scholarly journals Preparation of high-performance toluene adsorbents by sugarcane bagasse carbonization combined with surface modification

RSC Advances ◽  
2020 ◽  
Vol 10 (40) ◽  
pp. 23749-23758
Author(s):  
Yu Wang ◽  
Wangsheng Chen ◽  
Bo Zhao ◽  
Huaqin Wang ◽  
Linbo Qin ◽  
...  

A series of activated carbons were prepared by carbonizing sugarcane bagasse combined with surface modification, which showed an excellent performance of adsorbing toluene (522 mg g−1 at 30 °C).

2021 ◽  
Author(s):  
Yuan Qu ◽  
Li Xu ◽  
Yi Chen ◽  
Shikuan Sun ◽  
Yu Wang ◽  
...  

Abstract Carbon-based materials with great adsorption performance are of importance to meet the needs of industrial gas adsorption. Being massive agricultural wastes of sugarcane bagasse, China could use this waste into wealth. However, the comprehensive utilization of sugarcane bagasse as precursors for biochar that can be used as adsorbent has not been extensively explored. In this study, a series of in-situ sulfuric acid modified biochar were prepared by hydrothermal carbonization process. The prepared biochar (SBAC-7) is combined of two main advantages that are high microporosity (micropore surface area = 1106 m 2 /g) and rich in S-containing functional groups on the surface. In particular, SBAC-7 showed an excellent adsorption capacity of toluene (771.1 mg/g) at 30 o C, which is nearly 3 times as high as the commercial activated carbons. Meanwhile, it showed great stability and cyclic regeneration performance with five toluene adsorption-desorption test cycles. This study provides a high-performance biochar for adsorption-desorption cycle in practical engineering applications, and would contribute to the sustainable “sugarcane production - bagasse utilization” circular economy.


2017 ◽  
pp. 96-103 ◽  
Author(s):  
Gillian Eggleston ◽  
Isabel Lima ◽  
Emmanuel Sarir ◽  
Jack Thompson ◽  
John Zatlokovicz ◽  
...  

In recent years, there has been increased world-wide concern over residual (carry-over) activity of mostly high temperature (HT) and very high temperature (VHT) stable amylases in white, refined sugars from refineries to various food and end-user industries. HT and VHT stable amylases were developed for much larger markets than the sugar industry with harsher processing conditions. There is an urgent need in the sugar industry to be able to remove or inactivate residual, active amylases either in factory or refinery streams or both. A survey of refineries that used amylase and had activated carbon systems for decolorizing, revealed they did not have any customer complaints for residual amylase. The use of high performance activated carbons to remove residual amylase activity was investigated using a Phadebas® method created for the sugar industry to measure residual amylase in syrups. Ability to remove residual amylase protein was dependent on the surface area of the powdered activated carbons as well as mixing (retention) time. The activated carbon also had the additional benefit of removing color and insoluble starch.


RSC Advances ◽  
2021 ◽  
Vol 11 (33) ◽  
pp. 20601-20611
Author(s):  
Md. Mijanur Rahman ◽  
Kenta Inaba ◽  
Garavdorj Batnyagt ◽  
Masato Saikawa ◽  
Yoshiki Kato ◽  
...  

Herein, we demonstrated that carbon-supported platinum (Pt/C) is a low-cost and high-performance electrocatalyst for polymer electrolyte fuel cells (PEFCs).


2017 ◽  
Vol 5 (48) ◽  
pp. 25368-25377 ◽  
Author(s):  
Yeong A. Lee ◽  
Jiyoung Lee ◽  
Dae Wook Kim ◽  
Chung-Yul Yoo ◽  
Sang Hyun Park ◽  
...  

The mussel-inspired surface modification for high-performance electrochemical capacitors is demonstrated.


