scholarly journals Suppressing loss tangent with significantly enhanced dielectric permittivity of poly(vinylidene fluoride) by filling with Au–Na1/2Y1/2Cu3Ti4O12 hybrid particles

RSC Advances ◽  
2020 ◽  
Vol 10 (66) ◽  
pp. 40442-40449
Author(s):  
Pornsawan Kum-onsa ◽  
Nutthakritta Phromviyo ◽  
Prasit Thongbai
Keyword(s):  
Dielectric Permittivity ◽  
Gold Nanoparticle ◽  
Loss Tangent ◽  
Vinylidene Fluoride ◽  
Hybrid Particles ◽  
Particle Volume ◽  
Hybrid Particle ◽  
Volume Fractions ◽  
Three Phase ◽  
Poly Vinylidene Fluoride

Three-phase gold nanoparticle–Na1/2Y1/2Cu3Ti4O12 (Au–NYCTO)/poly(vinylidene fluoride) (PVDF) composites with 0.095–0.487 hybrid particle volume fractions (f) were fabricated.

scholarly journals Effects of Sub-Micro Sized BaTiO3 Blocking Particles and Ag-Deposited Nano-Sized BaTiO3 Hybrid Particles on Dielectric Properties of Poly(vinylidene-fluoride) Polymer

Polymers ◽  
2021 ◽  
Vol 13 (21) ◽  
pp. 3641
Author(s):  
Kanyapak Silakaew ◽  
Prasit Thongbai
Keyword(s):  
Dielectric Properties ◽  
Dielectric Permittivity ◽  
Loss Tangent ◽  
Vinylidene Fluoride ◽  
Interfacial Polarization ◽  
Blocking Effect ◽  
Alternative Route ◽  
Hybrid Particles ◽  
High Permittivity ◽  
Poly Vinylidene Fluoride

This work provided an alternative route to balance the significantly increased dielectric permittivity (ε′) and effectively retained tanδ using an effective two-step concept. Ag-deposited nano-sized BaTiO3 (Ag-nBT) hybrid particle was used as the first filler to increase the ε′ of the poly(vinylidene-fluoride) (PVDF) polymer via the strong interfacial polarization and a high permittivity of nBT and suppress the increased loss tangent (tanδ) owing to the discrete growth of Ag nanoparticles on the surface of nBT, preventing a continuous percolating path. The ε′ and tanδ values at 103 Hz of the Ag-nBT/PVDF composite with fAg-nBT~0.29 were 61.7 and 0.036. The sub-micron-sized BaTiO3 (μBT) particle was selected as the blocking particles to doubly reduce the tanδ with simultaneously enhanced ε′ due to the presence of the tetragonal BT phase. The μBT blocking particles can effectively further inhibit the formation of conducting network and hence further reducing tanδ. By incorporation of μBT clocking particles with fμBT = 0.2, the ε′ value of the Ag-nBT/PVDF-μBT composite (fAg-nBT = 0.30) can significantly increase to 161.4, while the tanδ was reduced to 0.026. Furthermore, the tanδ was lower than 0.09 in the temperature range of −60–150 °C due to the blocking effect of μBT particles.

scholarly journals Greatly enhanced dielectric permittivity in La1.7Sr0.3NiO4/poly(vinylidene fluoride) nanocomposites that retained a low loss tangent

RSC Advances ◽  
2017 ◽  
Vol 7 (28) ◽  
pp. 17128-17136 ◽  
Author(s):  
Keerati Meeporn ◽  
Prasit Thongbai ◽  
Teerapon Yamwong ◽  
Santi Maensiri
Keyword(s):  
Dielectric Properties ◽  
Dielectric Permittivity ◽  
Loss Tangent ◽  
Polyvinylidene Fluoride ◽  
Vinylidene Fluoride ◽  
Low Loss ◽  
Poly Vinylidene Fluoride

The effect of La1.7Sr0.3NiO4 nanoparticles (LSNO-NPs) on the dielectric properties of LSNO-NPs/polyvinylidene fluoride (LSNO-NPs/PVDF) composites is presented.

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