scholarly journals Palladium supported on mixed-metal–organic framework (Co–Mn-MOF-74) for efficient catalytic oxidation of CO

RSC Advances ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 4318-4326
Author(s):  
Reda S. Salama ◽  
Mohammed A. Mannaa ◽  
Hatem M. Altass ◽  
Amr Awad Ibrahim ◽  
Abd El-Rahman S. Khder

Pd nanoparticles were loaded on Cox–Mn(1−x)-MOF-74. 5 wt% [email protected]–Mn0.5-MOF-74 was the most effective catalyst for CO oxidation. The prepared catalysts displayed excellent stability during CO oxidation without significant decrease in catalytic performance.

RSC Advances ◽  
2015 ◽  
Vol 5 (53) ◽  
pp. 42329-42340 ◽  
Author(s):  
Chandan Sahu ◽  
Deepanwita Ghosh ◽  
Abhijit K. Das

A DFT study has been adopted to explore the catalytic CO oxidation on a free PdxO2+ (x = 4–6) cluster.


2016 ◽  
Vol 18 (19) ◽  
pp. 13232-13238 ◽  
Author(s):  
Soonho Kwon ◽  
Kihyun Shin ◽  
Kihoon Bang ◽  
Hyun You Kim ◽  
Hyuck Mo Lee

The mechanism of the catalytic oxidation of CO activated by MoS2-supported Au19 nanoparticles (NPs) was studied using density functional theory calculations.


2020 ◽  
Vol 49 (4) ◽  
pp. 1191-1199 ◽  
Author(s):  
Zhida Liu ◽  
Liangmin Ning ◽  
Kaiyuan Wang ◽  
Lixi Feng ◽  
Wen Gu ◽  
...  

In recent years, attributed to the excellent catalytic performance of precious metal materials, metal nanoparticles@MOF catalyst has been a popular research direction.


RSC Advances ◽  
2015 ◽  
Vol 5 (12) ◽  
pp. 9130-9137 ◽  
Author(s):  
Jiahuan Lei ◽  
Yu Liu ◽  
Xinyu Wang ◽  
Pan Hu ◽  
Xinsheng Peng

After assembling Au nanoparticles on CuO nanosheets (NSs), the non-enzymatic glucose sensitivity and low temperature catalytic oxidation of CO improved significantly.


2017 ◽  
Vol 201 ◽  
pp. 317-326 ◽  
Author(s):  
Qi Sun ◽  
Meng Chen ◽  
Briana Aguila ◽  
Nicholas Nguyen ◽  
Shengqian Ma

In this work, the influence of the hydrophilic/hydrophobic nature of metal–organic framework (MOF) materials on the catalytic performance of supported Pd nanoparticles for biofuel upgrade was studied. We show that the introduction of hydrophilic groups on a MOF can greatly enhance the performance of the resultant catalyst. Specifically, Pd nanoparticles supported on MIL-101–SO3Na with superhydrophilicity (Pd/MIL-101–SO3Na) far outperforms pristine MIL-101 and the benchmark catalyst Pd/C in the hydrodeoxygenation reaction of vanillin, a model component of pyrolysis oil derived from the lignin fraction. This is attributed to a favorable mode of adsorption of the highly water soluble reactants on the more hydrophilic support in the vicinity of the catalytically active Pd nanoparticles, thereby promoting their transformation.


CrystEngComm ◽  
2014 ◽  
Vol 16 (27) ◽  
pp. 6126-6134 ◽  
Author(s):  
Liangmiao Zhang ◽  
Taiang Liu ◽  
Xin Zhao ◽  
Na Qian ◽  
Pan Xiong ◽  
...  

Co3O4/Al2O3 hollow core–shell microspheres, which exhibit a large surface area, a mesoporous structure and an excellent CO catalytic performance, have been synthesized by a solvothermal process.


RSC Advances ◽  
2020 ◽  
Vol 10 (39) ◽  
pp. 22921-22928
Author(s):  
Qiang Fang ◽  
Hailian Li ◽  
Qingquan Lin ◽  
Kuo Liu ◽  
Yang Su ◽  
...  

Novel Au/Ce-Co-Ox/Al2O3 showed a very excellent performance for CO oxidation in the simulated atmosphere of CO2-laser mainly due to SMSI and labile lattice oxygen.


2020 ◽  
Vol 10 (6) ◽  
pp. 1661-1674 ◽  
Author(s):  
Weiwei Yang ◽  
Li Li ◽  
Yarong Fang ◽  
Yulong Shan ◽  
Jue Xu ◽  
...  

Different types of Cu–Ti interfacial structures determine different tolerance abilities of catalysts towards SO2 poisoning during CO oxidation at 250 °C.


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