scholarly journals Visible light-driven Giese reaction with alkyl tosylates catalysed by nucleophilic cobalt

RSC Advances ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 3539-3546
Author(s):  
Kimihiro Komeyama ◽  
Takuya Michiyuki ◽  
Yoshikazu Teshima ◽  
Itaru Osaka
Keyword(s):  
Visible Light ◽  
Visible Light Irradiation ◽  
Alkyl Radical ◽  
Cobalt Catalyst ◽  
Light Irradiation ◽  
Efficient Approach ◽  
Visible Light Driven

We report an efficient approach for the Giese reaction with abundant alkyl tosylates as alkyl radical sources using a nucleophilic cobalt catalyst under visible-light irradiation.

Visible light-driven novel g-C3N4/NiFe-LDH composite photocatalyst with enhanced photocatalytic activity towards water oxidation and reduction reaction

2015 ◽  
Vol 3 (36) ◽  
pp. 18622-18635 ◽  
Author(s):  
Susanginee Nayak ◽  
Lagnamayee Mohapatra ◽  
Kulamani Parida
Keyword(s):  
Photocatalytic Activity ◽  
Composite Materials ◽  
Visible Light ◽  
Water Splitting ◽  
Visible Light Irradiation ◽  
Water Oxidation ◽  
Reduction Reaction ◽  
Light Irradiation ◽  
Composite Photocatalyst ◽  
Visible Light Driven

Dispersion of exfoliated CN over the surface of exfoliated LDH composite materials, and its photocatalytic water splitting under visible-light irradiation.

Solvothermal synthesis and visible light-driven photocatalytic degradation for tetracycline of Fe-doped SrTiO3

RSC Advances ◽  
2014 ◽  
Vol 4 (88) ◽  
pp. 47615-47624 ◽  
Author(s):  
Ping Li ◽  
Chunbo Liu ◽  
Guoling Wu ◽  
Yang Heng ◽  
Shuang Lin ◽  
...  
Keyword(s):  
Visible Light ◽  
Photocatalytic Degradation ◽  
Visible Light Irradiation ◽  
Solvothermal Synthesis ◽  
Solvothermal Method ◽  
Light Irradiation ◽  
Photocatalytic Activities ◽  
Visible Light Driven ◽  
Facile Solvothermal Method

In this paper, Fe-doped SrTiO3 (FSTO) photocatalysts were successfully prepared via a facile solvothermal method, and their photocatalytic activities for degrading tetracycline (TC) under visible light irradiation were examined.

Dehydrogenative 6π Heterocyclization under Visible Light Irradiation and Mechanistic Insights

2021 ◽  
Author(s):  
Zhao Zhang ◽  
Haohua Chen ◽  
Niklas Keller ◽  
Qin Xiong ◽  
Lei Liu ◽  
...  
Keyword(s):  
Transition Metals ◽  
Visible Light ◽  
Visible Light Irradiation ◽  
Light Irradiation ◽  
Reaction Proceeds ◽  
Visible Light Driven

A visible-light-driven oxidative 6π heterocycilization for the synthesis of structurally diverse π-conjugated polycyclic 1-aminoisoquinolines has been developed. The reaction proceeds under visible-light or sunshine, obviates photocatalyst and transition-metals, and features...

Visible-light-driven photocatalysis of heterostructure Ag/Bi2WO6 nanocomposites and their photocatalytic degradation of dye under visible light irradiation

2015 ◽  
Vol 42 (3) ◽  
pp. 1651-1662 ◽  
Author(s):  
Phattranit Dumrongrojthanath ◽  
Anukorn Phuruangrat ◽  
Patcharanan Junploy ◽  
Somchai Thongtem ◽  
Titipun Thongtem
Keyword(s):  
Visible Light ◽  
Photocatalytic Degradation ◽  
Visible Light Irradiation ◽  
Light Irradiation ◽  
Visible Light Driven

Dechlorination of DDT catalyzed by visible-light-driven system composed of vitamin B12 derivative and Rhodamine B

