scholarly journals Synthesis, characterization, and catalytic application of hierarchical nano-ZSM-5 zeolite

RSC Advances ◽  
2020 ◽  
Vol 10 (50) ◽  
pp. 29618-29626
Author(s):  
Yanming Jia ◽  
Qinghua Shi ◽  
Junwen Wang ◽  
Chuanmin Ding ◽  
Kan Zhang
Keyword(s):  
Synergistic Effect ◽  
Hierarchical Structure ◽  
Crystal Size ◽  
Strong Acid ◽  
Catalytic Performance ◽  
Acid Amount ◽  
Catalytic Application ◽  
Zeolite P

The crystal size and strong acid amounts of ZSM-5 decrease and the mesopores increase with increasing of KH-560. High MTA catalytic performance could be obtained under synergistic effect of proper strong acid amount, smaller crystal size and abundant hierarchical structure.

scholarly journals Probing the surface reactivity of nanocrystals by the catalytic degradation of organic dyes: the effect of size, surface chemistry and composition

2017 ◽  
Vol 5 (23) ◽  
pp. 11917-11929 ◽  
Author(s):  
Jordi Piella ◽  
Florind Merkoçi ◽  
Aziz Genç ◽  
Jordi Arbiol ◽  
Neus G. Bastús ◽  
...  
Keyword(s):  
Surface Chemistry ◽  
Surface Coating ◽  
Crystal Size ◽  
Organic Dyes ◽  
Catalytic Performance ◽  
Surface Reactivity ◽  
Catalytic Degradation ◽  
Comprehensive Study

We herein present a comprehensive study on how the catalytic performance and reusability of Au nanocrystals (NCs) are affected by systematic variations of crystal size, surface coating and composition.

Effect of Preparation Methods of HPW/SiO2 Mesoporous Composites on its Catalytic Performance in Fuel Oils Desulfurization

2010 ◽  
Vol 148-149 ◽  
pp. 924-928
Author(s):  
Xue Min Yan ◽  
Yuan Zhu Mi
Keyword(s):  
Catalytic Activity ◽  
Self Assembly ◽  
Electrostatic Force ◽  
Oxidative Desulfurization ◽  
Strong Acid ◽  
Catalytic Performance ◽  
Synthesis Mechanism ◽  
Base Interaction ◽  
Preparation Methods ◽  
Oh Groups

Two kinds of mesoporous HPW/SiO2 composites, which have been synthesized respectively by the amino-functionalized (AF) method and evaporation-induced self-assembly (EISA) method, have been used as catalysts in the oxidative desulfurization process of dibenzothiophene(DBT). The catalytic performance results show that the catalyst synthesized by EISA method holds higher catalytic activity than that synthesized by the AF method. The difference of catalytic activity can be attributed to the different synthesis mechanism of two kinds of composites. In the AF method, the bonding force between HPW and SiO2 is strong acid-base interaction, which damages the Keggin structure. Whereas in the EISA process, electrostatic force and hydrogen bonds between W=O groups and Si-OH groups are main bonding forces. The hydrogen bond holds the electron-withdrawing effect, which increases the activity of nonbonding W=O groups in HPW and then results in the enhancement of the catalytic activity.

Introduction of Hierarchical Structure into YNU-5 Zeolite and Its Enhanced Catalytic Performance for Hexane Cracking

2021 ◽  
Vol 50 (9) ◽  
pp. 1725-1728
Author(s):  
Qing Liu ◽  
Ryota Sugimoto ◽  
Satoshi Inagaki ◽  
Yoshihiro Kubota
Keyword(s):  
Hierarchical Structure ◽  
Catalytic Performance

Fast identification of stability of atomically dispersed bi-atom catalysts by a structure descriptor-based model

2022 ◽  
Author(s):  
Danyang LI ◽  
Haoxiang Xu ◽  
Jiqin Zhu ◽  
Dapeng Cao
Keyword(s):  
Synergistic Effect ◽  
Active Sites ◽  
Catalytic Performance ◽  
Fast Identification ◽  
Structure Descriptor

Atomically dispersed bi-atom catalysts (BACs) exhibit remarkable catalytic performance in a variety of reactions due to the adjacent coordination-unsaturated metal active sites, as well as interatomic synergistic effect. However, high-efficiently...

