scholarly journals A chiral cobalt(ii) complex catalyzed enantioselective aza-Piancatelli rearrangement/Diels–Alder cascade reaction

2020 ◽  
Vol 11 (15) ◽  
pp. 3862-3867 ◽  
Author(s):  
Bin Shen ◽  
Qianwen He ◽  
Shunxi Dong ◽  
Xiaohua Liu ◽  
Xiaoming Feng

An asymmetric aza-Piancatelli rearrangement/Diels–Alder cascade reaction between 2-furylcarbinols and N-(furan-2-ylmethyl)anilines was realized by using a chiral N,N′-dioxide/cobalt(ii) complex catalyst.

Author(s):  
Mohammad Bagher Teimouri ◽  
Zahra Mokhtare ◽  
Hamid Reza Khavasi

Three new chemical bonds and three stereogenic centres and one heterocyclic ring were assembled stereoselectively in a convenient high atom-economy one-pot operation.


Carbon ◽  
2016 ◽  
Vol 98 ◽  
pp. 421-431 ◽  
Author(s):  
Rui Filipe Araújo ◽  
Maria Fernanda Proença ◽  
Carlos Jorge Silva ◽  
Tarsila G. Castro ◽  
Manuel Melle-Franco ◽  
...  

2018 ◽  
Vol 5 (24) ◽  
pp. 3574-3578 ◽  
Author(s):  
Yangyong Shen ◽  
Chaorong Wang ◽  
Wei Chen ◽  
Sunliang Cui

A cascade reaction involving Diels–Alder reaction for modular synthesis of amino α-pyrones, indolines and anilines is reported.


ChemInform ◽  
2015 ◽  
Vol 46 (28) ◽  
pp. no-no
Author(s):  
Jin-Bao Peng ◽  
Yue Qi ◽  
Ze-Ran Jing ◽  
Shao-Hua Wang ◽  
Yong-Qiang Tu ◽  
...  

Synlett ◽  
2017 ◽  
Vol 28 (14) ◽  
pp. 1758-1762 ◽  
Author(s):  
Duy Mai ◽  
Dmitriy Uchenik ◽  
Christopher Vanderwal

Two synthesis designs for the diterpenoid crotogoudin are discussed, and efforts to achieve each are described. First, a Cope rearrangement/intramolecular Diels–Alder cascade reaction was investigated. Second, a bioinspired sequence of cationic bicyclization and A-ring oxidative fragmentation set-up for a lactonization induced by a phenolic oxidation, ultimately providing a tricyclic intermediate that required only installation of the bridging ring of the salient bicyclo[2.2.2]octane system. This last endeavor was fraught with difficulty, but did lead to the development of conditions for cyclization of related keto-alkenes via manganese(III)-based radical chemistry.


2016 ◽  
Vol 138 (39) ◽  
pp. 12739-12742 ◽  
Author(s):  
Feng Xu ◽  
Kyle W. Hershey ◽  
Russell J. Holmes ◽  
Thomas R. Hoye

2016 ◽  
Vol 23 (1) ◽  
pp. 3-3
Author(s):  
Yang Li ◽  
Casper Barløse ◽  
Julie Jørgensen ◽  
Bjørn Dreiø Carlsen ◽  
Karl Anker Jørgensen

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