2013 ◽  
Vol 17 (01n02) ◽  
pp. 135-141 ◽  
Author(s):  
Keishiro Tahara ◽  
Kumiko Mikuriya ◽  
Takahiro Masuko ◽  
Jun-ichi Kikuchi ◽  
Yoshio Hisaeda
Keyword(s):  
Visible Light ◽  
Visible Light Irradiation ◽  
Rhodamine B ◽  
Cobalt Complex ◽  
Light Irradiation ◽  
Vitamin B ◽  
Free Process ◽  
Driven System ◽  
Derivative System ◽  
Visible Light Driven

The visible-light-driven dechlorination of 1,1-bis(4-chlorophenyl)-2,2,2-trichloroethane (DDT) was carried out in the presence of a hydrophobic vitamin B12 , heptamethyl cobyrinate perchlorate and Rhodamine B . DDT was successfully dechlorinated to form 1,1-bis(4-chlorophenyl)-2,2-dichloroethane (DDD) as the mono-dechlorinated product upon visible light irradiation with a tungsten lamp (λ > 440 nm). Upon prolonged visible light irradiation to DDT, DDMU (1-chloro-2,2-bis(4-chlorophenyl)ethylene), DDMS (1-chloro-2,2-bis(4-chlorophenyl)ethane) and DCS (trans-4,4′-dichlorostilbene) were obtained as the di- and tri-dechlorinated products. The use of the photostable organic sensitizer enabled prolonged photocatalysis via a noble-metal-free process. The vitamin B12 derivative was replaced by an imine/oxime-type cobalt complex although the cobalt complex system showed a lower catalytic activity than the B12 derivative system. The dechlorination mechanism in the B12 -Rhodamin B system was investigated by various methods such as UV-vis absorption and fluorescence quenching.

scholarly journals Photocatalytic oxidation of benzene to phenol using dioxygen as an oxygen source and water as an electron source in the presence of a cobalt catalyst

2017 ◽  
Vol 8 (10) ◽  
pp. 7119-7125 ◽  
Author(s):  
Ji Won Han ◽  
Jieun Jung ◽  
Yong-Min Lee ◽  
Wonwoo Nam ◽  
Shunichi Fukuzumi
Keyword(s):  
Visible Light ◽  
Visible Light Irradiation ◽  
Photocatalytic Oxidation ◽  
Cobalt Catalyst ◽  
Electron Source ◽  
Light Irradiation ◽  
Turnover Number ◽  
High Turnover ◽  
Hydroxylation Of Benzene ◽  
Oxidation Of Benzene

The present study reports the first example of photocatalytic hydroxylation of benzene with O2 and H2O, both of which are the most green reagents, under visible light irradiation to afford a high turnover number.

The effect of molecular structure and fluorination on the properties of pyrene-benzothiadiazole-based conjugated polymers for visible-light-driven hydrogen evolution

2018 ◽  
Vol 9 (35) ◽  
pp. 4468-4475 ◽  
Author(s):  
Chang Cheng ◽  
Xunchang Wang ◽  
Yaoyao Lin ◽  
Luying He ◽  
Jia-Xing Jiang ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Visible Light ◽  
Conjugated Polymers ◽  
Hydrogen Evolution ◽  
Visible Light Irradiation ◽  
Light Irradiation ◽  
Evolution Rate ◽  
Fluorinated Polymer ◽  
Hydrogen Evolution Rate ◽  
Visible Light Driven

The linear non-fluorinated polymer L-PyBT exhibited an impressive hydrogen evolution rate up to 83.7 μmol h−1 under visible light irradiation.

