scholarly journals Terpyridine-based Pd(ii)/Ni(ii) organometallic framework nano-sheets supported on graphene oxide—investigating the fabrication, tuning of catalytic properties and synergetic effects

RSC Advances ◽  
2020 ◽  
Vol 10 (39) ◽  
pp. 23080-23090 ◽  
Author(s):  
Ruirui Ren ◽  
Sa Bi ◽  
Linhong Wang ◽  
Wuduo Zhao ◽  
Donghui Wei ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Catalytic Activity ◽  
Synergistic Effect ◽  
Catalytic Properties ◽  
Synergetic Effects

The synergistic effect between Ni and Pd atom was the crucial factor for enhancing catalytic activity.

A facile construction of Au nanoparticles on a copolymer ligand brushes modified graphene oxide nanoplatform with excellent catalytic properties

RSC Advances ◽  
2016 ◽  
Vol 6 (69) ◽  
pp. 64937-64945 ◽  
Author(s):  
Yajiao Song ◽  
Jianhua Lü ◽  
Bingxin Liu ◽  
Changli Lü
Keyword(s):  
Graphene Oxide ◽  
Catalytic Activity ◽  
Au Nanoparticles ◽  
Catalytic Properties ◽  
High Catalytic Activity ◽  
Au Nps ◽  
Modified Graphene Oxide ◽  
Modified Graphene ◽  
Copolymer Brush

Au NPs were generated via in situ reduction on copolymer brush P(OEGMA-co-MQ) functionalized GO. MQ units in the brushes as capping agents could stabilize the Au NPs. The Au NPs–GO hybrid exhibited high catalytic activity for the reduction of 4-NP.

Ionic liquids grafted onto graphene oxide as a new multifunctional heterogeneous catalyst and its application in the one-pot multi-component synthesis of hexahydroquinolines

2017 ◽  
Vol 41 (14) ◽  
pp. 6219-6225 ◽  
Author(s):  
Sara Sobhani ◽  
Farzaneh Zarifi ◽  
Jørgen Skibsted
Keyword(s):  
Graphene Oxide ◽  
Catalytic Activity ◽  
Ionic Liquids ◽  
Reaction Mechanism ◽  
Synergistic Effect ◽  
Heterogeneous Catalyst ◽  
Carboxylic Acids ◽  
One Pot ◽  
The One

The synergistic effect of ionic liquids and carboxylic acids in the reaction mechanism improved the catalytic activity of supported ILs.

Polyoxometalate-assisted fabrication of the Pd nanoparticle/reduced graphene oxide nanocomposite with enhanced methanol-tolerance for the oxygen reduction reaction

2016 ◽  
Vol 40 (2) ◽  
pp. 914-918 ◽  
Author(s):  
Ji-Sen Li ◽  
Hui-Qing Dong ◽  
Shun-Li Li ◽  
Run-Han Li ◽  
Zhi-Hui Dai ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Catalytic Activity ◽  
Synergistic Effect ◽  
Oxygen Reduction Reaction ◽  
Reduced Graphene Oxide ◽  
Reduction Reaction ◽  
Methanol Tolerance ◽  
Pd Nanoparticle ◽  
Reduced Graphene ◽  
Effect Of Pd

The prepared Pd/polyoxometalate/reduced graphene oxide (Pd/POM/rGO) nanocomposite exhibits enhanced catalytic activity and excellent methanol-tolerance due to the synergistic effect of Pd, POM, and rGO.

Facile sonochemical synthesis and electrochemical investigation of ceria/graphene nanocomposites

2015 ◽  
Vol 3 (11) ◽  
pp. 2362-2370 ◽  
Author(s):  
Amin Shiralizadeh Dezfuli ◽  
Mohammad Reza Ganjali ◽  
Parviz Norouzi ◽  
Farnoush Faridbod
Keyword(s):  
Graphene Oxide ◽  
Catalytic Activity ◽  
Synergistic Effect ◽  
Self Assembly ◽  
Sonochemical Method ◽  
Electrochemical Investigation ◽  
Sonochemical Synthesis ◽  
Graphene Nanocomposites ◽  
Reduced Graphene ◽  
Electro Catalytic Activity

We have developed a self-assembly approach to anchor CeO2 nanoparticles onto reduced graphene oxide (RGO) through a sonochemical method. We found that a suitable loading content of CeO2 on RGO can induce a synergistic effect for optimizing the electro-catalytic activity of the nanocomposites.

