scholarly journals Influence of the acid–base stoichiometry and residual water on the transport mechanism in a highly-Brønsted-acidic proton-conducting ionic liquid

RSC Advances ◽  
2020 ◽  
Vol 10 (69) ◽  
pp. 42596-42604
Author(s):  
Jingjing Lin ◽  
Carsten Korte
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Transport Mechanism ◽  
Base Excess ◽  
Residual Water ◽  
Acid Base ◽  
Proton Conducting ◽  
Acidic Proton ◽  
Cooperative Transport

There is a transition between prevailing vehicular and cooperative transport mechanism in base-excess Brønsted-acidic proton-conducting ionic liquids depending on stoichiometry.

Influence of residual water and cation acidity on the ionic transport mechanism in proton-conducting ionic liquids

2020 ◽  
Vol 22 (3) ◽  
pp. 1145-1153 ◽  
Author(s):  
Jingjing Lin ◽  
Liming Wang ◽  
Tatiana Zinkevich ◽  
Sylvio Indris ◽  
Yanpeng Suo ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Transport Mechanism ◽  
Ionic Transport ◽  
Residual Water ◽  
Transport Mechanisms ◽  
Proton Conducting ◽  
Acidic Proton ◽  
Cooperative Transport

There will be a transition between vehicular and cooperative transport mechanisms in highly acidic proton conducting ionic liquids.

scholarly journals Correction: Influence of residual water and cation acidity on the ionic transport mechanism in proton-conducting ionic liquids

2020 ◽  
Vol 22 (9) ◽  
pp. 5383-5383
Author(s):  
Jingjing Lin ◽  
Liming Wang ◽  
Tatiana Zinkevich ◽  
Sylvio Indris ◽  
Yanpeng Suo ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Transport Mechanism ◽  
Ionic Transport ◽  
Chem Phys ◽  
Residual Water ◽  
Proton Conducting ◽  
Phys Chem Chem Phys

Correction for ‘Influence of residual water and cation acidity on the ionic transport mechanism in proton-conducting ionic liquids’ by Jingjing Lin et al., Phys. Chem. Chem. Phys., 2020, 22, 1145–1153.

Brønsted Acid−Base Ionic Liquids as Proton-Conducting Nonaqueous Electrolytes

2003 ◽  
Vol 107 (17) ◽  
pp. 4024-4033 ◽  
Author(s):  
Akihiro Noda ◽  
Md. Abu Bin Hasan Susan ◽  
Kenji Kudo ◽  
Shigenori Mitsushima ◽  
Kikuko Hayamizu ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Bronsted Acid ◽  
Brønsted Acid ◽  
Acid Base ◽  
Proton Conducting ◽  
Nonaqueous Electrolytes ◽  
Brönsted Acid

The volatilities and conductivities of ionic liquids — GC–MS methodology and preliminary studies of acetic acid – base systems

2006 ◽  
Vol 84 (6) ◽  
pp. 915-924 ◽  
Author(s):  
Ronald G Treble ◽  
Keith E Johnson ◽  
Evangeline Tosh
Keyword(s):  
Mass Spectrometry ◽  
Gas Chromatography ◽  
Acetic Acid ◽  
Ionic Liquids ◽  
Binary Systems ◽  
Gas Chromatography Mass Spectrometry ◽  
Acid Base ◽  
The Third ◽  
Acidic Proton ◽  
First Case

Gas chromatography – mass spectrometry studies of the headspaces above the binary systems pyridine (bp 115 °C) – acetic acid (bp 116 °C), 1-methylimidazole (bp 198 °C) – acetic acid, and triethylamine (bp 89 °C) – acetic acid show both components in the first case, acetic acid only in the second, and triethylamine only in the third. Negative deviations from Raoult's law are confirmed and proton transfer is evidenced by the downfield shift of the acidic proton as the addition of base proceeds. Specific conductances >2 mS cm–1 are found over wide composition ranges for all three systems with values >8 mS cm–1 at high (>2) mole ratios of acetic acid, suggesting the formation of acetatohydrogenate ionic liquids.Key words: GC–MS, air, vapor pressure, conductivity, ionic liquids, acetic acid.

A greener, halide-free approach to ionic liquid synthesis

2011 ◽  
Vol 84 (3) ◽  
pp. 723-744 ◽  
Author(s):  
Jamie L. Ferguson ◽  
John D. Holbrey ◽  
Shieling Ng ◽  
Natalia V. Plechkova ◽  
Kenneth R. Seddon ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Organic Acids ◽  
Acid Base ◽  
Halide Salt

Conventionally, ionic liquids with anions generated from simple organic acids are prepared following a metathetic procedure from a halide salt, usually a chloride. Here, we describe an efficient means of generating hydroxide solutions of the cations of interest, allowing many ionic liquids to be produced by simple acid–base reactions, completely avoiding the use of halides.

A novel proton conducting ionogel electrolyte based on poly(ionic liquids) and protic ionic liquid

2020 ◽  
Vol 346 ◽  
pp. 136224
Author(s):  
Jun Rao ◽  
Xiaoen Wang ◽  
Ruhamah Yunis ◽  
Vijayraghavan Ranganathan ◽  
Patrick C. Howlett ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Protic Ionic Liquid ◽  
Proton Conducting

scholarly journals Mono and co-immobilization of imidazolium ionic liquids on silica: effects of the substituted groups on the adsorption behavior of 2,4-dinitrophenol

RSC Advances ◽  
2019 ◽  
Vol 9 (56) ◽  
pp. 32425-32434 ◽  
Author(s):  
Zhike Wang ◽  
Honglian Ge ◽  
Xueyuan Wang ◽  
Cunling Ye ◽  
Shunli Fan
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Adsorption Capacity ◽  
Adsorption Behavior ◽  
High Adsorption ◽  
Acid Base ◽  
Imidazolium Ionic Liquids ◽  
High Adsorption Capacity

Ionic liquid modified silicas with high adsorption capacity for phenols prompt us to deeply explore the contribution of interactions between the adsorbent and adsorbate, with a particular focus on hydrophobicity, π–π, electrostatic and acid–base interactions.

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