scholarly journals PENGARUH KONSENTRASI NaOH DAN WAKTU PENAHANAN TERHADAP KARAKTERISTIK ZEOLIT YANG DISINTESIS DARI LIMBAH GEOTHERMAL

REAKTOR ◽  
2017 ◽  
Vol 17 (1) ◽  
pp. 17
Author(s):  
Sulardjaka Sulardjaka ◽  
Deni Fajar Fitriana
Keyword(s):  
Crystal Size ◽  
Holding Time ◽  
Zeolite A ◽  
Zeolite Structure ◽  
Silica Source ◽  
Zeolite P

Abstract THE EFFECT OF CONCENTRATION OF NaOH AND HOLDING TIME ON CHARACTERISTIC OF ZEOLIT SINTHESIZED FROM GEOTHERMAL WASTE. Objective of this research is to investigate the effect of concentration of NaOH and holding time on the characteristic of synthesized zeolite from geothermal waste. Geothermal waste was used as silica source and hydrothermally processed for zeolite synthesized. Variation concentration of NaOH was 1.67, 3, and 5 M and variation of holding time are 1, 3, and 5 hours. Synthesized products were characterized by XRD, FTIR and SEM photomicrograph. It can be concluded that the rise of concentration of NaOH reduce the cristalization time and crystal size. Increasing of concentration of NaOH and holding time produce divers zeolite structure. At holding time 5 h and NaOH 1.67 M produces zeolite A. At holding time 5 h and NaOH concentration 3 M produce zeolite P. Sodalite is produced at concentration NaOH 5 M with holding time 5 h. Keywords: hydrothermal; geothermal waste; zeolite   Abstrak Penelitian ini bertujuan untuk meneliti pengaruh konsntrasi NaOH dan waktu penahanan terhadap karakteristik zeolit yang disintesis dari limbah geothermal. Limbah geothermal dipilih sebagai bahan silika pada sintesis zeolit dengan metode hidrothermal. Penelitian dilakukan dengan variasi konsentrasi NaOH: 1,67, 3, dan 5 M, dan variasi waktu penahanan 1, 3 dan 5 jam. Produk hasil sintesis dikarakterisasi dengan XRD, FTIR dan foto SEM. Hasil dari penelitian ini menunjukkan bahwa  tinggi konsentrasi NaOH kristalisasi zeolit A semakin cepat, sehingga ukuran kristal semakin kecil. Konsentrasi NaOH yang semakin tinggi dan waktu penahanan yang semakin lama, menghasilkan  jenis struktur zeolit yang lebih beragam. Pada waktu penahanan 5 jam, variasi konsentrasi NaOH 1,67 M menghasilkan zeolit A, variasi konsentrasi NaOH 3M menghasilkan zeolit P (NaP1) dan pada variasi konsentrasi NaOH 5M menghasilkan sodalit. Kata kunci: hydrothermal; limbah geothermal; zeolit

scholarly journals Strain Effect in Pd@PdAg Twinned Nanocrystals towards Ethanol Oxidation Electrocatalysis

2021 ◽  
Author(s):  
Jingbo Huang ◽  
Qixing Liu ◽  
Yucong Yan ◽  
Ningkang Qian ◽  
Xingqiao Wu ◽  
...  
Keyword(s):  
Synergistic Effect ◽  
Ethanol Oxidation ◽  
Catalytic Performance ◽  
Strain Effect

Strain effect is a critical knob to tune the catalytic performance and has received unprecedented research interests recently. However, it is difficult to distinguish strain effect from synergistic effect, especially...

Synergistic effect of VOx and MnOx surface species for improved performance of V2O5/Ce0.5Ti0.5−xMnxO2−δ catalysts in low-temperature NH3-SCR of NO

2018 ◽  
Vol 8 (24) ◽  
pp. 6360-6374 ◽  
Author(s):  
Thanh Huyen Vuong ◽  
Stephan Bartling ◽  
Ursula Bentrup ◽  
Henrik Lund ◽  
Jabor Rabeah ◽  
...  
Keyword(s):  
Low Temperature ◽  
Synergistic Effect ◽  
Catalytic Performance ◽  
Surface Species ◽  
Nh3 Scr ◽  
Redox Couples ◽  
Scr Of No ◽  
Improved Performance

Inserting adjacent Mn3+/Mn2+ and VO3+/VO2+ redox couples in Ce1−xTixO2 improves catalytic performance.

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