scholarly journals Unraveling the catalytic mechanisms of H2 production with thiosemicarbazone nickel complexes

RSC Advances ◽  
2021 ◽  
Vol 11 (9) ◽  
pp. 5232-5238
Author(s):  
Alexandre Barrozo ◽  
Maylis Orio
Keyword(s):  
Reaction Mechanism ◽  
Nickel Complexes ◽  
H2 Production ◽  
Dft Methods ◽  
New Class ◽  
Redox Active ◽  
Thiosemicarbazone Complexes ◽  
Catalytic Mechanisms

The reaction mechanism of nickel thiosemicarbazone complexes, a new class of redox-active catalysts for H2 evolution, is investigated by the means of DFT methods.

scholarly journals Tuning the electrochemical potential of perfunctionalized dodecaborate clusters through vertex differentiation

2018 ◽  
Vol 54 (46) ◽  
pp. 5867-5870 ◽  
Author(s):  
Alex I. Wixtrom ◽  
Zeeshan A. Parvez ◽  
Miles D. Savage ◽  
Elaine A. Qian ◽  
Dahee Jung ◽  
...  
Keyword(s):  
Electrochemical Potential ◽  
New Class ◽  
Redox Active ◽  
Active Vertex

We report a new class of redox-active vertex-differentiated dodecaborate clusters featuring pentafluoroaryl groups.

Atomic Perspective about the Reaction Mechanism and H2 Production during the Combustion of Al Nanoparticles/H2O2 Bipropellants

2020 ◽  
Vol 124 (37) ◽  
pp. 7399-7410
Author(s):  
Gang Li ◽  
Liangliang Niu ◽  
Xianggui Xue ◽  
Weizhe Hao ◽  
Yu Liu ◽  
...  
Keyword(s):  
Reaction Mechanism ◽  
H2 Production ◽  
Al Nanoparticles

Redox active ligand and metal cooperation for C(sp2)–H oxidation: extension of the galactose oxidase mechanism in water-mediated amide formation

2018 ◽  
Vol 47 (43) ◽  
pp. 15293-15297 ◽  
Author(s):  
Zahra Alaji ◽  
Elham Safaei ◽  
Hong Yi ◽  
Hengjiang Cong ◽  
Andrzej Wojtczak ◽  
...  
Keyword(s):  
Driving Force ◽  
Nickel Complexes ◽  
Galactose Oxidase ◽  
Oxidative Transformation ◽  
Redox Active Ligand ◽  
Active Ligand ◽  
Amide Formation ◽  
Redox Active

Metal and ligand cooperation provides a driving force for the water-mediated oxidative transformation of imine to amide in copper and nickel complexes versus a zinc analogue.

scholarly journals Azo-triazolide bis-cyclometalated Ir(iii) complexes via cyclization of 3-cyanodiarylformazanate ligands

2020 ◽  
Vol 49 (12) ◽  
pp. 3775-3785 ◽  
Author(s):  
Ge Mu ◽  
Zhili Wen ◽  
Judy I-Chia Wu ◽  
Thomas S. Teets
Keyword(s):  
New Class ◽  
Chelating Ligand ◽  
Redox Active

Sterically encumbered iridium-bound formazanate ligands undergo redox-neutral cyclization to form azo-triazolides, a new class of redox-active chelating ligand.

Kinetic Simulations of H2 Production from H2S Pyrolysis in Sulfur Recovery Units Using a Detailed Reaction Mechanism

2016 ◽  
Vol 30 (12) ◽  
pp. 10823-10834 ◽  
Author(s):  
Arjun Ravikumar ◽  
Abhijeet Raj ◽  
Salisu Ibrahim ◽  
Ramees K. Rahman ◽  
Ahmed Al Shoaibi
Keyword(s):  
Reaction Mechanism ◽  
H2 Production ◽  
Sulfur Recovery ◽  
Detailed Reaction Mechanism
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