressure, and the interactions of the gas/wheel with the stations. Our model reveals that, compared to a rigid, Langmuir material, the chemistry of the RMS-MOF can be tuned to render gas adsorption more or less temperature-sensitive and to release more or less heat upon adsorption. The model also uncovers a non-monotonic relationship between the temperature and the position of the wheel if gas out-competes the wheel for its preferable station.

Three ligand-originated MOF isomers: the positional effect of the methyl group on structures and selective C2H2/CH4 and CO2/CH4 adsorption properties

2018 ◽  
Vol 47 (27) ◽  
pp. 8983-8991 ◽  
Author(s):  
Minghui He ◽  
Yao Wang ◽  
Xiaoxia Gao ◽  
Saidan Li ◽  
Yabing He
Keyword(s):  
Gas Adsorption ◽  
Adsorption Properties ◽  
Methyl Group ◽  
Positional Effect ◽  
Ch4 Adsorption

The positional effect of the methyl group on structures and gas adsorption properties was explored in a copper-based MOF platform constructed from bent diisophthalate ligands bearing the methyl group at different positions.

Three isoreticular MOFs derived from nitrogen-functionalized diisophthalate ligands: exploring the positional effect of nitrogen functional sites on the structural stabilities and selective C2H2/CH4 and CO2/CH4 adsorption properties

2018 ◽  
Vol 5 (6) ◽  
pp. 1423-1431 ◽  
Author(s):  
Dongjie Bai ◽  
Xiaoxia Gao ◽  
Minghui He ◽  
Yao Wang ◽  
Yabing He
Keyword(s):  
Structural Stability ◽  
Gas Adsorption ◽  
Adsorption Property ◽  
Adsorption Properties ◽  
Functional Sites ◽  
Positional Effect ◽  
Ch4 Adsorption

The positional effect of nitrogen functional sites on the structural stability and gas adsorption property was explored in a family of ssa-type MOFs.

scholarly journals Flexible monomer-based covalent organic frameworks: design, structure and functions

CrystEngComm ◽  
2017 ◽  
Vol 19 (33) ◽  
pp. 4868-4871 ◽  
Author(s):  
Lanfang Zou ◽  
Xinyu Yang ◽  
Shuai Yuan ◽  
Hong-Cai Zhou
Keyword(s):  
Gas Adsorption ◽  
Adsorption Properties ◽  
Covalent Organic Frameworks ◽  
Design Structure ◽  
Structure And Functions

A new flexible monomer-based COF has been designed and synthesized and its structure and gas adsorption properties have been carefully investigated.

Sign in / Sign up

Export Citation Format

Share Document