scholarly journals Lithium-ion attack on yttrium oxide in the presence of copper powder during Li plating in a super-concentrated electrolyte

RSC Advances ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 6361-6366 ◽  
Author(s):  
Tohru Shiga ◽  
Yumi Masuoka ◽  
Hiroshi Nozaki ◽  
Nobuko Ohba

When Li plating was conducted on a Cu + Y2O3 composite electrode in a super-concentrated electrolyte, a potential drop and subsequent potential plateau were observed, where Li plating occurs and Li+ attacks the Y2O3 crystals.

2015 ◽  
Vol 39 ◽  
pp. 187-198 ◽  
Author(s):  
Ahmed Abdulrahman Ahmed AL-TABBAKH ◽  
Norlida KAMARULZAMAN ◽  
Aseel Basim AL-ZUBAIDI

Nanoscale ◽  
2019 ◽  
Vol 11 (34) ◽  
pp. 15881-15891 ◽  
Author(s):  
Yong Xu ◽  
Jun Chen ◽  
Ze'en Xiao ◽  
Caixia Ou ◽  
Weixia Lv ◽  
...  

A novel porous diatomite composite electrode composed of NTCDA nanowires exhibits lower charge transfer impedance, higher capacity and better rate performance.


2021 ◽  
Vol 23 (09) ◽  
pp. 656-687
Author(s):  
K.C. Mahesh ◽  
◽  
G.S. Suresh ◽  

The kinetics of electrochemical lithium ion intercalation into Li[Li0.2Co0.3Mn0.5]O2 electrode in 2 M Li2SO4 aqueous electrolyte has been studied using two electroanalytical methods, namely, potentiostatic intermittent titration technique (PITT) and galvanostatic intermittent titration technique (GITT). The results are compared with those from nonaqueous electrolytes. Layered, lithium-rich Li[Li0.2Co0.3Mn0.5]O2 cathode material was synthesized by reactions under autogenic pressure at elevated temperature (RAPET) method. The effects of ohmic potential drop and charge-transfer resistance have been considered while predicting the current transients obtained with aqueous electrolyte. For PITT and GITT, we have defined their characteristic time-invariant functions, It1/2 and dE/dt1/2, respectively to present the diffusion time constant τ. Application of different theoretical diffusion models for treating the results obtained by the above-mentioned techniques allowed us to calculate the diffusion coefficient of lithium ions (D) at different potentials (E). The intercalation process is explained by considering the possible attractive interactions of the intercalated species in terms of Frumkin intercalation isotherm. We have observed a strictcorrespondence between the peaks of the intercalation capacitance and the minima in the corresponding log D vs. E curve.


2020 ◽  
Vol 332 ◽  
pp. 135471 ◽  
Author(s):  
Seoungwoo Byun ◽  
Jaecheol Choi ◽  
Youngjoon Roh ◽  
Danoh Song ◽  
Myung-Hyun Ryou ◽  
...  

2018 ◽  
Vol 264 ◽  
pp. 134-140 ◽  
Author(s):  
Jianfang Wang ◽  
Heping Yang ◽  
Liping Kang ◽  
Zong-Huai Liu ◽  
Gaini Zhang ◽  
...  

2020 ◽  
Vol MA2020-02 (5) ◽  
pp. 891-891
Author(s):  
Naoki Horikawa ◽  
Akinari Ohashi ◽  
Manabu Kodama ◽  
Shuichiro Hirai

2020 ◽  
Vol 3 (12) ◽  
pp. 11873-11885
Author(s):  
Irina Profatilova ◽  
Eric De Vito ◽  
Sylvie Genies ◽  
Christophe Vincens ◽  
Elise Gutel ◽  
...  

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