2017 ◽  
Vol 139 (6) ◽  
Author(s):  
X. P. Zhu ◽  
P. C. Du ◽  
Y. Meng ◽  
M. K. Lei ◽  
D. M. Guo

Inverse problem of manufacturing is studied under a framework of high performance manufacturing of components with functional surface layer, where controllable generation of surface integrity is emphasized due to its pivotal role determining final performance. Surface modification techniques capable of controlling surface integrity are utilized to verify such a framework of manufacturing, by which the surface integrity desired for a high performance can be more effectively achieved as reducing the material and geometry constraints of manufacturing otherwise unobtainable during conventional machining processes. Here, thermal spraying of WC–Ni coatings is employed to coat stainless steel components for water-lubricated wear applications, on which a strategy for direct problem from process to performance is implemented with surface integrity adjustable through spray angle and inert N2 shielding. Subsequently, multiple surface integrity parameters can be evaluated to identify the major ones responsible for wear performance by elucidating the wear mechanism, involving surface features (coating porosity and WC phase retention) and surface characteristics (microhardness, elastic modulus, and toughness). The surface features predominantly determine tribological behaviors of coatings in combination with the surface characteristics that are intrinsically associated with the surface features. Consequently, the spray process with improved N2 shielding is designed according to the desired surface integrity parameters for higher wear resistance. It is demonstrated that the correlations from processes to performance could be fully understood and established via controllable surface integrity, facilitating solution to inverse problem of manufacturing, i.e., realization of a material and geometry integrated manufacturing.


2021 ◽  
pp. 088532822110511
Author(s):  
Youbin Li ◽  
Shaochuan Wang ◽  
Shidan Li ◽  
Jun Fei

Implant-related infection is a disastrous complication. Surface modification of titanium is considered as an important strategy to prevent implant-related infection. However, there is no recognized surface modification strategy that can be applied in clinic so far. We explored a new strategy of coating. The clindamycin-loaded titanium was constructed by layer-by-layer self-assembly. The release of clindamycin from titanium was detected through high performance liquid chromatography. Different titanium was co-cultured with Staphylococcus aureus for 24 h in vitro, then the effect of different titanium on bacterial colonization and biofilm formation was determined by spread plate method and scanning electron microscopy. Cytotoxicity and cytocompatibility of clindamycin-loaded titanium on MC3T3-E1 cells were measured by CCK8. The antibacterial ability of clindamycin-loaded titanium in vivo was also evaluated using a rat model of osteomyelitis. The number of osteoclasts in bone defect was observed by tartrate-resistant acid phosphatase staining. Bacterial burden of surrounding tissues around the site of infection was calculated by tissue homogenate and colony count. Clindamycin-loaded titanium could release clindamycin slowly within 160 h. It reduced bacterial colonization by three orders of magnitude compare to control ( p < .05) and inhibits biofilm formation in vitro. Cells proliferation and adhesion were similar on three titanium surfaces ( p > .05). In vivo, clindamycin-loaded titanium improved bone healing, reduced microbial burden, and decreased the number of osteoclasts compared control titanium in the rat model of osteomyelitis. This study demonstrated that clindamycin-loaded titanium exhibited good biocompatibility, and showed antibacterial activity both in vivo and in vitro. It is promising and might have potential for clinical application.


2004 ◽  
Vol 4 (4) ◽  
pp. 89-94 ◽  
Author(s):  
R. Fabris ◽  
C.W.K. Chow ◽  
M. Drikas

Three different powdered activated carbons were applied in combination with aluminium sulphate to treat a high dissolved organic carbon (DOC) source water with a focus on improving natural organic matter removal. Treated water quality was analysed using absorbance at 254 nm, DOC, trihalomethane formation potential (THM-FP), rapid fractionation, C13 NMR and molecular weight distribution by high performance size exclusion chromatography. Carbon C and B offered equivalent DOC removal but carbon C was considered superior as treated water THM-FP was reduced. It is postulated that an organic fraction around 1000 Daltons is responsible for differences in THM-FP shown in the treated waters.


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