Decomposition of hydrogen peroxide on a two-component NiO-CdO catalyst and the effect of ionizing radiation on its catalytic properties

1979 ◽  
Vol 44 (4) ◽  
pp. 1015-1022 ◽  
Author(s):  
Viliam Múčka
Keyword(s):  
Aqueous Solution ◽  
Hydrogen Peroxide ◽  
Catalytic Activity ◽  
Nickel Oxide ◽  
Catalytic Properties ◽  
Cadmium Oxide ◽  
Chemisorb Oxygen ◽  
Composition Region ◽  
Chemisorbed Oxygen ◽  
Two Component

The catalytic properties of two-component catalyst nickel oxide-cadmium oxide with the proportions of the components covering the whole composition region 0-100% were examined by studying the decomposition of hydrogen peroxide in aqueous solution on it. In the range 0-25 mol.% CdO, cadmium oxide is found to affect infavourably the ability of nickel oxide to chemisorb oxygen. The amount of the chemisorbed oxygen increases several times on gamma irradiation of the samples. The effect of cadmium oxide on the catalytic activity of the system shows up in fresh samples only indirectly via the changed amount of the oxygen chemisorbed. In older samples the initial catalytic activity of the system is changed, which can be explained based on the concept of bivalent catalytic centres in terms of the co-action of the catalytic centres of the two oxides, which are in equilibrium. The irradiation of the system under study speeds up the processes leading to the establishing of this equilibrium which is thermally very stable, and results in a substantial increase of the catalytic activity of the samples investigated.

Hydrogen peroxide decomposition on a two-component CuO-Cr2O3 catalyst

1988 ◽  
Vol 53 (8) ◽  
pp. 1636-1646 ◽  
Author(s):  
Viliam Múčka ◽  
Kamil Lang
Keyword(s):  
Hydrogen Peroxide ◽  
Catalytic Activity ◽  
Extreme Values ◽  
Catalytic Properties ◽  
Active Components ◽  
Catalytic Systems ◽  
Heterogeneous Catalytic ◽  
Peroxide Decomposition ◽  
Two Component ◽  
Catalytically Active

Some physical and catalytic properties of the two-component copper(II)oxide-chromium(III)oxide catalyst with different content of both components were studied using the decomposition of the aqueous solution of hydrogen peroxide as a testing reaction. It has been found that along to both basic components, the system under study contains also the spinel structure CuCr2O4, chromate washable by water and hexavalent ions of chromium unwashable by water. The soluble chromate is catalytically active. During the first period of the reaction the equilibrium is being established in both homogeneous and heterogeneous catalytic systems. The catalytic activity as well as the specific surface area of the washed solid is a non-monotonous function of its composition. It seems highly probable that the extreme values of both these quantities are not connected with the detected admixtures in the catalytic system. The system under study is very insensitive with regard to the applied doses of gamma radiation. Its catalytic properties are changed rather significantly after the thermal treatment and particularly after the partial reduction to low degree by hydrogen. The observed changes of the catalytic activity of the system under study are very probably in connection with the changes of the valence state of the catalytically active components of the catalyst.

NiAg-graphene quantum dot-graphene hybrid with high oxidase-like catalytic activity for sensitive colorimetric detection of malathion

2021 ◽  
Author(s):  
Xu Dan ◽  
Ruiyi Li ◽  
Qinsheng Wang ◽  
Yongqiang Yang ◽  
Haiyan Zhu ◽  
...  
Keyword(s):  
Quantum Dots ◽  
Graphene Oxide ◽  
Catalytic Activity ◽  
Quantum Dot ◽  
Colorimetric Detection ◽  
Graphene Quantum Dots ◽  
Functionalized Graphene ◽  
Graphene Quantum Dot ◽  
Nickel Silver

The paper reports the synthesis of nickel-silver-graphene quantum dot-graphene hybrid. Histidine-functionalized graphene quantum dots (His-GQDs) were bonded to graphene oxide (GO) and then combined with Ni2+ and Ag+ to form...

scholarly journals Influence of the Reduction Temperature and the Nature of the Support on the Performance of Zirconia and Alumina-Supported Pt Catalysts for n-Dodecane Hydroisomerization

Catalysts ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 88
Author(s):  
Diana García-Pérez ◽  
Maria Consuelo Alvarez-Galvan ◽  
Jose M. Campos-Martin ◽  
Jose L. G. Fierro
Keyword(s):  
Catalytic Activity ◽  
Surface Area ◽  
Catalytic Properties ◽  
Catalytic Performance ◽  
Major Influence ◽  
Pt Catalysts ◽  
Reduction Temperature ◽  
Metal Dispersion ◽  
Tungsten Oxides ◽  
Supported Pt Catalysts

Catalysts based on zirconia- and alumina-supported tungsten oxides (15 wt % W) with a small loading of platinum (0.3 wt % Pt) were selected to study the influence of the reduction temperature and the nature of the support on the hydroisomerization of n-dodecane. The reduction temperature has a major influence on metal dispersion, which impacts the catalytic activity. In addition, alumina and zirconia supports show different catalytic properties (mainly acid site strength and surface area), which play an important role in the conversion. The NH3-TPD profiles indicate that the acidity in alumina-based catalysts is clearly higher than that in their zirconia counterparts; this acidity can be attributed to a stronger interaction of the WOx species with alumina. The PtW/Al catalyst was found to exhibit the best catalytic performance for the hydroisomerization of n-dodecane based on its higher acidity, which was ascribed to its larger surface area relative to that of its zirconia counterparts. The selectivity for different hydrocarbons (C7–10, C11 and i-C12) was very similar for all the catalysts studied, with branched C12 hydrocarbons being the main products obtained (~80%). The temperature of 350 °C was clearly the best reduction temperature for all the catalysts studied in a trickled-bed-mode reactor.

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