scholarly journals Two 3D Mn-based coordination polymers: synthesis, structure and magnetocaloric effect

RSC Advances ◽  
2020 ◽  
Vol 10 (56) ◽  
pp. 33628-33634
Author(s):  
Ning-Fang Li ◽  
Ye-Min Han ◽  
Jia-Nian Li ◽  
Jia-Peng Cao ◽  
Ze-Yu Du ◽  
...  
Keyword(s):  
Magnetocaloric Effect ◽  
Magnetic Materials ◽  
Coordination Polymers ◽  
Magnetic Studies

Two 3D coordination polymers (MnII6 and MnII12MnIII6) were synthesized. Magnetic studies revealed that they are potential magnetic materials.

Structure and Magnetocaloric Effect of Two Kinds of Ln-MnIIHeterometallic Coordination Polymers Produced by Fractional Crystallization

2016 ◽  
Vol 2016 (24) ◽  
pp. 3969-3977 ◽  
Author(s):  
Gang Xiong ◽  
Li-xin You ◽  
Bao-yi Ren ◽  
Yong-ke He ◽  
Shu-ju Wang ◽  
...  
Keyword(s):  
Magnetocaloric Effect ◽  
Fractional Crystallization ◽  
Coordination Polymers

Recent advances in lanthanide coordination polymers and clusters with magnetocaloric effect or single-molecule magnet behavior

2021 ◽  
Author(s):  
Jun-Jie Hu ◽  
Yan Peng ◽  
Sui-Jun Liu ◽  
He-Rui Wen
Keyword(s):  
Quantum Computing ◽  
Low Temperature ◽  
Magnetocaloric Effect ◽  
Coordination Polymers ◽  
Single Molecule ◽  
Information Storage ◽  
Lanthanide Ions ◽  
Single Molecule Magnets ◽  
Single Molecule Magnet ◽  
Lanthanide Coordination Polymers

The molecular magnetorefrigerant materials for low-temperature magnetic refrigeration and single-molecule magnets for high-density information storage and quantum computing have received extensive attention from chemists and magnetic experts. Lanthanide ions with...

Toward Actinide Molecular Magnetic Materials:  Coordination Polymers of U(IV) and the Organic Acceptors TCNQ and TCNE†

2007 ◽  
Vol 46 (14) ◽  
pp. 5528-5536 ◽  
Author(s):  
Eric J. Schelter ◽  
David E. Morris ◽  
Brian L. Scott ◽  
Joe D. Thompson ◽  
Jaqueline L. Kiplinger
Keyword(s):  
Magnetic Materials ◽  
Coordination Polymers ◽  
Molecular Magnetic Materials

Structures, fluorescence properties and magnetic properties of a series of rhombus-shaped LnIII4 clusters: magnetocaloric effect and single-molecule-magnet behavior

2019 ◽  
Vol 43 (33) ◽  
pp. 12941-12949 ◽  
Author(s):  
Wen-Min Wang ◽  
Li Zhang ◽  
Xian-Zhen Li ◽  
Li-Yuan He ◽  
Xin-Xin Wang ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Magnetocaloric Effect ◽  
Single Molecule ◽  
Magnetic Relaxation ◽  
Magnetic Refrigeration ◽  
Fluorescence Properties ◽  
Relaxation Processes ◽  
Magnetic Studies ◽  
Single Molecule Magnet ◽  
Slow Magnetic Relaxation

A family LnIII4 clusters were successfully synthesized and structurally characterized. Magnetic studies show that Gd4 cluster displays magnetic refrigeration, while Dy4 cluster demonstrates two distinct slow magnetic relaxation processes.

Construction of Co(II) coordination polymers with flexible carboxylate ligands: structural and magnetic studies

2013 ◽  
Vol 36 ◽  
pp. 122-125 ◽  
Author(s):  
Na Xu ◽  
Xiao-Hang Qiu ◽  
Chao Wang ◽  
Jinkui Tang ◽  
Peng Cheng ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Magnetic Studies ◽  
Carboxylate Ligands

scholarly journals 1D hetero-bimetallic regularly alternated 4f–3d coordination polymers based on N-oxide-4,4′-bipyridine (bipyMO) as a linker: photoluminescence and magnetic properties

2018 ◽  
Vol 47 (25) ◽  
pp. 8337-8345 ◽  
Author(s):  
Lidia Armelao ◽  
Daniela Belli Dell'Amico ◽  
Gregorio Bottaro ◽  
Luca Bellucci ◽  
Luca Labella ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Coordination Polymers ◽  
Magnetic Studies

4f–3d CPs: structural, PL and magnetic studies.

Two CoII coordination polymers of biphenyl-2,2′,5,5′-tetracarboxylic acid with flexible N-donor ligands: syntheses, structures and magnetic properties

2019 ◽  
Vol 75 (8) ◽  
pp. 1073-1083 ◽  
Author(s):  
Feng Su ◽  
Cheng-Yong Zhou ◽  
Lin-Tao Wu ◽  
Xi Wu ◽  
Jing Su ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Three Dimensional ◽  
Donor Ligands ◽  
Tetracarboxylic Acid ◽  
X Ray Diffraction ◽  
Magnetic Studies ◽  
Orbital Contribution ◽  
X Ray ◽  
3D Network ◽  
Methyl Benzene

Two CoII-based coordination polymers, namely poly[(μ4-biphenyl-2,2′,5,5′-tetracarboxylato){μ2-1,3-bis[(1H-imidazol-1-yl)methyl]benzene}dicobalt(II)], [Co2(C16H6O8)(C14H14N4)2] n or [Co2(o,m-bpta)(1,3-bimb)2] n (I), and poly[[aqua(μ4-biphenyl-2,2′,5,5′-tetracarboxylato){1,4-bis[(1H-imidazol-1-yl)methyl]benzene}dicobalt(II)] dihydrate], {[Co2(C16H6O8)(C14H14N4)2(H2O)2]·4H2O} n or {[Co2(o,m-bpta)(1,4-bimb)2(H2O)2]·4H2O} n (II), were synthesized from a mixture of biphenyl-2,2′,5,5′-tetracarboxylic acid, i.e. [H4(o,m-bpta)], CoCl2·6H2O and N-donor ligands under solvothermal conditions. The complexes were characterized by IR spectroscopy, elemental analysis, single-crystal X-ray diffraction and powder X-ray diffraction analysis. The bridging (o,m-bpta)4− ligands combine with CoII ions in different μ4-coordination modes, leading to the formation of one-dimensional chains. The central CoII atoms display tetrahedral [CoN2O2] and octahedral [CoN2O4] geometries in I and II, respectively. The bis[(1H-imidazol-1-yl)methyl]benzene (bimb) ligands adopt trans or cis conformations to connect CoII ions, thus forming two three-dimensional (3D) networks. Complex I shows a (2,4)-connected 3D network with left- and right-handed helical chains constructed by (o,m-bpta)4− ligands. Complex II is a (4,4)-connected 3D novel network with ribbon-like chains formed by (o,m-bpta)4− linkers. Magnetic studies indicate an orbital contribution to the magnetic moment of I and II due to the longer Co...Co distances. An attempt has been made to fit the χM T results to the magnetic formulae for mononuclear CoII complexes, the fitting indicating the presence of weak antiferromagnetic interactions between the CoII ions.

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