N-Loaded TiO2 for Photocatalytic Degradation of Methyl Orange under Visible Light Irradiation

2012 ◽  
Vol 622-623 ◽  
pp. 883-888
Author(s):  
Natkritta Boonprakob ◽  
Natda Wetchakun ◽  
Sukon Phanichphant ◽  
Jun Chen ◽  
Burapat Inceesungvorn
Keyword(s):  
Methyl Orange ◽  
Visible Light ◽  
Band Gap ◽  
Visible Light Irradiation ◽  
Sol Gel ◽  
Band Gap Energy ◽  
Light Irradiation ◽  
Gap Energy ◽  
Visible Light Driven ◽  
Degradation Of Methyl Orange

Nitrogen-loaded TiO2(N-loaded TiO2), a visible-light driven catalyst, was successfully synthesized by the modified sol-gel method. Physical characterizations of the as-prepared catalysts have been performed by using X-ray diffraction (XRD), Diffuse reflectance UVvisspectroscopy(DRUVvis), Raman spectroscopyand BETspecific surface areain order to obtain structure-activity relationship. Results from Raman spectroscopy clearly suggested that N atoms were incorporated into the TiO2crystal lattice as evidenced by the vibrational peak of TiN in TiO2-xNx.DR UVvis results also suggested that the nitrogen dopant might be responsible for narrowing the TiO2band gap energy, thus resulting in a shift towards the visiblelight region. Photocatalytic activity of N-loaded TiO2evaluated through the degradation of methyl orange (MO)under visible light irradiation (l> 400 nm) indicated that all N-loaded photocatalysts exhibited significantly higher activities than the unloaded TiO2and Degussa P25 TiO2. According to the results from DR UV-vis, XRD and BET studies, the enhanced photoactivity observed from N-loaded samples might be due to a decrease in TiO2band gap energy and/or changes in chemical and physical properties of the materials upon loading with nitrogen.

scholarly journals Enhanced Transformation of Atrazine by High Efficient Visible Light-Driven N, S-Codoped TiO2Nanowires Photocatalysts

2014 ◽  
Vol 2014 ◽  
pp. 1-8 ◽  
Author(s):  
Yanlin Zhang ◽  
Honghai Wu ◽  
Peihong Liu
Keyword(s):  
Visible Light ◽  
Visible Light Irradiation ◽  
Advanced Oxidation Process ◽  
Light Irradiation ◽  
Solar Irradiation ◽  
Electron Hole ◽  
Toc Removal ◽  
High Efficient ◽  
Endocrine Disrupting ◽  
Visible Light Driven

Advanced oxidation process using titanium dioxide as a photocatalyst under solar irradiation is one of the most attractive technologies to eliminate atrazine, an endocrine disrupting and carcinogen contaminant. The N, S-codoped TiO2nanowires at the calcination of 600°C obtained by a facile hydrothermal method revealed the best photocatalytic performance for the degradation of atrazine under visible light irradiation compared to N, S-codoped TiO2nanoparticles and S-doped TiO2nanowires. TOC removal experiment also exhibited the similar result and achieved 63% of atrazine mineralization within 6 h. The degradation of atrazine was driven mainly by•OH and holes during the photocatalytic process. Reactive species quantities such•OH andO2•-generated by N, S-codoped TiO2nanowires under visible light irradiation were much more than those of S-doped TiO2nanowires and N, S-codoped TiO2nanoparticles. These results were mainly attributed to the synergistic effect of N and S doping in narrowing the band gap, remarkable increase in electron-hole separation, extending the anatase-to-rutile transformation temperature above 600°C, and preferentially exposing high reactive{001}crystal facets of anatase.

Metal free visible light driven oxidation of alcohols to carbonyl derivatives using 3,6-di(pyridin-2-yl)-1,2,4,5-tetrazine (pytz) as catalyst

RSC Advances ◽  
2015 ◽  
Vol 5 (102) ◽  
pp. 84328-84333 ◽  
Author(s):  
Suvendu Samanta ◽  
Papu Biswas
Keyword(s):  
Visible Light ◽  
Visible Light Irradiation ◽  
Room Temperature ◽  
Light Irradiation ◽  
Metal Free ◽  
Carbonyl Derivatives ◽  
Oxidation Of Alcohols ◽  
Visible Light Driven ◽  
High Yields

A metal-free transformation of alcohols to the corresponding carbonyls in high yields under visible-light irradiation has been achieved at room temperature using di(pyridin-2-yl)-1,2,4,5-tetrazine (pytz) as catalyst.

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