scholarly journals Compositional and operational impacts on the thermochemical reduction of CO2 to CO by iron oxide/yttria-stabilized zirconia

RSC Advances ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 1493-1502
Author(s):  
Eric N. Coker ◽  
Andrea Ambrosini ◽  
James E. Miller

The versatile redox chemistry of ferrites makes them useful as active materials for the solar-thermochemical production of synthetic fuels. Optimization of the distribution of iron in a YSZ matrix allows the performance of ferrites to be enhanced.

2019 ◽  
Vol 42 (6) ◽  
pp. 1321-1329 ◽  
Author(s):  
Syafikah Huda Paiman ◽  
Mukhlis A Rahman ◽  
Khairul Hamimah Abas ◽  
Azian Abd Aziz ◽  
Ahmad Fauzi Ismail ◽  
...  

1989 ◽  
Vol 24 (10) ◽  
pp. 3660-3666 ◽  
Author(s):  
M. A. Ewaida ◽  
A. A. Higazy ◽  
B. Bridge ◽  
M. M. Abou Sekkina

1997 ◽  
Vol 72-74 ◽  
pp. 714-715 ◽  
Author(s):  
B. Savoini ◽  
J.E.Muñoz Santiuste ◽  
R. Gonźalez ◽  
Y. Chen

2015 ◽  
Vol 2015 ◽  
pp. 1-10 ◽  
Author(s):  
Jeffrey Leonard ◽  
Nichole Reyes ◽  
Kyle M. Allen ◽  
Kelvin Randhir ◽  
Like Li ◽  
...  

Mixed metal ferrites have shown much promise in two-step solar-thermochemical fuel production. Previous work has typically focused on evaluating a particular metal ferrite produced by a particular synthesis process, which makes comparisons between studies performed by independent researchers difficult. A comparative study was undertaken to explore the effects different synthesis methods have on the performance of a particular material during redox cycling using thermogravimetry. This study revealed that materials made via wet chemistry methods and extended periods of high temperature calcination yield better redox performance. Differences in redox performance between materials made via wet chemistry methods were minimal and these demonstrated much better performance than those synthesized via the solid state method. Subsequently, various metal ferrite samples (NiFe2O4, MgFe2O4, CoFe2O4, and MnFe2O4) in yttria stabilized zirconia (8YSZ) were synthesized via coprecipitation and tested to determine the most promising metal ferrite combination. It was determined that 10 wt.% CoFe2O4in 8YSZ produced the highest and most consistent yields of O2and CO. By testing the effects of synthesis methods and dopants in a consistent fashion, those aspects of ferrite preparation which are most significant can be revealed. More importantly, these insights can guide future efforts in developing the next generation of thermochemical fuel production materials.


2018 ◽  
Vol 44 (5) ◽  
pp. 4689-4693 ◽  
Author(s):  
Ching-Ti Kao ◽  
Wei-Hsing Tuan ◽  
Che-Yuan Liu ◽  
Shih-Chieh Chen

2013 ◽  
Vol 2013 ◽  
pp. 1-7
Author(s):  
Hyo-Sub Kim ◽  
Dong-Hee Lee ◽  
Hong-Soon Kim ◽  
Chu-Sik Park ◽  
Young-Ho Kim

Hydrogen storage and release by the redox reaction of an iron oxide with yttria-stabilized zirconia (YSZ) were investigated. YSZ was introduced to the samples to improve the thermal stability of the iron oxide. The average size of the samples synthesized using urea was 40–50 nm, whereas those synthesized using Na2CO3as a precipitant were 150–200 nm. The sample prepared via coprecipitation using urea exhibited better stability than the other samples. We prepared the Cu-added Fe/YSZ sample to enhance the low-temperature reactivity. The water-splitting reaction was initiated at approximately 200°C, and the maximum rate of hydrogen evolution was observed at approximately 350°C. In the isothermal redox test over 35 cycles, the degree of hydrogen storage and release was almost maintained over 1.8 wt% based on the total amount of the sample.


1998 ◽  
Vol 57 (21) ◽  
pp. 13439-13447 ◽  
Author(s):  
B. Savoini ◽  
C. Ballesteros ◽  
J. E. Muñoz Santiuste ◽  
R. González ◽  
Y. Chen

2002 ◽  
Vol 106 (51) ◽  
pp. 13146-13153 ◽  
Author(s):  
Marco de Ridder ◽  
Patrick C. van de Ven ◽  
Rob G. van Welzenis ◽  
Hidde H. Brongersma ◽  
Steve Helfensteyn ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document