scholarly journals Surface modification of biomaterials based on cocoa shell with improved nitrate and Cr(vi) removal

RSC Advances ◽  
2020 ◽  
Vol 10 (34) ◽  
pp. 20009-20019
Author(s):  
P. Nkuigue Fotsing ◽  
E. Djoufac Woumfo ◽  
S. Mezghich ◽  
M. Mignot ◽  
N. Mofaddel ◽  
...  

The present work addresses the development of simple, low-cost and eco-friendly cocoa-shell-based materials for efficient removal of heavy metal hexavalent chromium (Cr(vi)), and toxic nitrate (NO3−) from aqueous solution.

2017 ◽  
Vol 9 (6) ◽  
pp. 1031-1037 ◽  
Author(s):  
Jingtao Liu ◽  
Yu Ding ◽  
Lifei Ji ◽  
Xin Zhang ◽  
Fengchun Yang ◽  
...  

Hexavalent chromium (Cr(vi)) is one of the most toxic heavy metal pollutants in groundwater, and thus the detection of Cr(vi) with high sensitivity, accuracy, and simplicity and low cost is of great importance.


2011 ◽  
Vol 192 (3) ◽  
pp. 956-962 ◽  
Author(s):  
Fuqiang An ◽  
Baojiao Gao ◽  
Xin Dai ◽  
Min Wang ◽  
Xiaohua Wang

2018 ◽  
Vol 77 (5) ◽  
pp. 1313-1323 ◽  
Author(s):  
Jianjun Zhou ◽  
Xionghui Ji ◽  
Xiaohui Zhou ◽  
Jialin Ren ◽  
Yaochi Liu

Abstract A novel magnetic bio-adsorbent (MCIA) was developed, characterized and tested for its Cd(II) removal from aqueous solution. MCIA could be easily separated from the solution after equilibrium adsorption due to its super-paramagnetic property. The functional and magnetic bio-material was an attractive adsorbent for the removal of Cd(II) from aqueous solution owing to the abundant adsorption sites, amino-group and oxygen-containing groups on the surface of Cyclosorus interruptus. The experimental results indicated that the MCIA exhibited excellent adsorption ability and the adsorption process was spontaneous and endothermic. The adsorption isotherm was consistent with the Langmuir model. The adsorption kinetic fitted the pseudo-second-order model very well. The maximum adsorption capacity of Cd(II) onto MCIA was 40.8, 49.4, 54.6 and 56.6 mg/g at 293, 303, 313 and 323 K, respectively. And the MCIA exhibited an excellent reusability and impressive regeneration. Therefore, MCIA could serve as a sustainable, efficient and low-cost magnetic adsorbent for Cd(II) removal from aqueous solution.


RSC Advances ◽  
2015 ◽  
Vol 5 (7) ◽  
pp. 5164-5172 ◽  
Author(s):  
Yuhao Xiong ◽  
Fanggui Ye ◽  
Cong Zhang ◽  
Shufen Shen ◽  
Linjing Su ◽  
...  

A novel and inexpensive approach was adopted to develop magnetic porous γ-Fe2O3/C@HKUST-1 composites for the adsorption of dyes and heavy metal ions from aqueous solution.


Author(s):  
Muhammad Tahir Butt ◽  
Zara Amjad ◽  
Rauf Ahmad Khan

In the present study yeast biomass has been successfully used as biosorbent for removal of Crfrom aqueous solution. Yeasts of Saccharomyces cerevisiae are effective biosorbents for heavy metal ionsand it can be bought in large quantity at low cost. S. cerevisiae can remove toxic metals from aqueoussolutions to various levels. This low-cost biosorbent will make the process cost-effective and competitiveparticularly for environmental applications in detoxifying effluents. Langmuir’s and Freundlichs isothermswere also plotted to observe the maximum biosorption of heavy metal chromium (VI).


RSC Advances ◽  
2021 ◽  
Vol 11 (60) ◽  
pp. 37851-37865
Author(s):  
Zhanghong Wang ◽  
Kun Qin ◽  
Zhikang Wang ◽  
Dekui Shen ◽  
Chunfei Wu

The coked catalysts derived from catalytic reforming of the pyrolysis volatiles of polyethylene, lignin and their mixture were developed as low-cost and high-efficient carbon materials-containing composites to remove heavy metal ions from water.


2021 ◽  
Vol 12 (1) ◽  
pp. 1247-1262

This research work involved using factorial experimental design techniques to investigate the adsorption of hexavalent chromium from an aqueous solution on medlar activated carbon. A 24 full factorial experimental design was employed to determine the optimum values and degree of importance of parameters: pH, initial Cr (VI) concentration, adsorbent dose, and contact time at two levels. The optimized conditions for hexavalent chromium Cr (VI) removal were at initial pH 1.5, 5 mg.L−1Cr (VI), adsorbent dose 6 mg, and 60 min adsorption time. The results predicted a good agreement between the predicted values (R2= 0.9909), as obtained by the model, and the experimental value (R2= 0.9977). The main effects and interaction effects were analyzed using analysis of variance (ANOVA), F-test and P-values to define the most important process variables affecting Cr (VI) adsorption. The most significant variables were therefore the pH of the solution and the adsorbent dose. Therefore, the present results demonstrate that medlar activated carbon should be regarded as a low-cost alternative for removing Cr (VI) from an aqueous solution. The adsorption data were evaluated by Langmuir, Freundlich, and Dubinin-Radushkevich isotherms. The results showed that the Langmuir isotherm model best describes the equilibrium adsorption with a high correlation coefficient.


2021 ◽  
Vol 12 (2) ◽  
pp. 1884-1898

Natural water gets contaminated with heavy metal ions because of industrial effluents' discharge into the aquatic environment. As these heavy metal ions cause various health hazards, they should be removed from the aqueous solution. Heavy metal ion concentration in the aqueous solution is very less, so conventional metal removal and recovery processes cannot be applied here. The adsorption method is a great alternative to all these processes as it is a cost-effective and easy method. The use of natural, low-cost materials as adsorbents is eco-friendly also. However, metal uptake capacity of low-cost materials is very less. So, modification is required for low-cost materials to increase their efficiency. In the present review, different modification procedures adopted by different researchers have been discussed. Different low-cost materials used are sawdust, fruit and vegetable wastes, soil, minerals, etc. The modifying agents are heat, acids, bases, and other chemicals. Nevertheless, most of the studies are limited to batch tests only. Future research should be carried out on the extension of batch tests to column study for the large-scale treatment of contaminated water, and the cost of modification procedures and their impact on the environment should also be assessed.


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